• Title/Summary/Keyword: Wastes characteristics

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Characteristics of sound absorption materials by using ecological aggregates (에코골재를 사용한 흡음재의 특성)

  • Kim, Kang-Duk;Ryu, Yu-Gwang;Kim, Yoo-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.264-270
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    • 2008
  • Ecological lightweight aggregates were made by using the wastes come from various industrial fields. Wastes were crushed and pulverized by mills and a certain portions of wastes were mixed and formed by pelletizer like small beads. The formed lightweight aggregates were finally sintered with $1125^{\circ}C$/15 min conditions by using rotary kiln. Lightweight concrete sound absorbers were made of ecological lightweight aggregates K73 (Coal bottom ash 70 wt%: Dredged soil 30 wt%) and K631 (Clay 60 wt%: Stone sludge 30 wt%: Spent bleaching clay 10 wt%). For the reference, lightweight concrete sound absorbers made of DL (German made 'L' company LWA) were also made under the same conditions. Sound absorption characteristics were observed and measured according to the kinds of aggregates, water/cement ratio (W/C=20, 25, and 30%), and designed pore rates (V=20, 25, and 30%). The pore rates of the lightweight concrete sound absorber were turned out to be 5 to 10% higher than designed ones. Absorption coefficient of the lightweight concrete sound absorber by using K631 aggregates with W/C=20% and V=25% conditions was 0.88 at 1000 and 3150 Hz from the measurement by the impedance tube.

Content and leaching characteristics of non-regulated hazardous substances in waste from the paint industry (국내 도료공정 발생 폐기물 중 미규제 중금속류의 배출특성)

  • Jeong, Seong-Kyeong;Kim, Woo-Il;Kang, Young-Yeul;Kim, Dong-Un;Cho, Yoon-A;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.387-394
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    • 2011
  • This study was performed to investigate the contents and leaching characteristics of hazardous wastes from the paint industry. In order to establish a hazardous waste list, samples from industrial discharge have been analyzed for 8 non-regulated inorganic hazardous substances (i.e., Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples from a total of 64 workplaces, e.g. manufacture, formulation, supply and use (MFSU) of coatings, adhesives, sealants and printing inks processing, have been chosen and analyzed. Contents and leaching tests for inorganic metal species in samples show that the non-regulated hazardous substances satisfy all the criteria, while quantitative analyses reveal that some samples of the discharged wastes exceeded the criteria proposed by NIER (National Instituted of Environmental Research). In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

A Study on the Conceptual Development for a Deep Geological Disposal of the Radioactive Waste from Pyro-processing (파이로공정 발생 방사성폐기물 심지층 처분을 위한 개념설정 연구)

  • Lee, Jong-Youl;Lee, Min-Soo;Choi, Heui-Joo;Bae, Dae-Seok;Kim, Kyeong-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.219-228
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    • 2012
  • A long-term R&D program for HLW disposal technology development was launched in 1997 in Korea and Korea Reference disposal System(KRS) for spent fuels had been developed. After then, a recycling process for PWR spent fuels to get the reusable material such as uranium or TRU and to reduce the volume of radioactive waste, called Pyro-process, is being developed. This Pyro-process produces several kinds of wastes including metal waste and ceramic waste. In this study, the characteristics of the waste from Pyro-process and the concepts of a disposal container for the wastes were described. Based on these concepts, thermal analyses were carried out to determine a layout of the disposal area of the ceramic wastes which was classified as a high level waste and to develop the disposal system called A-KRS. The location of the final repository for A-KRS is not determined yet, thus to review the potential repository domains, the possible layout in the geological characteristics of KURT facility site was proposed. These results will be used in developing a repository system design and in performing the safety assessment.

Characteristics of hazardous oil & liquid fuel waste discharged from various industries (폐유 및 액상연료 공정 폐기물에서 무기물질류의 함량특성)

  • Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Kim, Woo-Il;Jeon, Tae-Wan;Kang, Young-Yeul;Yeon, Jin-Mo;Cho, Yoon-A;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.276-286
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    • 2013
  • This study was performed to investigate the contents characteristics of hazardous oil wastes and wastes of liquid fuels from different industrial process. In order to establish a hazardous waste list, samples of various industrial discharge have been analyzed for 16 non-regulated inorganic hazardous substances (i.e., Cu, Pb, Cd, CN, Hg, As, T-Cr, $Cr^{6+}$, Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples including waste hydraulic oils, waste engine, gear and lubricating oils, waste insulating and heat transmission oils, bilge oils, oil/water separator contents processing were collected from 37 workplaces and analyzed. We observed that the most of the inorganic substances exceeded the proposed criteria in many samples. Especially the concentration of Sb in heat transmission oil, bilge oil and gear & lubricating oils were ranged from 6 to 419 mg/kg whereas the proposed criteria is 50 mg/kg. The assessment result of hazardous waste in Korea according to the EWC showed that the out of 24 processes, 16 belongs to absolute entry and 8 belongs to mirror entry. In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

Characteristics of Hydrogen Production by Catalytic Pyrolysis of Plastics and Biomass (플라스틱 및 바이오매스의 촉매 열분해에 의한 수소 생성 특성)

  • Choi, Sun-Yong;Lee, Moon-Won;Hwang, Hoon;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.221-227
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    • 2010
  • In this study, we consider gas generation characteristics on pyrolysis of eco-fuel which were made by mixing of Pitch Pine and Lauan sawdust as biomass and polyethylene, polypropylene, polystyrene as municipal plastic wastes with catalyst in fixed bed reactor. From the result of higher heating value(HHV) measurement and of ultimate analysis, the heating value of plastic wastes and a hydrogen content in plastic sample are higher than biomass. An activation energy was reduced by a catalyst addition. However the catalyst content influence over 5 wt% was insignificant. The yield of hydrogen from gasification of biomass containing plastic wastes such as polyethylene, polypropylene and polystyrene were obtained higher than that of sole biomass. The high temperature and mixture ratio of catalyst conditions induced to high hydrogen yield in most of the samples. As the influence of catalyst, the hydrogen yield by catalytic reaction was higher than non-catalytic reaction. We confirmed that Ni-$ZrO_2$ catalyst is more active in increasing the hydrogen yield in comparison with that of carbonate catalyst. The maximum hydrogen yield was 65.9 vol.%(Pitch Pine / polypropylene / 20 wt.% Ni-$ZrO_2$(1:9) at $900^{\circ}C$).

Plan to Develop the Radioactive Waste Certification Program (방사성폐기물인증프로그램 개발 방안)

  • Chung Hee-Jun;Lee Jae-Min;Whang Joo-Ho;Kim Heon;Jeong Yi-Yeong
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.205-210
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    • 2005
  • The proposed regulation for low and intermediate level radioactive waste disposal facility, scheduled to be revised, recommends that the waste generator should verify the radioactive waste conforms to the disposal requirements before disposing of it. According to the regulation, the radionuclide concentration of the radioactive waste, and its physical and chemical characteristics and safety must be confirmed prior to the disposal of low and intermediate level radioactive wastes, and the waste generator is required to deliver this information to the disposal facility operator. In addition, the disposal facility operator must assess the safety of the disposal site to establish the SWAC (Site Specific Waste Acceptance Criteria) in consideration of the characteristics of the site, whereas the waste generator must comply with the criteria in managing, disposing of and delivering low and intermediate level radioactive wastes. To abide by the afore-mentioned regulation and criteria, the waste generator must verify that the radioactive wastes to be disposed of are suitable for disposal before they are transported to the disposal facility, and to this end a radioactive waste certification program must be developed. This study conducted an in-depth analysis of the radioactive waste certification programs enforced in countries advanced in atomic energy to develop a draft of a certification program applicable to local power plants, and the program is currently applied as pilot to Uljin Power Plants No. 1 & 2 to prove its applicability. This study is going to analyze the results of the pilot application with a view to developing a radioactive waste certification program suitable to local conditions.

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A Guideline for Construction Management Plan Based on the Characteristics of $CO_2$ Emissions: A Case Study for a High-Rise Residential Building Project ($CO_2$ 배출 특성을 고려한 건설폐기물 관리방안 수립기준: 고층 주거건물 건설 프로젝트를 대상으로 한 사례조사)

  • Kim, Jee-Hye;Shin, Dong-Woo;Cha, Hee-Sung
    • Korean Journal of Construction Engineering and Management
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    • v.8 no.6
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    • pp.150-158
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    • 2007
  • As the amount of $CO_2$ emission in Korea is ranked 9th and the increasing rate of $CO_2$ emissions highest in the world, it is strongly necessary to devise methods to decrease the amount of $CO_2$ in each industry as the basis of establishing environmentally sustainable production system. This paper aims to identify the characteristics of $CO_2$ emissions from construction wastes throughout the simplified LCA (Life Cycle Assessment) and suggest the strategic guideline for the construction waste management plan to decrease $CO_2$. As a result of LCA on the case of a high-rise residential building project, total sum of $CO_2$ emission generated from construction wastes appeared as 6,818,123kg-$CO_2$ and $CO_2$ emission per unit floor area as 21.01kg-$CO_2/{\beta}{\ge}$. The principal waste materials generating more than 95% of $CO_2$ are materials such as reinforcing bar, temporary materials, cement, ready-mixed-concrete, concrete products, and tile, which have relatively high unit emission rate of $CO_2$ in the process of production. Besides, more than 92% of $CO_2$ was generated from the activities such as structure work, plaster work, temporary work, and tile and stone work, which are generally executed in the early phase of the whole construction period. Reflecting these results, the guideline for the construction waste management plan was recommended. If the waste management plan is established considering the guideline suggested, there would be high potential to decrease the amount of $CO_2$ generated from construction wastes.

Characteristics of Solidified Cement of Electrokinetically Decontaminated Soil and Concrete Waste (동전기 제염 토양 및 콘크리트 폐기물의 시멘트 고화 특성)

  • Koo, Daeseo;Sung, Hyun-Hee;Hong, Sang Bum;Seo, Bum Kyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.83-91
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    • 2018
  • While using an electrokinetic method to analyze the characteristics of cement solidification of radioactive wastes from decontaminated uranium soil and concrete, the compressive strength, pH, electrical conductivity, irradiation effects, and volume expansion were measured for the solidified cement specimens. The workability of cement solidified from radioactive waste was about 170-190%. After the solidified cement was irradiated, the compressive strength decreased by about 15%, but met the criteria ($34kgf{\cdot}cm^{-2}$) of KORAD (Korea Radioactive Waste Agent). According to the results of SEM-EDS for solidified cement, the aluminum phase was well combined with cement, while the calcium phase was separated from cement. The volume of solidified cement in radioactive wastes was dependent on the waste-to-cement ratio and the amount of water, and increased by about 30% under the conditions used in this study. Therefore, it was concluded that permanent disposal of electrokinetically decontaminated radioactive wastes is appropriate.

Effect of Landfill Site Characteristics on Siloxane Production in Landfill Gas (매립지 특성이 매립가스 내 siloxane 발생에 미치는 영향)

  • Nam, Sangchul;Kang, Jeong-Hee;Hur, Kwang-Beom;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.44-53
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    • 2011
  • Siloxane, organo-silicon compound, is used in the various forms of products such as cosmetics and detergents due to its quality physical chemistry attributes. Siloxane included in landfill gas which is caused in the process of decomposing of such products after landfill has imposed negative impacts on the operation of landfill gas utility facilities. The objective of this study was to investigate the siloxane production characteristics depending on the features of various landfill site in Korea so that the analysis was made on the landfilling age and landfill waste by in terms of its concentration, structure and composition. As for the concentration of siloxane depending on time passage, 12 landfill sites were reviewed by landfilling age. As for production attributes change of siloxane by landfill wastes, the source of wastes, physical production ration and siloxane concentration were compared in 6 landfills. The average concentration of total-siloxane within LFG is $6.75mg/m^3$ and cyclic-siloxane out of it occupies over 93%. By element, D4 and D5 in order take the highest proportion regardless of total-siloxane concentration and landfilling age. Even though this study is not able to verify the different impact of each kind of wastes on the generation of siloxane, it is confirmed that total-siloxane and cyclic-siloxane decrease in line with the increase of landfilling age as it does in the first order decay model for landfill gas.

A Leg Analysis on the Discharge of Cargo Residue at Sea (화물잔류물의 해양 투입처분(배출) 사안에 대한 법률적 분석)

  • Hong, Gi-Hoon;Park, Chan-Ho
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.4
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    • pp.193-202
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    • 2006
  • The Consultative Meeting of the Convention on the Prevention of Marine Pollution by Dumping of Wastes and other matter, 1972 (London Convention 1972) has requested to International Maritime Organization (IMO) Marine Environmental Protection Committee to collaborate and help clarify a boundary issue between International Convention for the Prevention of Pollution from Shops, 1973 as modified by the Protocol of 1978 (MARPOL) and the London Convention concerning 'dumping' versus 'discharges' during normal operations of ships in 2004, and subsequently established a Joint London Convention/MEPC Correspondence Group. The Contracting Parties to London Convention expressed their environmental concerns on the broad interpretation of the "cargo-associated wastes" by the States, which could be discharged by ships under MARPOL. Regulatory regimes for the cargo residues appear to vary among states. Some countries require fur ships to discharge their cargo wastes into the port reception facility and IMO also recommends doing so. This paper examines the related current national and international legal texts for the regulation of disposal of wastes from ships in order to analyze the current global concern on the marine pollution associated with waste discharge during operations of ships. In particular, we attempt to evaluate the likely marine environmental consequences arising from the disposal of cargo residue using an hypothetical case for the coal cargo residue among bulk cargos in this paper, since location, magnitude and frequency of the discharge of coal cargo residues into the sea adjacent to Korean Peninsula are not readily available. The cargo residues may be discharged to the sea according to MARPOL 73/78; however, its marine environmental consequences can be significant depending upon the characteristics and amounts of wastes to be discharged. Also the public tolerance of the environmental consequences would be widely different among nations. Multilateral environmental agreements, in general, more strictly apply their rules if there are other options to disposal at sea, i.e. port reception facility in this case. Therefore, port reception facilities for the wastes generated by ships are recommended to be further constructed in major national ports in order to reduce the risk of environmental damages during the operations of ships.

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