• Title/Summary/Keyword: WC Alloy

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Behaviors of Cavitation Damage in Seawater for HVOF Spray Coated Layer with WC-10Co4Cr on Cu Alloy (WC-10Co4Cr으로 초고속 화염용사 코팅된 Cu 합금의 해수내 캐비테이션 손상 거동)

  • Han, Min-Su;Kim, Min-Sung;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.45 no.6
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    • pp.264-271
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    • 2012
  • Due to the good corrosion resistance and machinability, copper alloy is commonly employed for shipbuilding, hydroelectric power and tidal power industries. The Cu alloy, however, has poor durability, and the seawater application at fast flow condition becomes vulnerable to cavitation damage leading to economic loss and risking safety. The HVOF(High Velocity Oxygen Fuel) thermal spray coating with WC-10Co4Cr were therefore introduced as a replacement for chromium or ceramic to minimize the cavitation damage and secure durablility under high-velocity and high-pressure fluid flow. Cavitation test was conducted in seawater at $15^{\circ}C$ and $25^{\circ}C$ with an amplitude of $30{\mu}m$ on HVOF WC-10Co4Cr coatings produced by thermal spray. The cavitation at $15^{\circ}C$ and $25^{\circ}C$ exposed the substrate in 12.5 hours and in 10 hours, respectively. Starting from 5 hours of cavitation, the coating layer continued to show damage by higher than 160% over time when the temperature of seawater was elevated from $15^{\circ}C$ to $25^{\circ}C$. Under cavitation environment, although WC-10Co4Cr has good wear resistance and durability, increase in temperature may accelerate the damage rate of the coating layer mainly due to cavitation damage.

Synthesis of Ultrafine TiC-5%Co Powder by Using Co Nitrate and TiO(OH)2 Slurry and Evaluation of Sintered Materials Prepared by Mixing WC-Co (Co 질산염과 TiO(OH)2 슬러리를 이용한 초미립 TiC-5%Co 제조 및 WC-Co 분말과의 혼합에 따른 소결체 특성)

  • Hong, Seong-Hyeon;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.107-113
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    • 2008
  • Ultrafine TiC-5%Co powders were synthesized by spray drying of aqueous solution of TiO$(OH)_2$ slurry and cobalt nitrate, followed by calcination and carbothermal reaction. The oxide powders with carbon powder was reduced and carburized at $900^{\circ}C{\sim}1250^{\circ}C$ under hydrogen atmosphere. During reduction, CO gas was mainly evolved by reducing reaction of oxides. Ultrafine TiC-5%Co powders were easily formed by carbothermal reaction at $1250^{\circ}C$ due to using ultrafine powders as raw materials. The ultrafine WC-TiC-Co alloy prepared by sintering of mixed powder of ultrafine WC-13%Co powder and ultrafine TiC-5%Co powder has higher sintered density and mechanical properties than WC-TiC-Co alloy prepared by commercial WC, TiC and Co powders.

Microstructure Features of Large Grains in WC-Co Alloys

  • Delanoe, A.;Lay, S.;Missiaen, J.M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.650-651
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    • 2006
  • This paper presents a study of large grains by transmission electron microscopy in two WC-Co alloys, one W rich and one C rich. In the W rich alloy, some large grains are found in contact with the $\eta$ phase. The C content influences the morphology of large grains: they are flatter in the C rich alloy with smoother interfaces. Whatever the C content, they contain few dislocations compared to matrix grains except often in a small area. Small WC grains are often found inside the large grains. They have likely been engulfed during the growth of the large grains owing to the low boundary energy.

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Comparison of HVOF Thermal Spray Coatings of T800 and WC-Co Powders

  • Cho, T.Y.;Yoon, J.H.;Kim, K.S.;Baek, N.K.;Song, K.O.;Youn, S.J.;Hwang, S.Y.;Chun, H.G.
    • Journal of the Korean institute of surface engineering
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    • v.39 no.6
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    • pp.295-301
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    • 2006
  • Hard chrome plating has been used in surface hard coating over 50 years both for applying hard coating and re-building of worn components. Hard chrome plating solution and mist pollute environment with very toxic $Cr^{6+}$(hex-Cr) known as carcinogen which causes lung cancer, High velocity oxy-fuel (HVOF) thermal spray coatings of WC base cermet and Co-alloy powders are the most promising candidates for the replacement of the traditional hard chrome plating. Surface properties, wear, and friction behaviors of micron size Co-alloy (T800) and micron size WC-l2Co (WC-Co) have been studied for the application as hard coatings. The temperature dependence of wear and friction behaviors of T800 and WC-Co have been investigated at the temperature of $25^{\circ}C$ and $538^{\circ}C$ for the application to high speed spindle.

Effects of Sand Blasting on TiAlN Coating on WC Hard Metal Alloy Tip (WC위 TiAlN 코팅층에 미치는 Sand Blasting 처리의 영향)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.37 no.2
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    • pp.54-61
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    • 2021
  • The effect of the sand blasting before TiAlN coating in the manufacture of WC hard metal alloy tips have been studied. For four different tips, according to the status of processing of the sand blasting and the coating, residual stress measurement by X-ray diffraction and several tests for mechanical properties have been conducted. The results suggest that there was no difference in static mechanical properties, such as hardness, surface roughness and elastic modulus, between two coatings. Furthermore, compressive residual stress was generated equally on their surfaces. Additionally, the compressive residual stress in substrate WC was found to increase greatly when subjected to sand blasting treatment. However, the compressive residual stress decrease after coating regardless of sand blasting treatment. Nevertheless, it is confirmed that the compressive residual stress generated in the coating after sand blasting is less than that in the non-sandblasting coating. This was attributed to the plastic deformation occurring in the WC substrate during coating after sand blasting. In contrast to the scratch test results, sand blasting was assumed to have a negative effect on the adhesion between the coating and substrate. This is because there is a high possibility of microcracks due to plastic deformation in the WC substrate under the coating after sand blasting.

Development of Uniaxial Tensile Test Method to Evaluate Material Property of Tungsten Carbide-Cobalt Alloys for Cold Forging Dies (냉간단조 금형 WC-Co합금의 인장시험방법 개발 및 물성평가)

  • Kwon, I.W.;Seo, Y.H.;Jung, K.H.
    • Transactions of Materials Processing
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    • v.27 no.6
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    • pp.370-378
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    • 2018
  • Cold forging, carried out at room temperature, leads to high dimensional accuracy and excellent surface integrity as compared to other forging methods such as warm and hot forgings. In the cold forging process, WC-Co (Tungsten Carbide-Cobalt) alloy is the mainly used material as a core dies because of its superior hardness and strength as compared to other structural materials. For cold forging, die life is the most significant factor because it is directly related to the manufacturing cost due to periodic die replacement in mass production. To investigate die life of WC-Co alloy for cold forging, mechanical properties such as strength and fatigue are essentially necessary. Generally, uniaxial tensile test and fatigue test are the most efficient and simplest testing method. However, uniaxial tension is not efficiently application to WC-Co alloy because of its sensitivity to alignment of the specimen due to its brittleness and difficulty in thread machining. In this study, shape of specimen, tools, and testing methods, which are appropriate for uniaxial tensile test for WC-Co alloy, are proposed. The test results such as Young's modulus, tensile strength and stress-strain curves are compared to those in previous literature to validate the proposed testing methods. Based on the validation of test results it was concluded that the newly developed testing method is applicable to other cemented carbides like Titanium carbides with high strength and brittleness, and also can be utilized to carry out fatigue tests for further investigation on die life of cold forging.