• Title/Summary/Keyword: WT-300

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Electrical and Optical Properties of Ga-doped SnO2 Thin Films Via Pulsed Laser Deposition

  • Sung, Chang-Hoon;Kim, Geun-Woo;Seo, Yong-Jun;Heo, Si-Nae;Huh, Seok-Hwan;Chang, Ji-Ho;Koo, Bon-Heun
    • Journal of the Korean institute of surface engineering
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    • v.44 no.4
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    • pp.144-148
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    • 2011
  • $Ga_2O_3$ doped $SnO_2$ thin films were grown by using pulsed laser deposition (PLD) technique on glass substrate. The optical and electrical properties of these films were investigated for different doping concentrations, oxygen partial pressures, substrate temperatures, and film thickness. The films were deposited at different substrate temperatures (room temperature to $600^{\circ}C$). The best opto-electrical properties is shown by the film deposited at substrate temperature of $300^{\circ}C$ with oxygen partial pressure of 80 m Torr and the gallium concentration of 2 wt%. The as obtained lowest resistivity is $9.57{\times}10^{-3}\;{\Omega}cm$ with the average transmission of 80% in the visible region and an optical band gap (indirect allowed) of 4.26 eV.

Study of Deep Blue Organic Light-Emitting Diodes Using Doped BCzVBi with Various Blue Host Materials

  • Kim, Tae-Gu;Oh, Hwan-Sool;Kim, You-Hyun;Kim, Woo-Young
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.2
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    • pp.85-88
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    • 2010
  • Deep blue organic light emitting diodes (OLEDs) were fabricated using 5 wt.% doped BCzVBi with various blue host materials such as NPB, DPVBi, MADN and TPBi. A blue OLED device, using DPVBi as host material, was constructed via NPB ($500\;{\AA}$) / DPVBi:BCzVBi ($200\;{\AA}$) / Bphen ($300\;{\AA}$) / LiF ($20\;{\AA}$) / Al ($1,000\;{\AA}$) and it shows a maximum luminescence of $4,838\;cd/m^2$, a current density of $32.7\;mA/cm^2$, a luminous efficiency of 3.3 cd/A and CIExy coordinates of (0.19, 0.15) at 4.5 V whereas the luminous efficiencies and CIExy coordinates of other blue OLEDs using NPB, MADN and TPBi as host materials have 1.1, 2.6 and 2.0 cd/A and (0.15, 0.11), (0.15, 0.10) and (0.15, 0.10), respectively. Energy transfer mechanisms between BCzVBi and its host materials were discussed with an energy band structure of host materials.

Characterization of Single-walled Carbon Nanotubes Synthesized by Water-assisted Catalytic Chemical Vapor Deposition

  • Lee, Yeon-Ja;Kim, Bawl;Yu, Zhao;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.381-381
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    • 2011
  • The influence of the water vapor on the growth of single-walled carbon nanotubes (SWCNTs) was investigated. SWCNTs were synthesized by catalytic chemical vapor deposition of acetylene over Fe-Mo/MgO catalyst with injection of water vapor. The morphologies and structures of the water-assisted SWCNTs were investigated according to the growth conditions such as water vapor concentrations, flow rate of the gas, furnace temperature, and growth time. Water-assisted SWCNTs exhibited large bundle morphological features with well-alignment of each CNT, while SWCNTs synthesized in the absence of water vapor showed entangled CNT with the random orientation. We also found that the diameter of the SWCNT bundle could be controlled by the growth condition. In our optimal growth condition, the product yield and the purity were 300 wt. % and 75%, which were 7.5 and 2.5 times higher than those of SWCNTs synthesized without water vapor, respectively. More detail discussion will be offered at the poster presentation.

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Structural, Optical and Electrical Properties of GZO Thin Film for Annealing Temperature Change by RF Magnetron Sputtering System (RF magnetron sputtering으로 증착한 GZO 박막의 열 처리 온도 변화에 따른 구조적, 광학적, 전기적 특성)

  • Lee, Yun seung;Kim, Hong bae
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.4
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    • pp.41-45
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    • 2016
  • ITO/GZO double layered thin films were prepared on transparent glass substrates. Ga-doped ZnO(GZO) films were deposited by RF magnetron sputtering using an ZnO:Ga (98: 2 wt%) target. The post deposition annealing process was conducted for 30 minutes at different temperature of 100, 200, 300 and $400^{\circ}C$, respectively. As increase annealing temperature, ITO/GZO double layered thin films show the increment of the prefer orientation of ZnO diffraction peak (002) in the XRD patterns. We obtained Ga-doped ZnO thin films with a lowest resistivity of $1.84{\times}10^{-4}{\Omega}-cm$ at $400^{\circ}C$ and transparency above 80% in visible ranges. The figure of merit obtained in this study means that ITO/GZO double layered thin films which annealed at $400^{\circ}C$ have the highest optoelectrical performance in this study.

Effect of Ca addition on the microstructure and mechanical properties of extruded AZ31 alloy (마그네슘합금 AZ31 압출재의 기계적특성에 미치는 Ca의 효과)

  • Kim, Jeoung-Han;Kang, Na-Eun;Lee, Sang-Bok;Yim, Chang-Dong;You, Bong-Sun;Kim, Byoung-Kee
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.10a
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    • pp.281-284
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    • 2007
  • The effect of Ca addition on the microstructure evolution and deformation behavior of AZ31 magnesium alloy produced by hot extrusion was investigated. For this purpose, Ca was added into AZ31 melts to the level of 0.7 and 2.0 wt.% Ca. Then, AZ31 base alloy and Ca modified AZ31 alloys were extruded at $383^{\circ}C$. Ca added alloys showed finer grain size and increased hardness value rather than AZ31 base alloy. After isothermal hot compression, the shape of tested specimen exhibited a noticeable anisotropy due to the crystallographic texture effect. The ratio of major and minor axes of ovality was not directly related to test condition and Ca amount. Flow stress level increases with the increase of Ca addition at temperature below $300^{\circ}C$ because of fine microstructure. However, at high temperature and low strain rate region ($400^{\circ}C$ and $10^{-3}s^{-1}$), reverse tendency was observed since main deformation mechanism changes from dislocation slip to grain boundary sliding or diffusional process at high temperature.

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Effect of Ca/P Mole Ration on Mechanical Properties of Alumina added Hydroxyapatite (알루미나를 첨가한 Hydroxyapatite의 기계적 물성에 미치는 Ca/P 몰비의 영향)

  • Lee, D.Y.;Lee, S.K.;Park, H.;Kim, C.E.
    • Journal of the Korean Ceramic Society
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    • v.28 no.5
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    • pp.373-382
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    • 1991
  • The effect of Ca/P mole ratio (Ca/P=1.60, 1.67, 1.75) in the initial solution on the mechanical properties of alumina added hydroxyapatite was investigated. Hydroxyapatite was synthesized by precipitation method using Ca(NO3)2$.$4H2O and (NH4)2HPO4 as starting materials and 5 wt% of ${\alpha}$-Al2O3 was added to precipitation solution. The powder was calcined at 800$^{\circ}C$ and sintered at 1,150∼1,400$^{\circ}C$ under water vapor atmosphere. With the increasing of Ca/P mole ration in the initial solution, the amount of tricalcium phosphate formed from the decomposition of hydroxyapatite reduced and the sinterability and mechanical properties were increased. The bending strength and Vickers hardness of the specimen sintered at 1,300$^{\circ}C$ with the Ca/P mole ratio of 1.75 in the initial solution were 230 MPa and 650 kg/$\textrm{mm}^2$, respectively. The improvement of mechanical properties was attributed to not only the effect of Ca/P mole ratio but also the strengthening of sintered body by Al substitution for P ions.

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Poly(vinylidene fluoride)-based Porous Carbon Nanofibers (폴리비닐리덴 풀루오라이드로부터 제조된 다공성 탄소나노섬유)

  • Chung, H.J.;Jo, S.M.;Kim, D.Y.;Chin, B.D.;Lee, D.W.
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.4
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    • pp.334-342
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    • 2005
  • 200-300 nm 직경을 지닌 폴리비닐리덴 플루오라이드 초극세 섬유를 전기방사법으로 제조하였다. 이들을 불응화시킨 후, $800-1800^{\circ}C$ 온도에서 탄화시켜 PVdF 계 탄소나노 섬유를 제조하여 구조 및 기공분석을 하였다. 이들은 20-30 nm 크기의 탄소입자로 이루어져 있으며 탄소나노입자는 1 nm이하의 슬릿형 나노기공을 지니고 있었다. 탄화온도가 증가함에 따라 비표면적은 $1500^{\circ}C$에서 $414\;m^2/g$로 감소하였으나, $1800^{\circ}C$에서는 $1300\;m^2/g$로 급격히 다시 증가하였으며 1 nm 이하의 나노기공만을 지닌 탄소섬유가 얻어졌다. 비표면적 및 기공특성과 수소저장특성을 관계를 조사하기 위하여 Magnetic Syspension Balance(MSB)를 사용한 중량법으로 평가한 이들의 수소저장능은 0.04-0.4wt%이었다.

Properties of AZO thin flim for solar cells with various input current prepared by FTS method (FTS 법으로 제작한 태양전지용 AZO 박막의 투입전류에 따른 특성)

  • Jung, Yu-Sup;Kim, Sang-Mo;Choi, Myung-Kyu;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.471-472
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    • 2008
  • The properties of Al doped ZnO (AZO) thin flim for solar cells with various input currents were studied in this paper. Using facing target sputtering with 2wt.% AZO targets, TCO films were deposited on glass(corning 2948) substrate at room temperature. AZO thin films were deposited by 0.2A, 0.4A, 0.6A and 0.8A at the thickness of 300nm. Electrical, optical and structural of thin films investigated by a Hall effect measurement (Ecopia), an UV-VIS spectrometer(HP) and a X-ray diffractometer (Rigaku). As a results, all thin films showed transmittance about 80%, respectively and resistivity was $7.67\times10^{-4}\Omega$-cm at 0.6A.

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A Novel Donor-Acceptor-Acceptor-Acceptor Polymer Containing Benzodithiophene and Benzimidazole-Benzothiadiazole-Benzimidazole for PSCs

  • Tamilavan, Vellaiappillai;Song, Myungkwan;Agneeswari, Rajalingam;Kim, Sangjun;Hyun, Myung Ho
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1098-1104
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    • 2014
  • New electron deficient acceptor-acceptor-acceptor type of monomer unit composed of weak electron accepting benzimidazole and relatively strong electron accepting benzothiadiazole derivatives namely 4,7-bis(6-bromo-1-(2-ethylhexyl)-1H-benzo[d]imidazol-2-yl)benzo[c][1,2,5]thiadiazole (BBB) was synthesized. The Stille polycondensation of the newly synthesized BBB monomer with electron donating 2,6-bis(trimethyltin)-4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b']dithiophene (BDT) afforded donor-acceptor-acceptor-acceptor type of polymer namely 2,6-(4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b']dithiophene)-alt-4,7-bis(1-(2-ethylhexyl)-1H-benzo[d]imidazol-2-yl)benzo[c][1,2,5]thiadiazole (PBDTBBB). The opto-electrical studies revealed that the absorption band of PBDTBBB appeared in the range of 300 nm-525 nm and its highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels were positioned at -5.18 eV and -2.84 eV, respectively. The power conversion efficiency (PCE) of the polymer solar cell (PSC) prepared from PBDTBBB:PC71BM (1:2 wt %) blend was 1.90%.

Study of Flow Characteristics of Gel Propellant through Various Injector Geometries (인젝터 형상 변화에 따른 Gel 추진제의 유동 특성 연구)

  • Oh, Jeong-Su;Jeon, Doo-Sung;Choi, Sang-Tae;Kim, Deok-Yoon;Choi, Yang-Ho;Lee, Jeong-Hyuk;Moon, Hee-Jang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.300-303
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    • 2010
  • The present study investigates the flow characteristics of simulant gel propellant(carbopol 0.5%wt) in a variety of injectors. Rheological data for gel propellant has been measured and injector flow characteristics for plain-orifice, chamfered-orifice and venturi type injector have been numerically analyzed. The apparent viscosity of plain-orifice and chamfered-orifice have tendency to increase along axial direction, whereas for venturi type injector, low viscosity has been achieved in the injector flow. This phenomenon was clearly pronounced as Reynolds number is increased.

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