• Title/Summary/Keyword: Waste Acids

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Digestibility and Nitrogen Balance of Diets that Include Marine Fish Meal, Catfish (Pangasius hypophthalmus) By-product Meal and Silage, and Processing Waste Water in Growing Pigs

  • Thuy, Nguyen Thi;Lindberg, Jan Erik;Ogle, Brian
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.7
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    • pp.924-930
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    • 2010
  • Ileal and total tract digestibility and nitrogen (N) balance of diets with four different protein sources were determined in growing pigs. The diets were based on rice bran, broken rice and maize meal and contained Tra catfish by-product (CBP), processed using three different methods, and marine fish meal (FM). The CBP diets consisted of the by-product in meal form, ensiled with molasses, and CBP waste water (WWBD). The four diets were fed to four growing pigs fitted with post-valve T-cecum (PVTC) cannulas in a $4{\times}4$ Latin Square design. All experimental diets included $Cr_2O_3$ at 5 g/kg feed as an indigestible marker. The ileal apparent digestibility of organic matter and ether extract was higher on diet WWBD than on the other three diets (p<0.05), and the total tract apparent digestibility was higher on diet WWBD than on the FM diet (p<0.05). The ileal and total tract apparent digestibility of crude protein and amino acids was not significantly different among diets (p>0.05). No significant effects of diet were found on N-retention and N utilization. In conclusion, the catfish by-product meal, ensiled catfish by-product and processing waste water diets and the fish meal diet had similar ileal and total tract apparent digestibility, and similar N utilization in growing pigs.

Surface Properties of Modified Activated Carbon for Ammonia Gas Removal (암모니아 가스 제거용 개질 활성탄의 표면특성)

  • Lee, Seongwoo;Oh, Gilyong;Kim, Rina;Kim, Daekeun
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.3
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    • pp.317-324
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    • 2013
  • This research assessed the surface properties of modified activated carbons with three different acids and five different metals for ammonia gas removal. Raw bituminous coal-based activated carbon ($4{\times}8$ mesh) had low adsorption capacity of 0.72 mg $NH_3/g$ based on the analysis in the column adsorption experiment. Adsorption capacities of carbons modified with $CH_3COOH$, $H_3PO_4$, and $H_2SO_4$ increased up to 3.34, 21.00, and 35.21 mg $NH_3/g$, respectively. Those of carbons with Cu, Zn, Zr, Fe, and Sn were 9.63, 9.13, 7.09, 25.12 and 15.03 mg $NH_3/g$. Ammonia adsorption was enhanced by the presence of surface oxygen groups on carbon materials, which influenced pH of carbon surface. BET surface area of raw carbon was analyzed to be $1087m^2/g$, but it decreased by carbon surface modification. Fe-impregnated carbon showed $503.02m^2/g$ of surface area. These observations were mostly caused by chemical adsorption.

Biodegradation of Cutting Oil by Pseudomonas aeruginosa KS47 (Pseudomonas aeruginosa KS47에 의한 절삭유의 생물학적 분해)

  • Kim, Lan-Hee;Lee, Sang-Seob
    • Korean Journal of Microbiology
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    • v.44 no.1
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    • pp.22-28
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    • 2008
  • Cutting oils are emulsionable fluids widely used in metal working processes. Their composition is mineral oil, water, and additives (fatty acids, surfactants, biocides, etc.) generating a toxic waste after a long use. Cutting oils also affect colour, taste and odour of water, making it undesirable for domestic and industrial uses. In these days, conventional treatment methods as evaporation, membrane separation or chemical separation have major disadvantages since they generate a concentrated stream that is more harmful than the original waste. In this study, our purpose is to reduce cutting oils by using biological treatment. Eighty one strains were isolated from cutting waste oil of industrial waste water sludge under aerobic conditions. Among these strains, KS47, which removed 90.4% cutting oil in 48 hr, was obtained by screening test under aerobic conditions(pH 7, $28^{\circ}C$). KS47 was identified as Pseudomonas aeruginosa according to morphological, physiological and biochemical properties, 16S rDNA sequence, and fatty acid analysis. P. aeruginosa KS47 could utilize cutting oil as carbon source. In batch test, we obtained optimal degradation conditions(1.5 g/L cell concentration, pH 7, and temperature $30^{\circ}C$). Under the optimal conditions, 1,060 mg/L cutting oil was removed 83.7% (74.1 mg/L/hr).

The Synthesis and characterization of of asphalt anti-stripping agents, amides synthesized from waste oils (폐오일을 이용한 아마이드계 아스팔트 박리방지제의 합성 및 특성 분석)

  • Lee, Sang Ah;Kim, Jiwung;Cho, Namjun
    • Analytical Science and Technology
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    • v.29 no.6
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    • pp.300-304
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    • 2016
  • The asphalt antistripping agents were synthesized from ethylenediamine (ED) or N,N'-bis(2-hydroxyethyl)ethylenediamine (HEED) with three different fatty acids. The formation of amide bonds were successfully performed and confirmed by FT-IR and $^1H-NMR$ data. The adhesive properties of antistripping agents were compared in terms of contact angle and BBS test. The reaction product of ED with waste animal fat exhibited the most hydrophobic by the contact angle measurement, and the strongest water resistance of 94 % by BBS test. However, the reaction product of ED with waste vegetable oil showed the strongest absolute bond strength of ca. 3610 and 3227 kPa for before and after water conditioning, respectively. For the bond strength in general, the reaction products of ED were superior to HEED reaction products, and the reaction products of animal fat and waste vegetable oil were superior to those of pure soybean oil.

Energy production from organic waste by anaerobic treatment (I) : Hydrogen production from food waste (혐기성 처리에 의한 유기성 폐기물 에너지화 (I) : 음식폐기물의 수소화)

  • Han, Sun-Kee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.1
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    • pp.102-108
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    • 2011
  • Characteristics of hydrogen production from various food wastes in anaerobic batch reactors were evaluated to assess the energy potential of organic wastes. Organic wastes which were used in this study were scallion as vegetable, apple as fruit, rice as grain and pork as meat. Ultimate hydrogen yield of scallion, apple, rice and pork were 0.46, 0.47, 0.62 and $0.05mol\;H_2/mol\;hexose$, respectively. On the other hand, hydrogen production rates of scallion, apple, rice and pork were 0.013, 0.021, 0.014 and $0.005mol\;H_2/mol\;hexose/h$, respectively. These results indicated that anaerobic hydrogen fermentation from food waste except for meat was effective in removing organic material as well as producing renewable energy. Volatile fatty acids increased as hydraulic retention time was increased. In the hydrogen fermentation, acidification degree of rice was measured as the highest rate of 75.8% whereas pork was found as the lowest rate of 35.2%.

Adsorption behavior of platinum-group metals and Co-existing metal ions from simulated high-level liquid waste using HONTA and Crea impregnated adsorbent

  • Naoki Osawa;Seong-Yun Kim;Masahiko Kubota;Hao Wu;Sou Watanabe;Tatsuya Ito;Ryuji Nagaishi
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.812-818
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    • 2024
  • The volume and toxicity of radioactive waste can be decreased by separating the components of high-level liquid waste according to their properties. An impregnated silica-based adsorbent was prepared in this study by combining N,N,N',N',N",N"-hexa-n-octylnitrilotriacetamide (HONTA) extractant, N',N'-di-n-hexyl-thiodiglycolamide (Crea) extractant, and macroporous silica polymer composite particles (SiO2-P). The performance of platinum-group metals adsorption and separation on prepared (HONTA + Crea)/SiO2-P adsorbent was then assessed together with that of co-existing metal ions by batch-adsorption and chromatographic separation studies. From the batch-adsorption experiment results, (HONTA + Crea)/SiO2-P adsorbent showed high adsorption performance of Pd(II) owing to an affinity between Pd(II) and Crea extractant based on the Hard and Soft Acids and Bases theory. Additionally, significant adsorption performance was observed toward Zr(IV) and Mo(VI). Compared with studies using the Crea extractant, the high adsorption performance of Zr(IV) and Mo(VI) is attributed to the HONTA extractant. As revealed from the chromatographic experiment results, most of Pd(II) was recovered from the feed solution using 0.2 M thiourea in 0.1 M HNO3. Additionally, the possibility of recovery of Zr(IV), Mo(VI), and Re(VII) was observed using the (HONTA + Crea)/SiO2-P adsorbent.

Analysis of Aliphatic Carboxylic Acids Using Ion-Exchange Chromatography: Application to Groundwater Affected by Landfill Leachates (이온-교환 크로마토그래피를 활용한 유기산 분석: 매립지 침출수의 영향을 받은 지하수에 대한 적용)

  • Cheon, Su-Hyun;Koh, Dong-Chan;Ko, Kyung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.12 no.2
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    • pp.55-64
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    • 2007
  • An analytical method using ion-exchange chromatography was developed for simultaneous quantification of low-molecularweight organic acids ($C_1-C_6$ aliphatic carboxylic acids) and inorganic anions, and then applied to the assessment of ground water contaminated by leachates from a municipal solid waste landfill. Peak interferences of halide ions to organic acids were removed by pretreatment of water samples with Ag-containing cartridges. This method allowed accurate detection of low-molecular weight organic acids (i.e., formate, acetate, propionate, pyruvate, succinate, and oxalateas) low as 0.5 mg/L with a linear dynamic range up to 20 mg/L within 11 min run time along with typical inorganic anions. High level of pyruvate and low level of formate and acetate were detected in groundwater and landfill leachates using the analytical method. Pyruvate concentration in groundwater showed a significant correlation with concentrations of $Cl^-$ and $HCO_3^-$, and pyruvate levels decreased along the downgradient from the landfill, indicating the sources of pyruvate are landfill leachate.

Egg Quality Characteristics of Layer Chickens Reared with Tenebrio molitor Larvae (갈색거저리 유충을 급이한 산란계로부터 얻은 계란의 품질특성)

  • Kim, Do Hyeong;Kim, Dong Hyun;Park, Hyun Woo;Kim, Jin Kwon;Kim, Sam Woong;Kim, Tae Wan;Lee, Byeong Jin;Son, Daniel;Kim, Il-Suk
    • Journal of Life Science
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    • v.30 no.10
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    • pp.860-866
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    • 2020
  • This study examined the characteristics of eggs obtained from layer chickens reared with feed that included Tenebrio molitor larvae, which were in turn bred using feed that included dried food waste powder. The eggs showed a tendency to be slightly thinner in the treated groups, but the Haugh unit indicating freshness was higher in the treated groups than the control group, and the 5% larval-treated group showed the highest value. The color of the yolk tended toward higher redness, lower brightness, and lower yellowness in the 5%-treated group, which also showed similar crude fat and protein values to the control group; the 10%- and 15% larval-treated groups had lower crude fat and protein values, although the carbohydrate content was higher. Structural amino acids in the treated groups showed a higher ratio of non-essential amino acids to essential amino acids than the control. The polyphenol content, which is an index of antioxidants, was highest in the 5%-treated group, and it is thought that this may affect the storage and antioxidant properties of the eggs. Thus, when employed with a feed source to maintain high protein and high fat, T. molitor larvae may cause critical changes in the nutrient content of eggs and improve their freshness.

Effect of pH on the $VFA_s$ fermentation in the anaerobic treatment of food waste (pH조절이 음식폐기물의 유기산발효에 미치는 영향)

  • 조한진;성낙창;김은호;장성호;손영일;박진식
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.32-37
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    • 2001
  • The purpose of this study was to investigate the created liquid post-acid fermentation of usability of denitrification as exterior carbon sources by pH control. The time of acid fermentation of food waste, the slower loading capacity of organic matter, the faster decomposition rate, but the density of generation Volatile Fermentation Acids(VFAs), was weak and, $SBOD_{5}$ : ST-N rate and $SBOD_{5}/SCOD_{Cr}$ rate was low. Between TS and VS, VS was decreased to 4.5th day fast, and then was decreased slowly. 1.5 days after stating the experiments, $SCOD_{Cr}$, $SBOD_{5}$, STOC and $VFA_{s}$ was decreased of increased slowly, and then increased fast. And after showing the highest density, it was tended to decreased fast. At the time of $SBOD_{5}$ with the highest density, at $SBOD_{5}$ : ST-N ratio, $R_1$ was 303:1, $R_2$ was 319:1, $R_3$was the highest. After studying $SBOD_{5}$ : ST-N ratio and $SBOD_{5}/SCOD_{Cr}$ ratio, as a carbon source of biological denitrification it was profitable composition ratio.

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Bioleaching of electronic scrap using Aspergillus niger (Aspergillusniger를 이용한 전자스크랩의 미생물 침출 연구)

  • Ahn, Jae-Woo;Jeong, Jin-Ki;Lee, Jae-Chun;Kim, Dong-Gin;Ahn, Jong-Gwan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.214-223
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    • 2005
  • In order to recover valuable metals from fine-grained electronic waste, bioleaching of Cu, Zn, Al, Co, Ni, Sn and Pb were carried out using Aspergillus niger as a leaching microorganism in a shaking flask. Aspergillus niger was able to grow in tile presence of electronic scrap. The formation of organic acids(citric and oxalic acid) from Aspergillus niger caused the mobilization of metals from waste electronic scrap. In a preliminary study, in order to obtain the data on the leaching of Cu, Zn, Al, Co and Ni, the metal leaching behaviours were accomplished using Organic acid(Citric acid and Oxalic acid) instead of Aspergillus niger. At the electronic scrap concentration of 50g/L, Aspergillus niger were able to leach more than 95% of the available Cu, Co. But Al, Zn, Pband Sn were able to leach about 15-35%. Ni and Fe were detected in the leachate less than 10%.

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