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Production of Fine ZnO Powders by Carbothermal Reduction

  • Choi, Heon-Jin;Lee, June-Gunn;Jung, Kwang-Taik;Kim, Ki-Hwan
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.304-310
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    • 1998
  • Carbothermal reduction has been one of the important processes for the production of ceramic raw materials such as silicon carbide, silicon nitride, boron carbide, etc. The process has also been one of several trials for the recovery of ZnO from ZnO-containing waste. It usually involves two consecutive steps: the evolution of Zn vapor and its oxidation with air. In this study a ZnO-containing raw material is reduced by carbon at $1250^{\circ}C$ and the evolved Zn vapor is oxidized with air, resulting in fine powders of ZnO. computer programs, THERMO and PYROSIM developed by MINTEK, are used to simulate the process thermodynamically and the results are compared with the experimental results. It is shown that the ZnO-containing raw material can be reduced and can form fine ZnO with the yield as high as 98.7% under a proper condition. Based on these results, a process is engineered for the production of ZnO in a rotary kiln at a rate of 3 tons/day. The produced ZnO powders show properties suitable to the usual applications in ceramic industries with a purity of > 95wt% and an average particle size of ∼3${\mu}m$.

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Corrosion of Copper in Anoxic Ground Water in the Presence of SRB

  • Carpen, L.;Rajala, P.;Bomberg, M.
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.147-153
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    • 2018
  • Copper is used in various applications in environments favoring and enabling formation of biofilms by naturally occurring microbes. Copper is also the chosen corrosion barrier for nuclear waste in Finland. The copper canisters should have lifetimes of 100,000 years. Copper is commonly considered to be resistant to corrosion in oxygen-free water. This is an important argument for using copper as a corrosion protection in the planned canisters for spent nuclear-fuel encapsulation. However, microbial biofilm formation on metal surfaces can increase corrosion in various conditions and provide conditions where corrosion would not otherwise occur. Microbes can alter pH and redox potential, excrete corrosion-inducing metabolites, directly or indirectly reduce or oxidize the corrosion products, and form biofilms that create corrosive microenvironments. Microbial metabolites are known to initiate, facilitate, or accelerate general or localized corrosion, galvanic corrosion, and intergranular corrosion, as well as enable stress-corrosion cracking. Sulfate-reducing bacteria (SRB) are present in the repository environment. Sulfide is known to be a corrosive agent for copper. Here we show results from corrosion of copper in anoxic simulated ground water in the presence of SRB enriched from the planned disposal site.

The Sustainable Green Fashion Marketing Strategies according to Classification of Green Fashion Marketing of Domestic Fashion Companies (국내 패션 업체의 그린 마케팅 유형 분류를 통한 지속가능한 그린 패션 마케팅 전략)

  • Shin, Su-Yun;Hong, Jung-Min
    • The Research Journal of the Costume Culture
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    • v.18 no.5
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    • pp.872-891
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    • 2010
  • This study was an exploratory research to classify the types of green fashion marketing of the fashion companies in South Korea and analyse the present cases of each type. To analyse the current cases of green fashion marketing strategies, we researched all sorts of newspapers, magazines, publications of fashion companies, and web sites from 2008 to 2009. As a result, we categorized 5 types of green fashion marketing as follows ; eco-friendly fabrics (natural fabrics, recycled fabrics, biodegradable fabrics), re-use or re-form(reuse after cleaning and/or repairing and reformation through transformation and combination of raw materials), green certifications(ISO 14001, GOTS, OES, etc.), eco-friendly management and operation, and green marketing promotions. Based on the results, we proposed the green marketing strategies for fashion companies to progress toward the proper direction of green marketing. First of all, companies should escape from the narrow view point limited to the product itself. Then they have to focus on developing and execution of sustainable merchandising, manufacturing, logistics, and waste strategies.

Performance Analysis of Ammonia-Water Regenerative Rankine Cycles for Use of Low-Temperature Energy Source (저온 열원 활용을 위한 암모니아-물 재생 랭킨 사이클의 성능 해석)

  • Kim, Kyoung-Hoon;Han, Chul-Ho
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.15-22
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    • 2011
  • It is a great interest to convert more energy in the heat source into the power and to improve the efficiency of power generating processes. Since the efficiency of power generating processes becomes poorer as the temperature of the source decreases, to use an ammonia-water mixture instead of water as working fluid is a possible way to improve the efficiency of the system. In this work performance of ammonia-water regenerative Rankine cycle is investigated for the purpose of extracting maximum power from low-temperature waste heat in the form of sensible energy. Special attention is paid to the effect of system parameters such as mass fraction of ammonia and turbine inlet pressure on the characteristics of system. Results show that the power output increases with the mass fraction of ammonia in the mixture, however workable range of the mass fraction becomes narrower as turbine inlet pressure increases and is able to reach 16.5kW per unit mass flow rate of source air at $180^{\circ}C$.

POLYCHLORINATED NAPHTHALENE (PCN) AND DIBENZOFURAN (PCDF) CONGENER PATTERNS FROM PHENOL PRECURSORS IN THERMAL PROCESS: [II] EXPERIMENTAL RESULTS FROM DICHLOROPHENOLS (DCPs)

  • Ryu, Jae-Yong;Kim, Do-Hyong;Choi, Kum-Chan;Suh, Jeong-Min
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.232-240
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    • 2006
  • Polychlorinated naphthalenes (PCNs) formed along with dibenzo-p-dioxin and dibenzofuran products in the slow combustion of dichlorophenols (DCPs) at $600^{\circ}C$ were identified. Each DCP reactant produced a unique set of PCN products. Major PCN congeners observed in the experiments were consistent with products predicted from a mechanism involving an intermediate formed by ortho-ortho carbon coupling of phenoxy radicals; polychlorinated dibenzofurans (PCDFs) are formed from the same interemediate. Tautomerization of the intermediate and $H_2O$ elimination produces PCDFs; alternatively, CO elimination to form dihydrofulvalene and fusion produces naphthalenes. Only trace amounts of tetrachloronaphthalene congeners were formed, suggesting that the preferred PCN formation pathways from chlorinated phenols involve loss of chlorine. 3,4-DCP produced the largest yields of PCDF and PCN products with two or more chlorine substituents. 2,6-DCP did not produce tri- or tetra-chlorinated PCDF or PCN congeners. It did produce 1,8-DCN, however, which could not be explained.

An Application of Affective-Cognitive Ambivalence Theory in Environmental Risk Attitude: The Case Study of Marion County, Ohio in the U.S.

  • Lee, Jae-Young;Lee, Hyon-Yong;Fortner, Rosanne W.
    • Journal of the Korean earth science society
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    • v.28 no.5
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    • pp.635-642
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    • 2007
  • Using data from 132 telephone interviewees, we examined the role of affective-cognitive ambivalence in forming overall attitude and behavior toward toxic chemical and radioactive waste issues in Marion, Ohio in the U.S. In order to compare attitudinal preference, participants were divided into four A-C groups: action-group (Affective+/Cognitive+), detached-group (A-/C+), concerned-group (A+/C-), and inaction-group (A-/C-). Affective and cognitive components interacted, producing redundant influences on overall attitudes and judgments as frequently observed and postulated in previous attitude studies. The results showed that the action-group who were feeling unsafe and believed that environmental accidents had happened or are happening in Marion were less willing to move to the area than other three groups who were feeling safe and/or doubted reports of contamination and its relation with leukemia. Affective and cognitive components were found to have redundant influences on overall attitude. It was also observed that affective-cognitive ambivalence theory has a great potential for explaining the mechanism by which people form attitudes, especially when people have moderate or positive feelings (e.g. sympathy or eagerness for resources) toward the objects and/or when uncertainty is a major feature of environmental issue under consideration (e.g. global climate change).

Strength Properties of Non-cement Matrix by Using Recycled Aggregates and Sludge from Ready-Mixed Concrete (레미콘의 슬러지 고형분과 회수골재를 사용한 무시멘트 경화체의 강도특성)

  • Ryu, Dong-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.477-482
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    • 2016
  • This study investigates the expressions characteristics of compression strength depending on the condition of fresh concrete and cured concrete by producing Non-cement mortar and concrete only with solidified sludge in the dehydrated cake form, recycled concrete and premixed materials(BS, FA) in order to actively use remicon recycling water as resources, rather than as construction waste material. After treating wastewater of pH 12.5 or more with alkali activator and after promoting BS hydration reaction, the amount of BS inflow was found to be increased and compression strength was increased accordingly: these results coincide with the analysis results of TG-DTA and SEM.

Study on prestressed concrete beams and poles with cement replaced by steel dust

  • Sujitha Magdalene, P;Harishankar, S
    • Advances in concrete construction
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    • v.5 no.4
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    • pp.391-405
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    • 2017
  • Cement acts as the most important component of concrete as it binds and holds the concrete together. But it is one of the major $CO_2$ emitters all over the world, during manufacturing (900 kg of $CO_2$ per 1000 kg). Some of the modern construction methods aim at reducing the amount of usage of cement and came out with numerous solutions for replacement of the same. One such supplement in current trend is the Steel dust or the Electric Arc Furnace Dust (EAFD), which is a waste product from the electric arc furnace when the scrap metal is melted. When the concrete containing steel dust is exposed to atmosphere, the environmental oxygen and moisture play role to form rust and ultimately the member becomes harder. As Cement is the binder of conventional concrete, only certain percentage of the same could be replaced by the new material, steel dust. Tests were conducted for the 28 days cube strength of M45 grade (suitable for prestressing) concrete which has 0%, 10%, 20%, 30%, 40% and 50% steel dust instead cement. From the test, the optimum percentage replacement of steel dust was obtained, for which the beams and overhead poles were cast, prestressed and tested for the failure load and deflections. A conventional concrete beam and overhead pole were also cast, prestressed and tested to compare the results with those of the beam and pole that contained steel dust. The load vs. deflection plot and other results from the test is also discussed.

A Study of Up-cycling in 21st Century Fashion Art (21세기 패션아트에 나타난 업 사이클링에 관한 연구)

  • Kim, Sun-Young
    • The Research Journal of the Costume Culture
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    • v.20 no.3
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    • pp.295-308
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    • 2012
  • This study intends to analyze the up-cycling trend that is attracting great attention these days and its internal meaning in the context of fashion art. And, based on this, to provide enhanced value and creativity in the future fashion artwork and design businesses, keeping abreast of further fashion art developments. As part of the study methodology, both a literature review and a case study were carried out, along with an examination of up-cycling and research into related pictures and content. The materials covered in this work include design and fashion related books and domestic and foreign magazines from 2000 to 2011, when the up-cycling movement was initiated as a form of eco-friendly design. For the analysis of fashion art pieces, generic terms included art wear, wearable art wear, and unwearable art. Case review was followed by the works of artists shaping their fashion concept and meaning entirely from abandoned clothes and fabrics, waste materials, and their art collection. Consequently, key elements of the value of up-cycling fashion art are that it is eco-friendly, has a unique identity, and reflects multi-dimensionalism. This research saw the integration of fashion with other variables, artistic attributes, and reuse of resources. This could lead to a new realm where value-addition is formed and extended, thus providing another chance for the fashion industry.

Role of membranes in bioelectrochemical systems

  • Kokabian, Bahareh;Gude, Veera Gnaneswar
    • Membrane and Water Treatment
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    • v.6 no.1
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    • pp.53-75
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    • 2015
  • This paper provides an overview of the role of membranes in bioelectrochemical systems (BESs). Bioelectrochemical systems harvest clean energy from waste organic sources by employing indigenous exoelectrogenic bacteria. This energy is extracted in the form of bioelectricity or valuable biofuels such as ethanol, methane, hydrogen, and hydrogen peroxide. Various types of membranes were applied in these systems, the most common membrane being the cation exchange membrane. In this paper, we discuss three major bioelectrochemical technology research areas namely microbial fuel cells (MFCs), microbial electrolysis cells (MECs) and microbial desalination cells (MDCs). The operation principles of these BESs, role of membranes in these systems and various factors that affect their performance and economics are discussed in detail. Among the three technologies, the MFCs may be functional with or without membranes as separators while the MECs and MDCs require membrane separators. The preliminary economic analysis shows that the capital and operational costs for BESs will significantly decrease in the future due mainly to differences in membrane costs. Currently, MECs appear to be cost-competitive and energy-yielding technology followed by MFCs. Future research endeavors should focus on maximizing the process benefits while simultaneously minimizing the membrane costs related to fouling, maintenance and replacement.