• Title/Summary/Keyword: Waste Polypropylene

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Effects of the Recycled Waste Rope Fibers on the Strength and Carbonation Resistance of Cementitious Composites (폐로프 재활용 섬유보강 시멘트 복합체의 탄산화가 강도에 미치는 영향)

  • Sanghwan Cho;Taek Hee Han;Min Ook Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.407-415
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    • 2023
  • In this study, a carbonation test was conducted on cementitious composites reinforced with recycled waste rope fibers (W series) according to EN 12390-12 standards. The test results were compared to those of commercially available polypropylene fibers (P series). In the carbonation test, both the carbonation depth and area were significantly influenced by the water-to-cement ratio. Notably, the carbonation resistance performance of cementitious composites containing waste rope fibers surpassed that of commercially available PP fibers under equivalent conditions. Throughout the 250-day test period, the W series exhibited higher compressive strength values than the P series, while both series displayed a similar trend of strength increase during the same duration. During the initial stage, the W series exhibited flexural strength levels similar to those of the P series. However, in the later stages, the P series showed a higher mean flexural strength by 1.0 MPa.

Quality Changes of Brined Baechu Cabbage Prepared with Low Temperature Stored Baechu Cabbages (저온 저장 생배추를 이용하여 제조한 절임배추의 저장기간 중 품질 특성의 변화)

  • Jeong, Ji-Kang;Park, So-Eun;Lee, Sun-Mi;Choi, Hye-Sun;Kim, So-Hee;Park, Kun-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.3
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    • pp.475-479
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    • 2011
  • Although the storage period of raw baechu cabbage could be 2 months at $0{\sim}2^{\circ}C$, 1 month was appropriate considering the quality of the baechu cabbage, waste ratio, and storage cost. The polyethylene container was the most efficient storage container among polypropylene box, polypropylene net and polyethylene container. pH of a brined baechu cabbage using raw baechu cabbage was 4.0~4.3 after 8 weeks and its total bacteria and lactic acid bacteria counts were $10^7$ cfu/g, and textural property (springiness) lower than 50% was at 8th week of storage at $0{\sim}2^{\circ}C$ and thus its storage period was limited to 8 weeks. When brined baechu cabbage was prepared by raw baechu cabbage stored for 1 month at $0{\sim}2^{\circ}C$, its pH, microorganism counts and springiness showed similar trends to the brined cabbage using raw baechu stored for 0 month. However, its rates of change were faster than the brined baechu cabbage using the raw baechu, and the storage period was limited to 6 weeks. Brined baechu cabbage using the raw cabbage stored for 2 months and its storage period was limited by about 4 weeks judging by its indicated quality characteristics.

A Study on Catalytic Pyrolysis of Polypropylene with Mn/sand (Mn/sand 촉매를 활용한 폴리프로필렌 촉매 열분해 연구)

  • Soo Hyun Kim;Seung Hun Baek;Roosse Lee;Sang Jun Park;Jung Min Sohn
    • Clean Technology
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    • v.29 no.3
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    • pp.185-192
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    • 2023
  • This study was conducted to obtain basic process simulation data before conducting pyrolysis experiments for the development of a thermochemical conversion system by recirculation of heat carrier and gases thereby. In this study, polypropylene (PP) was used as a pyrolysis sample material as an alternative to waste plastics, and fluid sand was used as a heat transfer medium in the system. Manganese (Mn) was chosen as the catalyst for the pyrolysis experiment, and the catalyst pyrolysis was performed by impregnating it in the sand. The basic properties of PP were analyzed using a thermogravimetric analyzer (TGA), and liquid oil was generated through catalytic pyrolysis under a nitrogen atmosphere at 600℃. The carbon number distribution of the generated liquid oil was confirmed by GC/MS analysis. In this study, the effects of the presence and the amount of Mn loading on the yield of liquid oil and the distribution of hydrocarbons in the oil were investigated. When Mn/sand was used, the residue decreased and the oil yield increased compared to pyrolysis using sand alone. In addition, as the Mn loading increased, the ratio of C6~C9 range gasoline in the liquid oil gradually increased, and the distribution of diesel and heavy oil with more carbon atoms than C10 in the oil decreased. In conclusion, it was found that using Mn as a catalyst and changing the amount of Mn could increase the yield of liquid oil and increase the gasoline ratio in the product.

Effects of Ultrasonic Treatment and Particle Size on Mechanical Properties of Waste Polypropylene/WGRT Composites (초음파 처리와 분말 크기가 재생 폴리프로필렌/폐타이어 분말 복합체의 기계적 특성에 미치는 영향)

  • Kim, Donghak;Kim, Seonggil;Lee, Minji;Park, Jong-Moon;Oh, Myung-Hoon;Kim, Bong-Suk;Kim, Jinkuk;Bang, Daesuk
    • Resources Recycling
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    • v.24 no.2
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    • pp.36-45
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    • 2015
  • In this study, various sizes of waste ground rubber tire (WGRT) were devulcanized by a single screw extruder equipped with a sonicator in front of the die, and waste PP and devulcanized waste ground rubber tire (DWGRT) composites were prepared by an intermeshing co-rotating twin screw extruder. The crosslink density and percent devulcanization of WGRT and DWGRT for 40, 80 and 140 meshes were calculated. The mechanical properties of the composites were compared with each other. The effect of SEBS-g-MA as a compatibilizer was investigated on mechanical properties of both waste PP/WGRT and waste PP/DWGRT composites. The crosslink density was decreased with decreasing the WGRT size. On the other hand, the percent devulcanization was increased by adding the smaller size of WGRT. Also, tensile strength, impact strength and elongation at break of the composite with DWGRT were higher than those with WGRT. Especially, mechanical properties of the composites were significantly increased by adding the smaller size of WGRT and DWGRT. Addition of SEBS-g-MA into both waste PP/(D)WGRT composites exhibited better impact strength and elongation at break than the composites themselves.

Analysis of VOCs Produced from Incineration of Plastic Wastes Using a Small- Electric Furnace (소형전기로를 이용한 플라스틱류 소각시 발생하는 VOCs 농도분석)

  • Lee Byeong-Kyu;Kim Haengah
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.759-771
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    • 2004
  • This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of plastic wastes at $600^{\circ}C$. The plastic wastes used in this study included polyethyleneterephthlate (PETE), high density polyethylene (HOPE), polyvinyl chloride (PVC), low density polyethylene (LOPE), polypropylene (PP), polystyrene (PS) and other. Plastic wastes were heated from room temperature upto $600^{\circ}C$ providing the compressed air inside of a small-scale electric furnace for 90 minutes and then they were oxidized (incinerated) for 60 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and Tedlar air bags for 150 minutes and then the components and concentrations of the VOCs were analyzed by a GC-MS. The most prominent chemical structure of the VOCs obtained from the incineration process of the HOPE, LOPE and PP, which include ethylene groups in their main chains, was identified as aliphatic hydrocarbons such as 1-hexene. However, aromatics such as benzene were major chemical structure from the incineration of PETE, PVC and PS which include benzene rings in their main chains. This study estimated the total VOC production from the incineration of the plastic wastes based on the real plastic waste production and the emission factors. 64% and 27% of the total VOC emissions consisted of aliphatic hydrocarbons and aromatics, respectively, which have double bonds within their molecular structure and thus a high ground level ozone formation potential.

A Theoretical Consideration about Effects of Radiation on the Physical Properties of PP (PP 재질의 물성에 미치는 방사선의 영향에 대한 이론적 고찰)

  • 김문수;강덕원;엄희문
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.517-523
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    • 2003
  • The physical properties of polypropylene (PP) membranes under the radiation field were investigated. To calculate radiation flux affecting to PP, it was used MCNP4A Code. The PP membrane and deoxygenation equipment were standardized to bar structure in order to calculate the phonton flux with MCNP4A Code. The change in the properties of the PP membrane to be used in deoxygenation equipment was rarely occurred during the usage work because the radiation level of reactor coolant water was very low level and The doses of radiation workers are very low. From the results, it was found that the Physical properties of PP membranes which used for nuclear power plant reactor coolant water disposal were not rarely changed under the simulated radiation field.

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Studies on the Performance of Self Healing of Plastic Cracks Using Natural Fibers in Concrete

  • Saraswathy, Velu;Kwon, Seung-Jun;Karthick, Subbiah
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.115-127
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    • 2014
  • Addition of fibers in cement or cement concrete may be of current interest, but this is not a new idea or concept. Fibers of any material and shape play an important role in improving the strength and deformation characteristics of the cement matrix in which they are incorporated. The new concept and technology reveal that the engineering advantages of adding fibers in concrete may improve the fracture toughness, fatigue resistance, impact resistance, flexural strength, compressive strength, thermal crack resistance, rebound loss, and so on. The magnitude of the improvement depends upon both the amount and the type of fibers used. In this paper, locally available waste fibers such as coir fibers, sisal fibers and polypropylene fibers have incorporated in concrete with varying percentages and l/d ratio and their effect on compressive, split, flexural, bond and impact resistance have been reported.

Study on the Functionalization of Waste EPDM and PP Blend

  • Chung, Kyungho;Kim, Jinhee
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.245-250
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    • 2015
  • Recycling of ethylene-propylene-diene terpolymer (EPDM) scrap was tried by blending with polypropylene (PP). EPDM scrap powder was prepared by shear pulverization process at high temperature, which may lead to selective chain scission induced by difference in the critical elastic coefficient. On the other hand, EPDM scrap powder was prepared by adding a selected reclaiming agent during shear pulverization process at high temperature. Terpene as a bonding agent was then introduced to improve adhesion property. PP, used as a matrix for manufacturing thermoplastic elastomer, was modified by the incorporation of dicumyl peroxide and maleic anhydride. The functionalized EPDM and modified PP were blended and cured dynamically at $190^{\circ}C$. The blend materials prepared in this study showed the comparable results to those of conventional TPE in terms of tensile and flow properties. Also, the odor component of recycled EPDM was analyzed using GC-MS.

Biodegradation of PPC-PVL and PVL by Stenotrophomonas maltophilia (Stenotrophomonas maltophilia에 의한 PPC-PVL과 PVL의 분해)

  • Park Suk Kyoung;Ju Hyun;Cho Sung Ki;Kim Donguk;Oh Kwang Joong;Ree Moonhor
    • KSBB Journal
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    • v.20 no.1 s.90
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    • pp.18-20
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    • 2005
  • Polypropylene carbonate-polyvalerolactone(PPC-PVL) and polyvalerolactone (PVL) produced from exhausted carbon dioxide were degraded by Stenotrophomonas maltophilia separated from soils of waste landfill. The biodegradation was confirmed by FTIR spectrum. PPC-PVL and PVL were degraded $6.6\%,\;12\%$ respectively, at 28 days of pure Stenotrophomonas maltophilia culture.

Development of Triboelectrostatic Separation Technique for Material Separation of EVA & PET Mixture Plastic Wastes (EVA와 PET 혼합(混合) 폐플라스틱의 재질분리(材質分離)를 위한 마찰하전형(摩擦荷電形) 정전선별(靜電選別) 기술개발(技術開發))

  • Jeon, Ho-Seok;Park, Chul-Hyun;Baek, Sang-Ho;Kim, Byoung-Gon;Kim, Hyung-Seok
    • Resources Recycling
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    • v.18 no.1
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    • pp.13-21
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    • 2009
  • A research on material separation of EVA and PET mixture plastic waste using a triboelectrostatic separator has been carried out. It was found that PP was the best charging material to give the highest charge on the surface of EVA and PET mixture plastics with an opposite polarity. Therefore, a charger of pipe line type using PP material was manufactured for separation of EVA and PET mixture plastic waste. At optimum test conditions that used PP cyclone charger developed in this study, we could separate out PET with a glade of 98.7% and a recovery of 89.7%.