• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2005.04a
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• pp.30-30
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• 2005

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.158-158
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• 1996

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.217.1-217
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• 2003

• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.227-229
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• 2009

• Journal of Environmental Health Sciences
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• v.38 no.3
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• pp.261-268
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• 2012

Objectives: The photocatalytic degradation of toluene in a batch mode photoreactor for the purpose of the hazardous waste treatment was investigated. Methods: Kinetic experiments using a low pressure mercury lamp (Lambda Scientific Pty Ltd, 50 Watt) emitting both UV and visible light were performed at $31^{\circ}C$ over toluene concentrations ranging from 10 to 50 mg/l in water with $50%TiO_2/6%WO_3$ (TW) concentration of 1 g/l at a pH of 6. Results: Kinetic studies showed that $50%TiO_2/6%WO_3$ (TW) photocatalyst was highly active in toluene degradation; we observed that 99% of the pollutant was degraded after six hours under visible irradiation; furthermore, we observed that adsorption onto TW catalyst was responsible for the decrease of toluene with pseudo-first order kinetics. It was also found that oxygen as a radical source in the sol medium played a significant role in affecting the photodegradation of toluene, especially with a two-fold elevation. This increase was achieved by a more than four-fold elevation of the photodegradation of toluene in the presence of acetone than without, presumably via an energy transfer mechanism. Conclusions: We concluded that photodegradation in acetone and oxygen molecules along with TW was an effective method for the removal of toluene from wastewater.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.220-220
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• 2016

본 연구에서는 녹황색 빛을 내는 NaY(WO4)2:Tb3+ 형광체 파우더를 하소 350도에 1시간 소결 950도에 4시간 고상반응법으로 합성하였으며, 파우더는 X-ray diffraction과 PL 장비를 이용하여 측정하였다. XRD 분석은 Tb3+이온 도핑농도에 의한 순수한 NaYWO4 상을 나타내었다. Fig.1 220-330nm에서 관찰되는 넓은 밴드는 $O2-{\rightarrow}W6+$에 의해 발생한 LMCT(ligand to metal charge transfer)이고, Tb3+에서 WO42-그룹으로 에너지 전달에 의해서 생긴다. 이것의 최대세기는 272nm 이다. LMCT 옆 330-390nm에 관찰되어지는 약한 강도와 넓은 밴드는 Tb3+ 4f8의 f-f transition에 의해 발생한다. Fig.2에서 보여 지듯이$ 5D4{\rightarrow}7F6$, 7F5, 7F4, 7F3는 파장 489nm, main peak인 545nm (Green,초록색), 588nm (orange, 주황색), 620nm (Red, 적색)에서 Peak가 나타났으며, Tb3+이온의 함량비가 0.08mol일 때 최대 발광이 관측 되었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.625-629
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• 1999

In this study, in order to develop high sensitivity and low noise acoustic emission sensor, we manufactured the Pb(Zr, Ti)O$_3$ ceramics with the addition of WO$_3$ wt% to search for its required characteristics. Dielectric constant was increased as a function of the increase of WO$_3$ wt%. The Pb(Zr, Ti)O$_3$ (EC-65) ceramics added with 0.1lwt% WO$_3$ showed excellent dielectric constant and piezoelectric constants of 1931 and 199.55$\times$10$^{-12}$ (C/N), respectively. Accordingly It was shown as the composition ceramics suitable for AE sensor.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.1022-1028
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• 1997

This work was performed to study the characteristics of electrochemical intercalation reactions occurring at the interface between the organic electrolyte and tungsten trioxide thin film (thickness of $4000{\AA}$) prepared by e-beam evaporation method as cathodically coloring oxide with regard to the electrochromism by the intercalating reactions of the lithium cation in the 1M $LiClO_4/PC$ organic solution. The characteristics of electrochemical intercalation reactions were investigated by various DC electrochemical methods such as cathodic Tafel polarization test, multiple and the single sweep cyclic voltammetry and the coulomety titrations method. The surfaces of thin films were observed with the patterns of X ray diffraction after the coloring and bleaching reactions. In comparison with the previous results that $WO_3$ thin film intersely detached from the surface of electrode when the hydrogen cation was intercalated into $WO_3$ thin film in the o.1N $H_2SO_4$ aqueous solution, the intercalation reaction of lithium cation into $WO_3$ thin film in the 1M $LiClO_4/PC$ organic solution was shown that the stable bleaching and coloration was appeared within 1.0V of the applied overpotential. When the overpotential of electrochromic reaction for lithium cation in the 1M $LiClO_4/PC$ organic solution had been applied up to 1.5V, the accumulation phenomenon of lithium in amorphous $WO_3$ thin film layer occurred because the inserted lithium into amorphous $WO_3$ thin layer for coloring process was not fully removed from the thin layer to the electrolyte during bleaching process. It was found that there is a limitation of applied overpotential for coloring process by the reduction of the current densities of bleaching and coloration after few number of coloring and bleaching cycles.

• Applied Chemistry for Engineering
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• v.28 no.5
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• pp.576-580
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• 2017

In the present paper, the thermal deactivation characteristics of plate-type commercial $V_2O_5-WO_3/TiO_2$ SCR catalyst were investigated. For this purpose, the plate-type catalyst was calcined at different temperatures ranging from $500^{\circ}C$ to $800^{\circ}C$ for 3 hours. Structural and morphological changes were characterized byXRD, specific surface area, porosity, SEM-EDS and also NOx conversion with ammonia according to the calcine temperature. The NOx conversion decreased with increasing calcine temperature, especially when the catalysts were calcined at temperatures above $700^{\circ}C$. This is because the crystal phase of $TiO_2$ changed from anatase to rutile, and the $TiO_2$ grain growth and $CaWO_4$ crystal phase were formed, which reduced the specific surface area and pore volume. In addition, $V_2O_5$, which is a catalytically active material, was sublimated or vaporized over $700^{\circ}C$, and a metal mesh used as a support of the catalyst occurred intergranular corrosion and oxidation due to the formation of Cr carbide.

• Korean Journal of Metals and Materials
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• v.49 no.8
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• pp.596-600
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• 2011

Thermal degradation behavior of a $WO_3-TiO_2$ monolithic catalyst was investigated in terms of structural, morphological, and physico-chemical analyses. The catalyst with 4 wt.% $WO_3$ contents were prepared by a wet-impregnation method, and a durability test of the catalysts were performed in a temperature range between $400^{\circ}C$ and $800^{\circ}C$ for 3 h. An increase of thermal stress decreased the specific surface area, which was caused by grain growth and agglomeration of the catalyst particles. The phase transition from anatase to rutile occurred at around $800^{\circ}C$ and a decrease in the Brønsted acid sites was confirmed by structural analysis and physico-chemical analysis. A change in Brønsted acidity can affect to the catalytic efficiency; therefore, the thermal degradation behavior of the $WO_3-TiO_2$ catalyst could be explained by the transition to a stable rutile phase of $TiO_2$ and the decrease of specific surface area in the SCR catalyst.