• Environmental Engineering Research
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• 제15권3호
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• pp.163-166
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• 2010

Pulp and paper mill wastewater has been treated by biological treatment, but the secondary effluent still contains high lignin, chemical oxygen demand, color and total dissolved solids. Tertiary treatment by land application, referred to as 'Project Green,' has been implemented to treat such high quantities of undesirable matters. The impacts of seepage from Project Green diffusing into receiving streams on the water quality and fish pen aquaculture were studied via the integration of technical and social approaches. The determination of the water quality was performed for 13 sampling stations along the receiving stream, including the Chot stream, Chot lagoon and the Pong River. The water quality was generally at normal levels, with the exception of total dissolved solids. The levels of matter were higher at the Chot stream, but became more diluted at the Chot lagoon and the Pong River, respectively. The social approach was conducted through the voluntary participation of the villagers as research assistants for the fish aquaculture study. Fish could grow at three fish pens within the study sites at the location of Project Green, the Chot lagoon and the Pong River. Fish growth at the Chot lagoon was better at the site of Project Green and the Pong River. The integration of technical and social approaches was a meaningful tool not only for the technical feasibility but in helping to solve the conflict between the community and industry.

• Membrane and Water Treatment
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• 제9권5호
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• pp.373-383
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• 2018

Fouling by solids and microorganisms is the major obstacle limiting the efficient use of membrane wastewater treatment. In our previous study, two stages microalgae/membrane filtration system was proposed to treat anaerobic digested palm oil mill effluent (AnPOME). This two stages microalgae/membrane filtration system had showed great potential for the treatment of AnPOME with high removal of COD, $NH_3-N$, $PO_4{^{3-}}$, TSS, turbidity, and colour. However, fouling behavior of the membrane in this two stages microalgae/membrane filtration system was still unknown. In this study, empirical models that describe permeate flux decline for dead-end filtration (pore blocking - complete, intermediate, and standard; and cake layer formation) presented by Hermia were used to fit the experimental results in identifying the fouling mechanism under different experimental conditions. Both centrifuged and non-centrifuged samples were taken from the medium with 3 days RT intervals, from day 0 to day 12 to study their influence on fouling mechanisms described by Hermia for ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO) filtration mode. Besides, a more detailed study on the use of resistance-in-series model for deadend filtration was done to investigate the fouling mechanisms involved in membrane filtration of AnPOME collected after microalgae treatment. The results showed that fouling of UF and NF membrane was mainly caused by cake layer formation and it was also supported by the analysis for resistance-in-series model. Whereas, fouling of RO membrane was dominated by concentration polarization.

• 한국물환경학회지
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• 제16권4호
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• pp.491-499
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• 2000

Effluent concentration estimation equations for treatment wetland were reviewed with 3 -year experimental data. Four equations from USEPA, WPCF, Kadlec and Knight, and this study were applied to the over 100 data points of 1996 to 1999 study at the pilot plant in Konkuk University. The system was a subsurface flow type and consisted of 60cm depth of sand and reeds, and it worked continuously including winter with domestic sewage from school building. Generally, all the equations demonstrated reasonable agreement with experimental data and they could be used for design process if selected carefully. Among them, the equation from this study showed the best fit for the data. The reason might be not only the equation was derived from the experimental data, but also it included plant coverage parameter in the equation while others did not Plant coverage was proved to be an important parameter in the prediction of the treatment wetland system, and its inclusion in the estimation equation could improve the accuracy. Although existing equations could be used in the wetland design, pilot plant experiment for the anticipated condition and subsequent equation development can provide more reliable equation. It takes time to obtain meaningful data from wetland system. Therefore, timely onset of well organized study is recommended before large scale application of treatment wetland system to either point or nonpoint source pollution abatement.

• 한국물환경학회지
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• 제26권5호
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• pp.725-731
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• 2010

This study was to evaluate the ozone oxidation of dissolved Fe, Mn, $SO{_4}^{2-}$ ions and color in abandoned mining drainage by conducting a bench-scale operation at various reaction times in an ozone reactor. The influent was collected from an abandoned mine drainage (AMD) near the J Mine in Jungsungun, Kangwon Province. The ozone reactor was operated at ozone reaction times of 10, 20 and 30 min with ozone doses of 0.0 and $2.4g\;O_3/hr$. Samples from each effluent from subsequent sand filtration were regularly collected and analyzed for pH, Fe, Mn, Al, Cr, Hg, $SO{_4}^{2-}$, alkalinity, color, ORP, TDS and EC. The effluent concentrations of Fe and Mn from the sand filter were less than 0.1 mg/L, which were below the concentrations on Korean drinking water quality standards (Fe, Mn < 0.30 mg/L). The influent $SO{_4}^{2-}$, concentrations were not noticeably changed during this ozone oxidation. Cr and Hg in the raw wastewater from the abandoned mining drainage were not detected in this study. The experimental result shows that the ozone oxidation of dissolved heavy metals and subsequent sand filtration of metal precipitates are desirable alternative for removing heavy metals in AMD.

• 한국산학기술학회논문지
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• 제7권3호
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• pp.440-447
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• 2006

본 연구의 목적은 미나리와 끈상 미생물접촉재를 이용하여 생활하수의 하수처리장 방류수의 수질 개선을 위함이다. 최종 방류수의 수질을 개선하기 위한 침전조 모형 플랜트를 2개 제작하여 실험하였는데, 하나(Tank 1)는 기존 하수처리장 침전조와 같게 제작 하였으며, 다른 하나의 침전조(Tank 2)는 침전조의 수초섬 상부에는 미나리를 식재하고 하부에는 끈상 미생물 접촉재를 배치하였다. 유기 오염물질인 BOD, 부유고형물질인 SS, 질소 그리고 인에 대한 고도처리 효율을 검증하였다. 실험 결과 Tank 2에서 유출되는 배출수가 Tank 1에서 배출되는 유출수보다 처리 효율이 향상되었다. 처리 효율을 살펴보면, Tank 1보다 Tank 2 유출수의 BOD는 $7.9%{\sim}38.8%$가 향상되었으며, 부유고형 물질인 SS는 $14.3%{\sim}60.0%$ 향상되었다. 부영양화 물질인 T-N은 $9.6%{\sim}31.5%$ 향상되었으며, T-P는 $33.0%{\sim}80.0%$까지 향상되었다. 처리 효율로 판단하면 T-P와 SS 제거효율이 BOD와 T-N보다 높았다.

• 한국농공학회논문집
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• 제58권6호
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• pp.9-21
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• 2016

Agricultural reservoirs in Korea have been recognized as an emerging resource for recreational and cultural activities for residents. However, most of the reservoirs are eutrophic and showing high level of contamination with nuisance algal bloom and offensive odor during the summer. For better management and restoration of the reservoirs' water quality, scientific modeling approaches could be used to diagnose the problems and evaluate the efficacy of alternative control measures. The objectives of this study were to validate the performance of a three-dimensional (3D) hydrodynamic and water quality model (Environmental Fluid Dynamics Code, EFDC) for a eutrophic agricultural reservoir and assess the effect of bypassing of the effluent from a wastewater treatment plant on the reservoir water quality. The 3D model successfully simulated the temporal variations of water temperature, DO, TOC, nitrogen and phosphorus species and Chl-a observed in 2014 and also captured their spatial heterogeneity in the reservoir. The simulation results indicated that the point source bypassing may reduce the T-N and T-P concentrations of the reservoir by 6.6 ~ 8.2 %, and 1.7 ~ 16.8 %, respectively. The bypassing, however, showed a marginal effect on the control of TOC due to the increased algal biomass associated with the increased water retention time after bypassing as well as the lower TOC level of the effluent compared to the ambient reservoir water.

• 한국물환경학회지
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• 제21권5호
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• pp.458-463
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• 2005

Considering the characteristics of a filtration bio-reactor equipped with a mesh filter module which can effectively maintain high concentration of biomass and enhanced solid-liquid separation performance, the hybrid process of filtration bio-reactor combined with coagulation was investigated to get improved filtration characteristics as well as water quality in this work. Two bio-reactors (Run-1 & Run-2) were operated under the following conditions: working volume of 25 L, continuous loading of a synthetic wastewater (BOD: 200 mg/L, T-N: 50 mg/L, T-P: 5 mg/L), where an appropriate amount of alum ($Al_2(SO_4)_3{\cdot}18H_2O$) was added once a day into the reactor (Run-2). In the system without using a alum (Run-1), the clogging of mesh filter module was observed two times through 85 days of whole operation. Meanwhile, the filter module did not clog even at higher MLSS concentration (6,000~12,000 mg/L) and the stable filtration (0.7 mid) was continued in the case of using a alum. Due to the stable formation of cake layers, BOD and SS were shown below 6 and 3 mg/L, respectively. T-P and pH of the effluent were changed because of the intermittent addition of the alum. In the case of Al/P=2.5, the average T-P removal efficiency per day was 85.2% and the average T-P concentration of the effluent was 0.3 mg/L. However, the removal efficiency of phosphate was influenced by pH in the reactor.

• 한국물환경학회지
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• 제25권5호
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• pp.704-712
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• 2009

Advanced Phase Isolation Ditch (APID) process was studied to develop economic retrofitting technology, for the plants where retrofitting of common activated sludge process is required. In this study, to evaluate and monitor the effluent water quality ($BOD_5$, SS, T-N, and T-P) and operating conditions (Influent, SVI, SRT, and HRT) as process capable and stable parameters for treating municipal wastewater, a demonstration plant was installed and operated in the existing sewage treatment plant of P city. During this study, the average effluent $BOD_5$, SS, T-N, and T-P concentrations were 7.7, 5.6, 10.8, and 1.6 mg/L. Trend analysis of influent $BOD_5$, SS, T-N, and T-P in APID process were illustrated that APID process need for more strong APID process management on the winter session, such as developing new intermediated aeration mode, operating methods, and managements strategy. At the application of control chart, the signal of uncommon effects at APID process was determined much higher existing control chart tntr conventional control chart in this study. These results indicate that conventional control chart has been collected and determined cleary signal at only stable situation. Therefore, newly developed APID process of dynamic control chart can be one of the useful tool for monitoring and management process.

• Membrane and Water Treatment
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• 제11권4호
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• pp.283-294
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• 2020

This work aims at studying the feasibility of continuous removal of mixed heavy metal ions from simulated zinc plating wastewaters by coupling a microbial fuel cell and a microbial electrolysis cell in batch and continuous modes. The discharging voltage of MFC increased initially from 0.4621 ± 0.0005 V to 0.4864 ± 0.0006 V as the initial concentration of Cr⁶⁺ increased from 10 ppm to 60 ppm. Almost complete removal of Cr⁶⁺ and low removal of Cu²⁺ occurred in MFC of the MFC-MEC-coupled system after 8 hours under the batch mode; removal efficiencies (REs) of Cr⁶⁺ and Cu²⁺ were 99.76% and 30.49%. After the same reaction time, REs of nickel and zinc ions were 55.15% and 76.21% in its MEC. Cu²⁺, Ni²⁺, and Zn²⁺ removal efficiencies of 54.98%, 30.63%, 55.04%, and 75.35% were achieved in the effluent within optimum HRT of 2 hours under the continuous mode. The incomplete removal of Cu²⁺, Ni²⁺ and Zn²⁺ ions in the effluent was due to the fact that the Cr⁶⁺ was almost completely consumed at the end of MFC reaction. After HRT of 12 hours, at the different sampling locations, Cr⁶⁺ and Cu²⁺ removal efficiencies in the cathodic chamber of MFC were 89.95% and 34.69%, respectively. 94.58%, 33.95%, 56.57%, and 75.76% were achieved for Cr⁶⁺, Cu²⁺, Ni²⁺ and Zn²⁺ in the cathodic chamber of MEC. It can be concluded that those metal ions can be removed completely by repeatedly passing high concentration of Cr⁶⁺ through the cathode chamber of MFC of the MFC-MEC-coupled system.

• Membrane and Water Treatment
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• 제11권4호
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• pp.257-274
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• 2020

There are many previous review articles are available to summarize either the characterization methods of effluent organic matter (EfOM) or the individual control treatment options. However, there has been no attempt made to compare in parallel the physicochemical treatment options that target the removal of EfOM from biological treatments. This review deals with the recent progress on the characterization of EfOM and the novel technologies developed for EfOM treatment. Based on the publications after 2010, the advantages and the limitations of several popularly used analytical tools are discussed for EfOM characterization, which include UV-visible and fluorescence spectroscopy, Fourier transform infrared spectroscopy (FTIR), size exclusion chromatography (SEC), and Fourier transform-ion cyclotron resonance-mass spectrometry (FT-ICR-MS). It is a recent trend to combine an SEC system with various types of detectors, because it can successfully track the chemical/functional composition of EfOM, which varies across a continuum of different molecular sizes. FT-ICR-MS is the most powerful tool to detect EfOM at molecular levels. However, it is noted that this method has rarely been utilized to understand the changes of EfOM in pre-treatment or post-treatment systems. Although membrane filtration is still the preferred method to treat EfOM before its discharge due to its high separation selectivity, the minimum requirements for additional chemicals, the ease of scaling up, and the continuous operation, recent advances in ion exchange and advanced oxidation processes are greatly noteworthy. Recent progress in the non-membrane technologies, which are based on novel materials, are expected to enhance the removal efficiency of EfOM and even make it feasible to selectively remove undesirable fractions/compounds from bulk EfOM.