• 한국지반환경공학회 논문집
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• 제16권5호
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• pp.27-33
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• 2015

정수공정 중에 응집된 망간은 슬러지 농축조에 체류하는 동안 재용출 되어 배출수의 망간 허용기준치를 초과하는 문제가 발생되고 있다. 본 연구에서는 정수공정 중에 슬러지 농축조 배출수의 pH를 조정함으로써 망간 농도에 미치는 pH의 영향에 대하여 연구하였다. 초기 pH 6.1에서는 응집된 슬러지로부터 망간이 재용출 되어 청정지역 배출 기준인 2mg/L를 초과하였으나 NaOH, KOH, CaO, $Ca(OH)_2$, $CaCO_3$ 등 알칼리 물질을 이용하여 pH를 상승시켰을 경우 망간 농도를 청정지역 배출 기준 이하로 낮출 수 있었다. 또한 알칼리성 물질로서 석회석 광산에서 선별과정 중 발생하는 폐석회석을 이용하여 정수장 슬러지의 망간 재용출을 억제할 수 있는 가능성을 확인하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 INTERNATIONAL SYMPOSIUM ON SOIL & GROUNDWATER ENVIRONMENT
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• pp.59-61
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• 2005

In Korea, hundreds of abandoned and closed coal and metallic mines are present in the steep mountain valleys due to the depression of the mining industry since the late 1980s. From these mines, enormous amounts of coal waste were dumped on the slopes, which causes sedimentation and acid mine drainage (AMD) to be discharged directly into streams causing detrimental effects on soil and water environments. A limestone slurry by-product (lime cake) is produced from the Solvay process in manufacturing soda ash. It has very fine particles, low hydraulic conductivities ($10^{-8}{\sim}10^{-9}cm/sec$), high pH, high EC due to the presence of CaO, MgO and $CaCl_2$ as major components, and traces of heavy metals. Due to these properties, it has potential to be used as a neutralizer for acid-producing materials. A field plot experiment was used to test the application of lime cake for reclaiming coal wastes. Each plot was 20 x 5 m (L x W) in size on a 56% slope. Treatments included a control (waste only), calcite ($CaCO_3$), and lime cake. The lime requirement (LR) for the coal waste to pH 7.0 was determined and treatments consisted of adding 100%, 50%, and 25% of the LR. The lime cake and calcite were also applied in either a layer between the coal waste and topsoil or mixed into the topsoil and coal waste. Each plot was hydroseeded with grasses and planted with trees. In each plot, surface runoff and subsurface water were collected. The lime cake treatments increased the pH of coal waste from 3.5 to 6, and neutralized the pH of the runoff and leachate of the coal waste from 4.3 to 6.7.

• 한국건축시공학회지
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• 제14권3호
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• pp.237-243
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• 2014

지구온난화 현상으로 인해 환경 문제가 심각하며, 또한, 시멘트의 원료인 석회석과 골재의 무분별한 채취로 인한 환경파괴와 자원고갈의 심각성이 강조되고 있는 상황에서 문제점을 줄이려는 노력이 지속되고 있는 실정이다. 따라서, 본 연구에서는 천연골재 대체재인 폐자기를 혼합하여 적용시켰다. 또한, 시멘트 대체재로써 마그네시아 인산염 복합체와 플라이애시를 혼입하여 그에 따른 인조석재의 특성을 알아보고자 한다. 실험결과, 폐유리 혼합비율 60% 및 폐자기 혼합비율 70%가 인조석재의 전반적인 실험에서 가장 우수한 것으로 판단되며, 인조석재의 기초적인 자료로 활용할 수 있을 것으로 기대된다.

• 한국결정성장학회지
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• 제28권6호
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• pp.256-262
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• 2018

화력발전소에서 발생하는 폐기물인 플라이애시(fly ash)는 현재까지도 상당량이 재활용되지 못하고 매립되어 환경오염 및 막대한 경제적 비용을 발생시키고 있다. 본 연구에서는 플라이애시를 건축 도자타일의 점토 원료를 대신함과 동시에 양산 공정을 그대로 적용하여 최종 제품을 제조하였다. 광물형 원료를 사용하여 소지와 1차(엔고베)와 2차(표면) 유약을 제조하고, 신속 소성(fast firing) 과정을 적용하여 도자타일을 제조한 후 도자타일의 성능을 측정하였다. 특히 소지에 첨가되는 석회석 함량을 증가시켜 플라이애시 첨가에 따른 도자타일 성능에 미치는 영향에 대하여 고찰하였다. 플라이애시가 첨가된 다공성 도자타일은 굽힘 강도와 흡수율, 뒤틀림 및 내마모성은 우수하지만 오토클레이브 실험을 통한 내구성은 크게 저하된 것을 확인하였다. 반면에 석회석을 첨가할 경우 도자타일의 흡수율과 뒤틀림 및 수화팽창은 증가하는 결과를 보이지만, 플라이애시가 첨가된 도자타일의 내구성을 크게 향상시키는 것으로 확인되었다. 결론적으로 플라이애시와 석회석 첨가를 통하여 국내 건축기준을 만족하면서 기존 도자타일 성능과 유사한 플라이애시 재활용 건축 도자타일을 제조할 수 있었다.

• 한국토양비료학회지
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• 제47권6호
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• pp.540-546
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• 2014

Acid mine drainage sludge (AMDS) has been classified as mine waste and generally deposited in land. For this reason, studies have been conducted to examine the possibility of recycling AMDS as an amendment for heavy metal stabilization in soil. The main objective of this study was to evaluate heavy metal stabilization efficiency of AMDS comparing with the widely used lime stone. Also, optimum mixing ratio was evaluated for enhancing heavy metal stabilization. AMDS and limestone were mixed at the ratio of 0:100, 25:75, 50:50, 75:25, and 100:0 with five different heavy metal solutions ($100mg\;L^{-1}$ of $NaAsO_2$, $CdCl_2$, $CuCl_2$, $Pb(NO_3)_2$, and $ZnSO_4{\cdot}7H_2O$). The amendments were added at a rate of 3% (w/v). In order to determine the stabilization kinetics, samples were collected at different reaction time of 0, 1, 2, 4, 8, 16, 32, 64, 128, 256, 512, 1024 minutes. The heavy metal stabilization by AMDS was faster and higher than those of limestone for all examined heavy metals. While limestone showed only 20% of arsenic (As) stabilization after 1,024 minutes, 96% of As was stabilized within 1 minute by AMDS. The highest effect on the stabilization of heavy metal (loid) was observed, when the two amendments were mixed at a ratio of 1:1. These results indicated that AMDS can be effectively used for heavy metal stabilization in soil, especially for As, and the optimum mixing ratio of AMDS and lime was 1:1 at a rate of 3% (w/v).

• 대한기계학회논문집B
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• 제21권8호
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• pp.1068-1076
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• 1997

Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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• pp.250-251
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• 2014

With the recent movement toward sustainable development, many efforts have been made to reduce environmental loads in various domains of industry. In particular, a great deal of research and technology development has been underway on approaches to reducing industrial waste and the emission of greenhouse gases. For this reason, a quantitative analysis of the reduction in CO₂ emission that could be achieved by replacing limestone material with cementitious waste powder was performed in this study. Through the analysis, it was found that CO₂ emissions were reduced by up to 50 percent compared with the scenario in which OPC was used, which suggests that it is possible to reduce global CO₂ emissions by approximately 5percent, or by 446.4 Tg of the 965 Tg of CO₂ emissions generated by the cement industry, in the total global CO₂ emissions of 19300Tg.

• 한국도로학회논문집
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• 제17권1호
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• pp.25-33
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• 2015

PURPOSES : This paper, presents the results of a laboratory study aimed to verify the suitability of a particular type of Electric Arc Furnace (EAF) steel slag to be recycled in the lithic skeleton of both dense graded and porous asphalt mixtures for flexible pavements. METHODS : Cyclic creep and stiffness modulus tests were performed to evaluate the mechanical performance of three different asphalt mixtures (dense graded, porous asphalt, and stone mastic) prepared with two types of EAF steel slag. For comparison purposes, the same three mixtures were also designed with conventional aggregates (basalt and limestone). RESULTS : All the asphalt mixtures prepared with EAF steel slag satisfied the current requirements of the European standards, which support EAF steel slag as a suitable material for flexible pavement construction. CONCLUSIONS : Based on the experimental work, the use of waste material obtained from steel production (e.g. EAF steel slag) as an alternative in the lithic skeleton of asphalt mixtures can be a satisfactory and reasonable choice that fulfills the "Zero Waste" objective that many iron and steel industries have pursued in the past decades.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.160-161
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• 2013

Recently, the enviroment problem is serious due to the global warming phenomenon because of the greenhouse gas exhaustion. In addition, the effort to reduce the problem in the situation where the severity of the destruction of environment because of the indiscriminate picking of the that is the raw material of the cement, Accordingly, in the interior of a country, the industrial site using the artificial stone instead of the natural stone is increased. Thus the cement reduction amount of use and substitute material research is the urgent actual condition with the gas emission, which here it is generated in conducting compression molding in the building stone manufacturing process performance degradation phenomenon and fire resistance, and problem of the durability. limestone and aggregate and exhaustion of resource are emphasized is continued. In this research, the fly ash and waste porcelain is applied to the magnesia phosphate composite (MPC) and the characteristic of the artificial stone according to it tries to be looked into.

• Advances in concrete construction
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• 제9권2호
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• pp.217-225
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• 2020

The recovery of waste proves a solution with two impacts: the environmental impact by the reduction of pollution and the gain of the occupied space by this waste, and the economic impact by the use of these lasts in the building and in the area of public works. The present research consists in recovering a waste marble (thrown powder exposed to the different meteorological phenomena) generated by the quarry marble of Fil-fila, located at the east side of Skikda in the north-east of Algeria, and add it, as sand in the composition of sand concrete. To carry out this research, we analyzed the evolution brought by the substitution of ordinary sand by marble waste sand, with 25%, 50%, 75% and 100% on the properties in the fresh state (density, workability and air content) and in the cured state (compressive strength, tensile strength, surface hardness and sound velocity). For durability we tested water absorption by immersion and chloride penetration. The results obtained are compared with control samples of 0% of substitution rate. In order to have a good filling of the voids in the granular skeleton; we added a quantity of limestone recycled fines from the quarries and for a good workability a super-plasticizing additive. The results showed that the partial substitution modified both the fresh and the hardened characteristics of the tested concretes, the durability parameters also improved.