• Journal of the Korean Applied Science and Technology
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• v.34 no.1
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• pp.50-57
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• 2017

Zinc oxide is, one of metal oxide semiconductor, harmless to human and environment-friendly. It has excellent chemical and thermal stability properties. Wurtzite-zinc oxide is a large band gap energy of 3.37 eV and high exciton binding energy of 60 meV. It can be applied to various fields, such as solar cells, degradation of the dye waste, the gas sensor. The photocatalytic activity of zinc oxide is varied according to the particle shape and change of crystallinity. Therefore, It is very important to specify the additives and the experimental variables. In this study, the zinc oxide were synthesized by using a microwave assisted hydrothermal synthesis. The precursor was used as the zinc nitrate, the pH value was controlled as 11 by NaOH. Surfactants are the ethanolamine, cetyltrimethylammonium bromide, sodium dodecyl sulfate, sorbitan monooleate was added by changing the concentration. The composite particles had the shape of a star-like, curcular cone, seed shape, flake-sphere. Physical and chemical properties of the obtained zinc oxide was characterized using x-ray diffractometer, field emission scanning electron microscopy, thermogravimetric analysis and optical properties was characterized using UV-visible spectroscopy, photoluminescence and raman spectroscopy.

• Journal of Energy Engineering
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• v.17 no.1
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• pp.8-14
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• 2008

The effects of calcium type catalysts addition on the thermal decomposition of low density polyethylene (LDPE) and ethylene vinyl acetate (EVA) resin have been studied in a thermal analyze. (TGA, DSC) and a small batch reactor. The calcium type catalysts tested were calcinated dolomite, lime, and calcinated oyster shell. As the results of TGA experiments, pyrolysis starting temperature for LDPE varied in the range of $330{\sim}360^{\circ}C$ according to heating rate, but EVA resin had the 1st pyrolysis temperature range of $300{\sim}400^{\circ}C$ and the 2nd pyrolysis temperature range of $425{\sim}525^{\circ}C$. The calcinated dolomite enhanced the pyrolysis rate in LDPE pyrolysis reaction, while the calcium type catalysts reduced the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of calcium type catalysts reduced the melting point, but did not affect to the heat of fusin. Calcinated dolomite reduced 20% of the heat of pyrolysis reaction. In the batch system experiments, the mixing of calcinated dolomite and lime enhanced the yield of fuel oil, but did not affect to the distribution of carbon numbers.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.4019-4023
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• 2014

This study examined the effectiveness of ultrasound on enhancing the dewaterability and volume reduction of bio solids from a waste treatment plant. The test specimen was obtained from a storage tank immediately before the dewatering process at a local treatment plant. The test conditions included the energy levels of ultrasonic waves and treatment time. The tests were undertaken using three types of different treatment processors (7 liter, 1 ton, 7 ton container). The capillary suction time (CST) and the viscosity of sludge, which is one of the influencing factors for dewaterbility, were obtained under various test conditions. The results showed that ultrasound increases the CST of the raw specimens, whereas a significant reduction (20 % of the maximum value) of CST occurred in the sample with ultrasound and flocculent. The decrease in viscosity reached 40 % of the maximum value. A centrifugal test was performed to examine the characteristics of the sludge settlement. The settling rate and time required to reach the final values were both enhanced by the ultrasonic energy. An ultrasonic treatment is potentially useful tool for reducing the amount of released sludge. To examine the possible use of field application, the real scale sonic processor was designed and operated. The results were similar (50 % of the maximum value) to those of laboratory experiments.

• Journal of the Korean Society for Marine Environment & Energy
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• v.9 no.3
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• pp.154-159
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• 2006

It is essential to understand the decomposition characteristics for developing the optimum anaerobic digestion system of organic wastes. In this study, BMP (Biochemical Methane Potential) test using serum bottle was conducted to evaluate the anaerobic degradability of fish offal. 3 different groups of fish offal including waste from mackerel and hairtail handling except viscera and fish viscera were chosen for the substrates. Grinded fish offal was transferred anaerobically to serum bottle in amounts of 50 ml, 100 ml and 150 ml, respectively. BMP test was carried out in triplicate. Cumulative methane production and methane production rate depending on incubation time were evaluated. These results varied depending on substrate characteristics. The average values of ultimate methane yield ranged between $420ml{\cdot}CH_4/g{\cdot}VS$ and $490ml{\cdot}CH_4/g{\cdot}VS$, and the methane production and degradation rate of viscera were higher than those of other parts of fish offal. According to the analysis of elemental composition, average C/N ratio of fish offal used in this study was 5.2. Theoretical ultimate methane yield calculated from elemental composition was $522ml{\cdot}CH_4/g{\cdot}VS$. Biodegradability was calculated as 0.847.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.19 no.6
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• pp.581-585
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• 1986

A growth experiment of the Israeli strain of common carp (Cyprinus carpio) under varying dissolved oxygen levels in the recirculating water system was conducted at the Fish Culture Experiment Station of the National Fisheries University of Pusan from August 28, 1985 to September 17, 1985. Five tanks with a capacity of $5m^3$ of water each were used under the same condition of water parameters except for dissolved oxygen levels which were designed to maintain at 2.0, 2.5, 3.0, 3.5 and 4.0 mg/l ranges. The weight of fish in the beginning was about 300g and each tank was stocked with 200kg of fish. DO level of 3.5mg/l was found to be the best level with a feed coefficient of 1.57 and a daily growth rate of $1.411\%$ whereas 4.mg/l showed a slightly decreased performance of 1.63 and $1.365\%$ respectively. The amounts of feed consumed in 3.5 and 4.0mg/l DO levels were almost the same. Below 3.0mg/l DO levels the growth rate markedly decreased. Furthermore, in 2.0 and 2.5 mg/l groups, the fish did not accept feed vigorously and after feeding the fish usually concentrated around the inflow point showing oxygen deficiency response, The experiment indicates that the DO range of 3.5 to 4.0mg/l is the optimum level for the best growth at $27.5^{\circ}C$. DO concentration above these levels is considered a waste of energy resulting in uneconomical performance, and on the other hand, below these levels, the carp certainly shows a poor growth performance.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Journal of the Korean Society of Safety
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• v.27 no.2
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• pp.49-56
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• 2012

If cement can be manufactured with industrial byproducts such as granulated blast furnace slag, phosphogypsum, and waste lime instead of clinker, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by CO2 discharge, and reduction of the production cost. By this reason, in this study, mechanical behavior tests of non-burnt cement concrete were performed, and elasticity modulus and stress-strain relationship of non-burnt cement concrete were proposed. 6 test members were manufactured and tested according to reinforcement ratio and concrete compressive strength. By the test results, there was no difference between ordinary concrete and non-burnt cement concrete of flexural behavior. In order to verify the proposed non-burnt cement concrete model, nonlinear analytical model was derived by using strain compatibility method. By the results of comparison between test results, ordinary concrete model and proposed model, The proposed model well predicted the flexural behavior of non-burnt cement concrete.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.3
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• pp.172-177
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• 2014

Low pressure air flotation (LAF) pilot plant for sludge thickening was installed in Chung Nam N.S. municipal waste water treatment plant to verify its application possibility. Effects of operating conditions such as coagulant dosages and microbubble water ratio on thickening of the mixed sludge were examined. Microbubbles which were generated in the chamber of $1.5kgf/cm^2$ by high speed collision method with foaming agent were used to float sludge. Solid loading of $30kg/m^2/hr$, solid contents in thickened sludge of 60,300 mg/L and SS removal efficiency of 99% were obtained through long period operating LAF in conditions of mixed sludge concentration of 14,400 mg/L, coagulant dosage of 27.6 mg/L, foaming agent addition of 4.0 mg/L and microbubble water injection ratio of 9.7%.

• Journal of the Korea Institute of Building Construction
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• v.12 no.1
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• pp.115-121
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• 2012

If cement could be manufactured with industrial byproducts such as granulated blast furnace slag, phosphogypsum, and waste lime rather than clinker, there would be many advantages, including the maximization of the use of these industrial byproducts for high value-added resources, the conservation of natural resources and energy by omitting the use of clinker, the minimization of environmental pollution problems caused by $CO_2$ discharge, and the reduction of the production cost. For this reason, in this study, mechanical behavior tests of non-sintered cement concrete were performed, and elasticity modulus and stress-strain relationship of non-sintered cement concrete were proposed. Nine test members were manufactured and tested according to reinforcement ratio and concrete compressive strength. According to the test results, there was no difference between general cement concrete and non-sintered cement concrete in terms of flexure and shear behavior.

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.1
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• pp.115-123
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• 2005

In this study, life cycle assessment(LCA) technique was employed to evaluate the environmental impact of material recycling of polyethylene terephthalate(PET) bottle. Life cycle inventory was established based on the data collected from recycling companies in Korea. Simapro 5.0 LCA software and Eco-indicator 95 index were used for the analysis. The biggest impact by the material recycling of PET bottle on the environmental category was the global warming. It is because melting and production of the recycled PET product consume a significant amount of electricity and energy. In the environmental pollution discharge, $CO_2$ emission was the highest, followed by NOx. This is probably due to the use of diesel and gasoline in the consumption of electricity and transportation. All the environmental impact showed (-) value except the ozone layer depletion, which means that the material recycling of PET bottle is environmentally fair. The use of recycled PET product greatly reduced the environmental impact.