• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.11
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• pp.5551-5557
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• 2012

Sedimentary rocks dug up in construction fields are mostly stockpiled for landfill disposal, leading to an increase in construction costs and construction inefficiency. After screening, some of the sandstone can be used as aggregate; however, most of the shale ends up as industrial waste in practice. In this study, to stabilize the demand and develop resources for alternative aggregates of concrete, the potential use of shale, which is widely distributed in the Daegu-Kyeongbuk region, as a concrete aggregate was evaluated. Red and black shale exported from a Daegu excavation site was selected for use in the experiments and evaluated by comparing with hornfels, which is widely used as a coarse aggregate and is a type of andesite and metamorphosed sedimentary rock. The physical properties of the aggregate were evaluated in accordance with the test methods of KS F 2527 "crushed concrete aggregate," and the compressive strength against the shale aggregate replacement ratio was measured. The compressive strength of the concrete after 28 days was 30.8 MPa when the black shale replaced 100% of the aggregate in the concrete and 31.1 MPa when the red shale replaced 100% of the aggregate in the concrete. Compared with the compressive strength of 37.5 MPa for concrete prepared by using plain aggregate, using shale as a substitute for the aggregate produced an average compressive strength that was 82% of normal concrete.

• The Journal of Engineering Geology
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• v.13 no.1
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• pp.1-16
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• 2003

Geochemical characteristics of groundwater in the different kinds of various lithology such as Haman formation, Panyaweol formation, Jusan andesitic formation and Palgongsan granite is distinguished by mineralogical and chemical compositions. The Concentration of the majority of solutes in groundwaters of Haman and Panyaweol formation is higher than in that of andesite and granite. Higher concentration of $HCO_3^{-}{\;}and{\;}SO_4^{2-}$ anions in the groundwater is peculiar. High concentrations of $Ca^{2+},{\;}Mg^{2+},{\;}HCO_3^{-}$ in the groundwaters of the sedimentary rocks result mainly from reaction of $CO^{2-}$ charged water with calcite and weathered feldspars. With the Piper diagram, the groundwaters of Haman formations are mainly plotted in $CaSO_4-CaCl_2$ type, whereas those of Panyaweol formations are plotted in the bothside of $Ca(HCO_3)_2{\;}and{\;}CaSO_4-CaCl_2$ type. Thses two different types of $Ca(HCO_3)_2{\;}and{\;}CaSO_4-CaCl_2$ groundwater were originated from dissolution of calcite($Ca(HCO_3)_2)$ and the oxidation of pyrite($CaSO_4-CaCl_2$), respectively. And it also is influenced by anthropogenic contamination. Three factors were extracted from the factor analysis for chemical data. Factor 1, controlled by $SO_4^{2-},{\;}Na^{+},{\;}Ca^{2+}$ and Fe, explains the dissolution of calcite, plagioclase and oxidation of pyrite. Factor 2, controlled by $HCO_3^{-}{\;}and{\;}Mg^{2+}$, mainly explains the dissolution of Mg-carbonates and dolomitization. Factor 3, controlled by $Cl^{-},{\;}K^{+}{\;}and{\;}NO_3^{-}$, is subject to the influence of artificial pollution including industrial waste water disposal. In this study area, some industrial complex which is close to Keumho river show the higher score of factor 3.

• The Journal of Engineering Geology
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• v.27 no.4
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• pp.489-500
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• 2017

It is not rare that pseudotachylite, dark colored rock with glassy texture, is recognizable in deep core samples drilled up to 900 m from the surface. Pseudotachylite with widths varying few to 20 cm is sharply contacted or interlayered with the host rocks composed of Jurassic granite and Precambrian amphibolite gneiss, showing moderately ductile deformation or slight folding. Pseudotachylite occurring at varying depths in the deep drill core are slightly different in texture and thickness. There is evidence of fault gouge at shallower depths, although brittle deformation is pervasive in most drill cores and pseudotachylite is identified at random depth intervals. Under scanning electron microscope (SEM), it is evident that the surface of pseudotachylite is characterized by a smooth, glassy matrix even at micrometer scale and there is little residual fragments in the glass matrix except microcrystals of quartz with embayed shape. Such textural evidence strongly supports the idea that the pseudotachylite was generated through the friction melting related to strong seismic events. Based on X-ray diffraction (XRD) quantitative analysis, it consists of primary minerals such as quartz, feldspars, biotite, amphibole and secondary minerals including clay minerals, calcite and glassy materials. Such mineralogical features of fractured materials including pseudotachylite indicate that the fractured zone might form at low temperatures possibly below $300^{\circ}C$, which implies that the seismic activity related to the formation of pseudotachylite took place at shallow depths, possibly at most 10 km. Identification and characterization of pseudotachylite provide insight into a better understanding of the paleoseismic activity of deep grounds and fundamental information on the stability of candidate disposal sites for high-level radioactive waste.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.4
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• pp.199-211
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• 1997

As a part of study on geological disposal of radioactive waste, hydrogeochemical characteristics of deep granitic groundwater in Korea were investigated through the construction of a large geochemical dataset of natural water, the examination on the behaviour of dissolved constituents, and the consideration of phase stability based on thermodynamic approach. In granitic region, the contents of total dissolved solids increase progressively from surface waters to deep groundwaters, which indicates the presence of more concentrated waters at depth due to water-rock interaction. The chemical composition of groundwater evolves from initial $Ca^{2＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) or $Ca^{2＋}$-HC $O_3$$^{－}$ type to final N $a^{＋}$-HC $O_3$$^{－}$ or N $a^{＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) type, via $Ca^{2＋}$-HC $O_3$$^{－}$ type. Three main mechanisms seem to control the chemical composition of groundwater in the granitic region; 1) congruent dissolution of calcite at shallower depth, 2) calcite precipitation and incongruent dissolution of plagioclase at deeper depth, and 3) kaolinite-smectite or/and kaolinite-illite reaction at equilibrium at deeper depth. The behaviour of dissolved major cations (C $a^{2＋}$, $K^{＋}$, $Mg^{2＋}$, M $a^{＋}$) and silica is likely to be controlled by these reactions.

• The Journal of Engineering Geology
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• v.26 no.3
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• pp.307-314
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• 2016

Shear characteristics of soils can be investigated using various types of shear stress measuring apparatus. Ring shear tests are often applied for examining the residual shear strength under the unlimited deformation. This paper presents drainage-consolidation-shear velocity dependent undrained shear strengths measured in terms of water leakage. A series of ring shear tests were performed under the constant normal stress (50 kPa) and controled shear velocity ranging from 0.01~1 mm/sec under the undrained condition. As a result, undrained shear strengths are dependent on shear velocity. It exhibits that straining hardening behavior is observed for the shear velocity lower than 0.1 mm/sec; however, the strain softening behavior is observed for the shear velocity higher than 0.1 mm/sec. Water leakage can cause the increase in shear stress irrespective of shear velocity. Shear stress increases with increasing amount of water leakage. It is due to the fact that the small grains and water flow out through the rubble edge in the ring shear box. Repetitive saturation and consolidation processes may minimize the error.

• Economic and Environmental Geology
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• v.38 no.3 s.172
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• pp.237-245
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• 2005

The batch tests were performed to evaluate the applicability of the permeable reactive barrier (PRB) to in-situ treatment of groundwater with high concentration of heavy metals. The lead\chates used in this study were collected from waste rock dump of the Imgy mine, and have a low pH and high metal concentration. The acidity loading was 65kg as $CaCO_3/day$, metal loading of Fe+Al+Mn was 11.6kg/day. This type of water could be treated with biological-mediated sulfate reduction using the organic carbon mixture as a reactive media. The batch tests were carried out with five mixtures that were composed with different mixing ratios of mushroom compost, pine-tree bark, and limestone cheep. Results indicated that the PRB could reduce the acidity loading $CaCO_3/day$ to 12.3kg and reduce the metal loading to 3.3kg/day. Considering about the low pH and high metal loading, the contaminated water may be ameliorated by passing it through the buffering PRB composed with inorganic carbonate materials and then through the PRB composed with the organic carbon mixture which can induce sulfate reduction.

• Journal of Korea Water Resources Association
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• v.40 no.6 s.179
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• pp.469-483
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• 2007

Nitrate and chloride are the most common contaminants in groundwater and their concentrations increase easily due to fertilizer consumption and urbanization. The number of time series data for groundwater quality at a single site was not sufficient to analyze trends on Jeju Island. Therefore rectangle grids were drawn for the whole island and single grid was determined to be $500m{\times}500m$ after considering similar stream density, homogeneous hydraulic coefficients, geologic features of volcanic rock and low topographic slopes. All data within each lattice were collected and arranged in time series order and analyzed using Sen's method. 10.6 % of the total lattices for chloride and 22.4% for nitrate showed upward trends from the early 1990's to the early 2000's. Especially, upward trends for nitrate concentration are distinct in the low mid-mountainous areas of western and southern watersheds. Many septic tanks and much domestic waste from the urbanization of the low mid-mountainous area have produced this upward trend. Additionally, the agricultural region has dramatically increased since the 1990's and this has led to an increase of fertilizer consumption and, as a result, nitrate concentration. Therefore, the target of any management plan for groundwater quality on Jeiu Island needs to be focused on careful land use decisions in the mid-mountainous areas which are near Halla Mountain.

• Economic and Environmental Geology
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• v.23 no.4
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• pp.425-452
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• 1990

A tentative hydrogeologic and hydrodispersive study was carried out to evaluate the groundwater pollution potential at a selected site by utilizing empirical assessment methodologies in an advanced stage of quantitative computer aided assessment. The upper most aquifer is defind as saturated overburden and weathered zone including the upper part of highly fractured rock. Representative hydraulic conductivity and storativity of the uppermost aquifer are estimated at 2.88 E-6 m/s and 0.09, respectively. Also calculated Darcian and average linear velocity of groundwater along the major pathway are 0.011 m/d and 0.12 m/d with average hydraulic gradient of 4.6% in the site. The results of empirical assessment methodologies indicate that 1) DRASTIC depicts that the site is situated on non-sensitive and non-vulnerable area. 2) Legrand numerical rating system shows that the probability of contamination and degree of acceptability are classed to "Maybe-Improbable, and Probable Acceptable and Marginally Unacceptable" with situation grade of "B". 3)Waste soil-site interaction matrix assessment categorizes that the study site is located on "Class-8 Site".

• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.347-356
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• 2010

Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.451-462
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• 2005

In order to examine the extent of environmental contamination at abandoned Samsanjeil Cu mines in Kosung-kun, Kyeongsangnam-do, we have investigated the contaminations and mobility of toxic trace elements from mine wastes including about 280,000 tonnages of tailings by chemical experiments (total extraction, partial extraction by 0.1N HCI and sequential extraction procedure). Total concentrations of trace elements showed that Cu, As, Co, Zn, Pb, and Cd concentrations in tailings were 14.0, 3.6, 3.1, 2.1, 2.1 and 1.6 times greater than those in background soil, respectively. From the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals decrease in order of $Zn(29.0\%)>Cu(12.3\%)Pb(9.6\%)>Cd(3.0\%)>As=Co(0.0\%)$. Based on the concentrations, chemical speciations of tailings, waste rock and nearby soil, it was revealed that Cu and Zn were the most possible elements to contaminate the surrounding environment in Samsanjeil mine area. In addition, the tailings had total trace metal concentrations below Dutch guideline values except Cu, and they might not affect adverse impact on environment.