• Title/Summary/Keyword: WO$_3$

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Conducting Metal Oxide Interdigitated Electrodes for Semiconducting Metal Oxide Gas Sensors

  • Shim, Young-Seok;Moon, Hi-Gyu;Kim, Do-Hong;Jang, Ho-Won;Yoon, Young-Soo;Yoon, Soek-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.65-65
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    • 2011
  • We report the application of conducting metal oxide electrodes for semiconducting metal oxide gas sensors. Pt interdigitated electrodes have been commonly used for metal oxide gas sensor because of the low resistivity, excellent thermal and chemical stability of Pt. However, the high cost of Pt is an obstacle for the wide use of metal oxide gas sensors compared with its counterpart electrochemical gas sensors. Meanwhile, relatively low-cost conducting metal oxides are widely being used for light-emitting diodes, flat panel displays, solar cell and etc. In this work, we have fabricated $WO_3$ and $SnO_2$ thin film gas sensors using interdigitated electrodes of conducting metal oxides. Thin film gas sensors based on conducting metal oxides exhibited superior gas sensing properties than those using Pt interdigitated electrodes. The result was attributed to the low contact resistance between the conducting metal oxide and the sensing material. Consequently, we demonstrated the feasibility of conducting metal oxide interdigitated electrodes for novel gas sensors.

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An analysis of shear bond strength of Co-Cr alloy of porcelain fused to metal and ceramic (도재용착용 비귀금속 합금(Co-Cr)과 세라믹의 소성술식에 따른 전단결합강도 분석)

  • Im, Joong-Jae
    • Journal of Technologic Dentistry
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    • v.39 no.3
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    • pp.153-159
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    • 2017
  • Purpose: In this study, a corresponding porcelain coating material was applied to dental Co-Cr metal among PFM. Methods: The bonding strength of the fired specimens was measured by a three-point flexural rigidity test. SEM/EDS was used to observe the surface component of specimens. Results: First, All groups were higher than the minimum bonding strength of 25 MPa specified in ISO 9693 for dental metal-ceramics specimens. Second, The bonding strength of control group(WO) is 44.64 MPa. Experimental group DM was 35.45 MPa and DP was 31.82 MPa(P<0.05). Tukey's HSD tests results have shown that the bonding strength in control group(WO) is higher than that of experimental group(DM, DP). Third, In the case of metal - porcelain bonding strength, the application of opaque porcelain and firing were higher than those of the group treated with degassing process. Conclusion: The bonding strength was higher when the powder opaque porcelain was applied than the paste opaque porcelain.

Growth of lead-based functional crystals by the vertical bridgman method

  • Xu Jiayue
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.1
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    • pp.1-7
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    • 2006
  • Some lead-based crystals show excellent ferroelectric, piezoelectric or scintillation properties and have attracted much attention in recent years. However, the erosion of the high temperature solution on platinum crucible and the evaporation of PbO component are the main problems often encountered during the crystal growth. In this paper, we reported recent progress on the Bridgman growth of lead-based functional crystals, such as novel relaxor ferroelectric crystals (PZNT and PMNT), scintillation crystals $(PbWO_4,\;PbF_2\;and\;PbClF)$ and piezoelectric crystals $(Pb_5Ge_3O_{11}\;and\;Pb_2KNb_5O_{15}),$ in Shanghai Institute of Ceramics, Chinese Academy of Sciences. The vertical Bridgman method has been modified to grow PZNT crystals from high temperature solution and as-grown crystals have been characterized. Large size lead-based scintillators, $PbWO_4\;and\;PbF_2$ crystals, have been mass-produced by the vertical Bridgman method in the multi-crucible fumace. These crystals have been supplied to CERN and other laboratories for high-energy physics experiments. The Bridgman growth of piezoelectric crystals $Pb_5Ge_3O_{11}\;and\;Pb_2KNb_5O_{15}$ are discussed also.

Carbothermal Reduction of Oxide Powder Prepared from Waste WC/Co Hardmetal by Solid Carbon (WC/Co 초경 스크랩 산화물의 고체탄소에 의한 환원/침탄)

  • Lee Gil-Geun;Ha Gook-Hyun
    • Journal of Powder Materials
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    • v.12 no.2 s.49
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    • pp.112-116
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    • 2005
  • In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{\circ}C$, formed tungsten carbides at about $950^{\circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{\circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{\circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {\mu}m$.

Eine statistische Untersuchung zur Wortstellung im Deutschen (독일어의 어순에 관한 몇 가지 관찰 - 부사와 목적어의 어순 및 동사위치에 따른 어순변화)

  • Song Kyung-An;Cho Tong Sop
    • Koreanishche Zeitschrift fur Deutsche Sprachwissenschaft
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    • v.3
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    • pp.75-94
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    • 2001
  • Die vorliegende Arbeit versuchte durch Umfragen an die deutschen Studierenden eine statistische Untersuchung $\"{u}ber$ die Grundwortstellung des Objekts und der Adverbien des Deutschen und $\"{u}ber$ ihre $Ver\"{a}nderungsm\"{o}glichkeit$ in Bezug auf die Verbposition. Dabei wurde gezeigt, dass die Grundwortstellung je nach der Art der Adverbien variiert. Die temporalen Adverbien gehen z.B. dem Objekt vor, $w\"{a}hrend$ die lokalen Adverbien generell hinter dem Objekt stehen. Im Gegensatz zum Ergebnis von Song (1993) wurde aber fesgestellt, dass im Deutschen die Wortfolge 'Objekt + Adverb' eher die vorherrschendere ist, als die von 'Adverb + Objekt'. Hier sollte man aber klarmachen, dass man dabei fast keine absolut bevorzugte Grund­wortstellung festlegen konnte, sondem dass sie eher je nach dem Sprecher sehr variiert. Im Vergleich mit dem Koreanischen, wo die Grundwortstellung zwischen dem Objekt und Adverbien nicht schwankend ist, ist es dem Deutschen charakteristisch, dass diese Grundwortstellung je nach der Art der Adverbien variiert und auch je nach dem Sprecher schwankend ist. Die Wortstellung des Deutschen kontrastiert sich auch gegen die des Englischen, in dem das Objekt konsistent den Adverbien vorgeht. Diese Ergebnisse waren $f\"{u}r$ DaF in Korea sinnvoll, wo das Englische als die erste und das Deutsche als die zweite Fremdsprache gelehrt werden und die Lemenden im Deutschunterricht nicht nur ihre Muttersprache, sondern auch das Englische als Bezugspunkt nehmen. Durch die Umfragen hat es sich nun ergeben, dass die Grund­wortstellung des Deutschen auch mit der Verbposition $zusammenh\"{a}ngt$. D.h., im Deutschen, wo das Verb an der zweiten Stelle oder am Ende des Satzes vorkommen kann, kann die Wortstellung von der Verbposition beeinflusst werden. Unter den verbfinalen Strukturen zeigt sich in den $Nebens\"{a}tzen\;die\;M\"{o}glichkeit\;der\;Wortfolgever\"{a}nderung$ deutlicher als in den $Modalverbs\"{a}tzen$ oder in den perfektiven$S\"{a}tzen$.

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Microwave Sol-Gel Process for Microcystalline Ho3+/Yb3+/Tm3+ Tri-Doped NaY(WO4)2 Phosphors and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.757-763
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    • 2016
  • $Ho^{3+}/Yb^{3+}/Tm^{3+}$ tri-doped $NaY_{1-x}(WO_4)_2$ phosphors with proper doping concentrations of $Ho^{3+}$, $Yb^{3+}$ and $Tm^{3+}$ ($x=Ho^{3+}+Yb^{3+}+Tm^{3+}$, $Ho^{3+}$=0.04, 0.03, 0.02, 0.01, $Yb^{3+}$=0.35, 0.40, 0.45, 0.50 and $Tm^{3+}$=0.01, 0.02, 0.03, 0.04) were successfully synthesized via the microwave sol-gel route, and their upconversion properties were investigated. Well-crystallized microcrystalline particles showed fine and homogeneous microcrystalline morphology with particle sizes of $1-2{\mu}m$. The optical properties were comparatively examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the doped particles exhibited white emissions based on blue, green and red emission bands, which correspond to the $^1G_4{\rightarrow}^3H_6$ transitions of $Tm^{3+}$ in the blue region, the $^5S_2/^5F_4{\rightarrow}^5I_8$ transitions of $Ho^{3+}$ in the green region, the $^5F_5{\rightarrow}^5I_8$ transitions of $Ho^{3+}$, and the $^1G_4{\rightarrow}^3F_4$ and $^3H_4{\rightarrow}^3H_6$ transitions of $Tm^{3+}$ in the red region. The pump power dependence of the upconversion emission intensity and the Commission Internationale de L'Eclairage chromaticity coordinates of the phosphors were evaluated in detail.

고속철도 PC Box교량 잭업을 위한 교각코핑부 안정성 검토

  • 강진욱;이명섭;김진욱
    • Journal of the Korean Society for Railway
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    • v.7 no.1
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    • pp.51-56
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    • 2004
  • 경부고속철도 제7-2공구 현장은 충청북도 영동군 심천면 초강리에서 영동읍 화신리에 이르는 총연장 10km의(182k800∼199k800) 고속철도 노반공사 현장으로서 총 연장 중 교량공은 3.6km, NATM터널 2.6km, 그리고 토공 3.8km로 구성되어 있다. 이중 교량공은 PC Box 연속교(2@40m, 2@25m, 3@25m 등)가 주를 이루고 있으며 가설공법으로는 현장타설공법인 FSM(Full Staging Method) 공법을 채택하였다. 교량의 받침 형식으로는 고정단에는 포트받침 그리고 가동단에는 탄성받침이 적용되었다(참조 : www.ktx7-2.wo.to). (중략)

Gif-KRICT Biomimetic Oxidation of Cyclohexane: The Influence of Metal Oxides

  • 박애숙;남상성;김성보;이규완
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.49-52
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    • 1999
  • Various metal oxides such as Fe2O3, FeO, TiO2, MnO2, MoO3, WO3 and ZnO have been used as a catalyst for Gif-KRICT type cyclohexane oxidation. In this reaction, the conversion of cyclohexane to cyclohexanone and cyclohexanol and the selectivity ratio of cyclohexanone to cyclohexanol were greatly affected by the acidity of metal oxides. When metal oxide has more acidic property, the reactivity on oxidation is increased and the formation of cyclohexanone is more favored. From this result, we proposed a new mechanism for the biomimetic Gif-KRICT oxidation system.

Petrological study on the Miocene Dangsari volcanic rocks, eastern part of Ulsan city, southeastern Korea (울산 동부 마이오세 당사리화산암류에 대한 암석학적 연구)

  • 윤성효;고정선;박기호;이영애
    • The Journal of the Petrological Society of Korea
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    • v.9 no.3
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    • pp.169-186
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    • 2000
  • The Miocene volcanic rocks in the Dangsari area, eastern part of Ulsan city, are mainly composed of andesite lava flows and pyroclastic rocks. The andesite lavas are identified as two-pyroxone andesite, comprising phenocrysts of augite ($Wo_{43.2}$ $En_{41.0}$ $Fs_{15.8}$ ) and hyperthene ($Wo_{2.7}$ $65.8_{En}$ $_{Fs}$ 31.5). The andesitic pyroclastic rocks are largely composed of pyroclastic breccias with alternating tuff-breccia and lapilli tuff, which showing planar layering, and minor amount of andesitic tuff with thin deposits of interlayered tuffaceous shale. According to the petrochemical data, andesitic rocks belong to medium-K calc-alkaline andesite. The position of bulk composition on the AFM diagram and the presence of normative quartz and hypersthene indicate that the volcanic rocks are calc-alkaline. The trace element composition and REE patterns of andesite, which are characterized by a high LILE/HFSE ratio and enrichment in LREE, suggest that they are typical of continental margin arc calc-alkalic volcanic rocks produced in the subduction environment. On the discrimination diagram, the Dangsari volcanic rocks fall into the fields of subduction related continental margin arc volcanic province. The primary magic melts may be derived from about 15% partial melting of mantle wedge in the upper mantle under destructive plate margin. And the melt evolved to calc-alkaline andesite magma by fractional crystallization and the magma was a little contaminated with crustal materials.

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