• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.5
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• pp.199-204
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• 2022

A new three-dimensional Gd-MOF, [Gd(p-XBP4)₄(H₂O)]·W(CN)₈; (1; p-XBP4 = N,N'-p-phenylenedimethylenbis (pyridin-4-one)) has been synthesized by slow-evaporation and its crystal structure was characterized by single-crystal X-ray diffraction (SCXRD) analysis. For each Gd^III ion, there are seven coordination sites, which are occupied by six oxygen atoms of six p-XBP4 ligands and one oxygen atom from the water molecule. The [W(CN)₈]^3- anion exists for charge balance with cationic framework. The Gd^II ions are interconnected by the p-XBP4 ligand to form the three-dimensional structure. Considering the magnetic property of lanthanide ions, magnetic studies of Gd-MOF were investigated by direct-current (DC) magnetic susceptibilities measurements.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.2
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• pp.303-310
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• 2017

Evapotranspiration is a significant hydrologic quantity for understanding the amount of available water resource evaluation, water balance analysis, water circulation and energy circulation. Various methods have been developed for estimating the evapotranspiration using data observed at meteorological observatories. Especially, the focus of methods has been on the complementary relationship that the actual evapotranspiration is equal to the difference between the twice of evapotranspiration in the wet condition and the potential evapotranspiration. The Granger and Gary (GG) method is an empirical formula that can be used to estimate the evapotranspiration using only empirical parameters based on the complementary relationship and using only the net radiation and temperature of the region. In this study, we compared the evapotranspiration data observed at 10 sites in Asia within the dataset of FLUXNET2015, with the evapotranspiration calculated by GG method. The evapotranspiration in inland area was estimated more accurately than that of coastal area. Simulated Annealing (SA) was used for the coastal area to modify the parameters. Using the modified GG method, we could improve the statistics such as root mean square error, the coefficient of determination ($R^2$), and the mean absolute ${\mid}BIAS{\mid}$ of the evapotranspiration estimation in coastal area.

• Journal of Wetlands Research
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• v.22 no.1
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• pp.15-23
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• 2020

The purpose of this study is to investigate how the degree of distribution influences the calibration of snow and runoff in distributed hydrological models using a multi-criteria calibration method. The Hydrology Laboratory-Research Distributed Hydrologic Model (HL-RDHM) developed by NOAA-National Weather Service (NWS) is employed to estimate optimized parameter sets. We have 3 scenarios depended on the model complexity for estimating best parameter sets: Lumped, Semi-Distributed, and Fully-Distributed. For the case study, the Durango River Basin, Colorado is selected as a study basin to consider both snow and water balance components. This study basin is in the mountainous western U.S. area and consists of 108 Hydrologic Rainfall Analysis Project (HRAP) grid cells. 5 and 13 parameters of snow and water balance models are calibrated with the Multi-Objective Shuffled Complex Evolution Metropolis (MOSCEM) algorithm. Model calibration and validation are conducted on 4km HRAP grids with 5 years (2001-2005) meteorological data and observations. Through case study, we show that snow and streamflow simulations are improved with multiple criteria calibrations without considering model complexity. In particular, we confirm that semi- and fully distributed models are better performances than those of lumped model. In case of lumped model, the Root Mean Square Error (RMSE) values improve by 35% on snow average and 42% on runoff from a priori parameter set through multi-criteria calibrations. On the other hand, the RMSE values are improved by 40% and 43% for snow and runoff on semi- and fully-distributed models.

• Journal of the Korean Chemical Society
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• v.51 no.1
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• pp.21-30
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• 2007

A multiwavelength spectrophotometric titration method was applied to study protolytic constants of four water-soluble vitamins, folic acid(vitamin B9 or B0), thiamine(vitamin B1), riboflavin(vitamin B2) and pyridoxal (vitamin B6) in binary ethanol-water mixtures at 25oC and an ionic strength of 0.1M NaNO3. The protolytic equilibrium constants, spectral profiles, concentration diagrams and also the number of components has been calculated from the curve fitting of the pH-absorbance data with appropriate mass balance equations by an established factor analysis model. DATAN program was used for determination of acidity constant and SPECFIT program was used for calculation of standard deviations and partial correlation coefficients. A glass electrode calibration procedure based on the four parameter equation pH=α+SpcH+JH+[H+]+ JOH-Kw/[H+] based on the Gran,s plots was used to obtain pH-readings in the concentration scale (pcH). The effect of the solvent on the protolytic constants was discussed.

• The Journal of Engineering Geology
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• v.18 no.3
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• pp.263-276
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• 2008

In diverse hydrogeologic fields, estimation of groundwater storage change is one of the most critical issues. Accurate estimation methods for determining groundwater storage change are required more and more. For Yeonyang area of Ulsan Megacity, groundwater storage change was estimated by using water balance method and hydrogeological analyses. The estimates of groundwater storage change was 240 mm corresponding to 18.7% of mean annual precipitation. Direct runoff was calculated as 137 mm (10.6% of mean annual precipitation) by using SCS-CN method. Evapotranspiration based on the Thornthwaite method was calculated as 776 mm (60.5% of mean annual precipitation). Hydraulic properties of the soil types do not show any distinct relation with hydraulic conductivity of the rocks. This fact suggests that hydraulic property on the surface is different from that of subsurface geology. According to multi-linear regression analysis between groundwater storage change and hydraulic parameters, a regression equation of groundwater storage change, which was explained by precipitation and evapotranspiration, was established.

• Journal of Korea Water Resources Association
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• v.41 no.3
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• pp.243-249
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• 2008

Continuous stirred tank reactor(CSTR) model which can be applied to control and management of the surface flow wetland is developed to simulate the water quality in this research. The model solution is obtained from the optimization model using the least-squares and 4th-order Runge-Kutta methods. The model is applied to simulate BOD and TSS in the wetland database of U.S. EPA, in which the hydraulic and water quality data are enough and the number of pond is just one for simple analysis of running results. The model is tested in two different cases, one constant volume case and another constant volume and flow rate case considering only reaction term, mass flux term and both reaction and mass flux terms respectively. It is found that the model simulates the real water quality very well with both reaction and mass flux terms rather than only reaction term and the settling velocity of TSS becomes $0.3{\sim}0.4\;m/d$. The model can be applied in wetlands treatment efficiently.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.2
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• pp.161-170
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• 1997

The concentrations of dimethylsulfide (DMS) were determined using samples collected from a station located at Kosan, Cheju Island during two field campaigns held in December 1996 and January 1997. The atmospheric DMS concentrations measured at 6-hr intervals during the entire campaign periods, after excluding a few extreme values, spanned in the range of 14 to 410 pptv with mean and 1 SD value of 127 $\pm$ 94 pptv (N=42). Between two month periods during which the field campaigns were conducted, a notable reduction in DMS levels was observed which was comparable to the dramatic shift in air temperature. A considerable difference was also noted in DMS levels, when data were grouped by day/night basis. The cause of unexpected, high day-to-night DMS ratios is best explained in terms of high efficiency of daytime source processes relative to low efficiency of nighttime sink processes due to the characteristics of the study location. The surface water DMS of the study site, although scarcely measured, also behaved similarly to its atmospheric counterpart with its range from 0.3 to 19 nM (N=11). When correlation analysis was conducted between the atmospheric DMS concentration and other concurrently determined parameters, significant correlations were observed from most basic meteorological parameters such as windspeed, relative humidy, and air temperature. However, the existence of "not-so-strong" correlations between air temperature and DMS concentrations relative to other ones indicated that the effect of temperature on DMS behavior must be reflected in more complicated manners at the study site. The sea-to-air flux of DMS was approximated through an application of the mass-balance flux calculation method of Wylie and de Mora (1996) under the assumption that sink mechanism within the marine boundary layer is in steady-state condition with its counterpart, source mechanism. Based on this estimation method, we reached a conclusion that oceanic DMS emitted from the southwest sea of the Korean Peninsula can amount to approximately 9 $\sim$ 36 Gg S $yr^{-1}$.$yr^{-1}$.

• Ecology and Resilient Infrastructure
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• v.10 no.3
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• pp.51-63
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• 2023

Riverine tree management is crucial in realizing a balance between flood control and ecological preservation, which requires an accurate assessment of the impact of trees on river water elevations. In this study, eight different formulas for evaluating vegetation roughness considering the drag force acting on trees, were reviewed, and the characteristics and applicability of these methods were evaluated from a practical engineering perspective. The study compared the characteristics of vegetation roughness measurement methods for calculated roughness coefficients at different water depths and analyzed factors such as effects of tree canopy width, tree density and diameter, and tree stiffness coefficient, and water level estimation results. A comparison of roughness coefficients at the same water depths revealed that the Kouwen and Fathi-Moghadam formulas and the Fischenich formula yield excessive drag coefficients compared to other formulas. Factors such as channel geometry, tree diameter, and tree density showed varying trends depending on the formula but did not exhibit excessive outliers. Formulas considering the tree stiffness coefficient, such as the Freeman et al.'s formula and the Whittaker et al.'s formula, showed significant variations in drag coefficients depending on the stiffness coefficient. When applied to small- and medium-sized virtual rivers in South Korea using the drag coefficient results from the eight formulas, the results indicated a maximum increase in water level of approximately 0.2 to 0.4 meters. Based on this review, it was concluded that the Baptist et al., Huthoff et al., Cheng, Luhar, and Nepf's formulas, which exhibit similar characteristics and low input data uncertainties, are suitable for practical engineering applications.

• Journal of Soil and Groundwater Environment
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• v.12 no.5
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• pp.19-32
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• 2007

In Korea, there have been various methods of estimating groundwater recharge which generally can be subdivided into three types: baseflow separation method by means of groundwater recession curve, water budget analysis based on lumped conceptual model in watershed, and water table fluctuation method (WTF) by using the data from groundwater monitoring wells. However, groundwater recharge rate shows the spatial-temporal variability due to climatic condition, land use and hydrogeological heterogeneity, so these methods have various limits to deal with these characteristics. To overcome these limitations, we present a new method of estimating recharge based on water balance components from the SWAT-MODFLOW which is an integrated surface-ground water model. Groundwater levels in the interest area close to the stream have dynamics similar to stream flow, whereas levels further upslope respond to precipitation with a delay. As these behaviours are related to the physical process of recharge, it is needed to account for the time delay in aquifer recharge once the water exits the soil profile to represent these features. In SWAT, a single linear reservoir storage module with an exponential decay weighting function is used to compute the recharge from soil to aquifer on a given day. However, this module has some limitations expressing recharge variation when the delay time is too long and transient recharge trend does not match to the groundwater table time series, the multi-reservoir storage routing module which represents more realistic time delay through vadose zone is newly suggested in this study. In this module, the parameter related to the delay time should be optimized by checking the correlation between simulated recharge and observed groundwater levels. The final step of this procedure is to compare simulated groundwater table with observed one as well as to compare simulated watershed runoff with observed one. This method is applied to Mihocheon watershed in Korea for the purpose of testing the procedure of proper estimation of spatio-temporal groundwater recharge distribution. As the newly suggested method of estimating recharge has the advantages of effectiveness of watershed model as well as the accuracy of WTF method, the estimated daily recharge rate would be an advanced quantity reflecting the heterogeneity of hydrogeology, climatic condition, land use as well as physical behaviour of water in soil layers and aquifers.

• Journal of the Society of Naval Architects of Korea
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• v.28 no.1
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• pp.60-68
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• 1991

The updated Lagrangian Finite Element Method is introduced to analyse rigid body-fluid impact problem which is characterized by incompressible Navier-Stokes equations and impact-contact conditions between free surface and rigid body. For the convenience of numerical computation, velocity fields are splinted into vicous and pressure parts, and then the governing equations and boundary conditions are decomposed in accordance with the decomposition. However, Viscous stresses acting an the solid boundaries are neglected on the assumption that very small velocity gradients may occur during extremely small time interval of the impact. Four coded quadrilateral elements are used to discretize the space domain and the fully explicit time-marching algorithm is employed with a reasonably small time step. At the beginning of each time step, contact velocity of the rigid body is computed from the momentum balance between the body and the fluid. The velocity field is then computed to satisfy the discretized equations of motions and incompressibility and contact constraints as well as an exact free surface boundary condition. At the end of each time step, the fluid domain is updated from the velocity field. In the present time stepping numerical analysis, behaviour of the free surface near the body can be observed without any difficulty which is very important in the water impact problem. The applicability of the algorithm is illustrated by a wedge type falling body problem. The numerical solutions for time-varying pressure distributions and impact loadings acting ion the surface are obtained.