• Title/Summary/Keyword: WAsP Engineering

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Effects of Microstructure and Surface Oil Film on the Welding in Zr Electroplated steel (전기아연도금 강에서 미세조직 및 표면유막이 용접 spatter에 미치는 영향)

  • 최한철;최수찬;김광연;안덕수;김영우
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.13-22
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    • 1997
  • In order to investigate the effects of microstructure Oil film on the welding spatter in Zn electroplated steel, Zn electroplated surface and layer structure with USS-Paddition was observed using XRD, XPS and optical microscopy. Wettability of water drop on the Zn electroplated steel surface was measured using Z.Mei model. Oil absorption test was carried out using Oil pen. Morphology of spot welding and spatter with USS-P addition, applied current, and oil-spray or oil-without was observed using SEM and optical microscopy. Surface morphology of Zn electroplated steel showed finer structure as USS-P content increased. Wettabiliy on the Zn electroplated surface decreased with increasing USS-P content. Size of welding trace increased and spatter occured arround the welding part as applied current increased, whereas spatter disappeared as USS-P content increased and disappeared in case of oil spraying on the Zn electroplated surface.

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Effect of Benzo[a]pyrene on Genes Related to the Cell Cycle and Cytochrome P450 of Saccharomyces cerevisiae

  • Lee, Hyun-Joo;Gu, Man-Bock
    • Journal of Microbiology and Biotechnology
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    • v.13 no.4
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    • pp.624-627
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    • 2003
  • Benzo[a]pyrene (B[a]P) is an environmental pollutant that has been implicated in carcinogenesis. Saccharomyces cerevisiae was treated with B[a]P, and the responses of its cytochrome P450 (CYP) enzyme and DNA-damage checkpoint genes were examined through gene expression profiles using a reverse transcription polymerase chain reaction (RT-PCR). The DNA-damage checkpoint genes tested were the chk1 and pds1 genes, involved in a metaphase arrest, the swi6 gene targeted by G1 arrest, the pol2 gene related to S phase arrest, and the cln2 gene encoding a cyclin protein, all of which are based on rad9 and rad24. Among these genes, no noticeable effect was found when the cells were exposed to various concentrations of B[a]P. However, the transcriptional activity of CYP51 was significantly different when the cells were exposed to B[a]P. Accordingly, the present results indicate that cytochrome P450 plays a more significant role than DNA-damage checkpoint genes in the response of S. cerevisiae to B[a]P.

NH3 and H2S Removal Characteristics on Spherical Carbons: Synergistic Effect between Activated Carbon and Zeolite Composites

  • Ye, Shu;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.726-732
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    • 2016
  • In this study, we used activated carbon(AC) as a carbon source, along with zeolite, to prepare spherical carbons using sucrose, starch and phenolic resin(PR) as binder material. The physicochemical characteristics of the three samples(AZ4P, AZ6P and AZ8P) were examined by BET, XRD, SEM, EDX, $H_2S/NH_3$ gas adsorption, compressive strength and ignition test techniques. Through comparative analysis of the compressive strength and ignition test results the AZ8P sample was found to have the best hardness and the highest temperature resistance capacity. After activation, the AZ8P sample had the best $H_2S$ adsorption capacity, and AZ6P was the most suitable for the adsorption of ammonia.

Hydrolysis of p-N itrophenyldiphenylphosphate by Dichloroisocyanuric Acid Sodium Salt (Dichloroisocyanuric Acid Sodium Salt에 의한 p-Nitrophenyl Diphenyl Phosphate의 가수분해 반응)

  • Lee, Yong-Han;Park, Hoon;Choi, Kui-Nam;Chang, Sung-Il;Kim, Tae-Heung
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.114-120
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    • 1994
  • Esterolysis reactions of PNPDPP (p-nitrophenyldiphenylphosphate) by DCI ( dichloroisocyanuric acid sodium salt) in borate buffer pH8.0 micellar phase were studied. The rate of hydrolysis reaction was rapidly increased by adding cationic surfactants, CTAC (cetyltrimethylammonium chloride) or CTAB (cetyltrimethylammonium bromide), to the DCI solution. Especially in CTAB micellar system, the N-Cl bond of DCI was transformed to the N-Br bond during the reaction.

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Comparison of Deposition Behavior and Properties of Cyanide-free Electroless Au Plating on Various Underlayer Electroless Ni-P films

  • Kim, Dong-Huyn
    • Journal of the Korean institute of surface engineering
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    • v.55 no.4
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    • pp.202-214
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    • 2022
  • Internal connections between device, package and external terminals for connecting packaging and printed circuit board are normally manufactured by electroless Ni-P plating followed by immersion Au plating (ENIG process) to ensure the connection reliability. In this study, a new non-cyanide-based immersion and electroless Au plating solutions using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent was investigated on different underlayer electroless Ni-P plating layers. As a result, it was confirmed that the deposition behavior and film properties of electroless Au plating are affected by grain size and impurity of the electroless Ni-P film, which is used as the plating underlayer. Au plating on the electroless Ni-P plating film with a dense surface structure showed the highest bonding strength. In addition, the electroless Au plating film on the Ni-P plating film has a smaller particle size exhibited higher bonding strength than that on the large particle size.

Comparison of the Nutritional Composition of Bullfrog Meat from Different Parts of the Animal

  • Zhu, Yanli;Bao, Min;Chen, Chong;Yang, Xiaoli;Yan, Wenliang;Ren, Fazheng;Wang, Pengjie;Wen, Pengcheng
    • Food Science of Animal Resources
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    • v.41 no.6
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    • pp.1049-1059
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    • 2021
  • The objective of this study was to evaluate the nutritional content of bullfrog meat from different parts of the animal, including fore-chest, thigh and calf. Bullfrog meat was found to be a rich source of proteins, essential amino acids and minerals, but with a low fat content, compared with other aquatic meat products. There was no significant difference (p>0.05) between thigh and calf in mineral content (K, P, Na, Mg, Ca, Zn, Fe, Cu, and Mn), but the contents of K, P, and Mg were higher in thigh and calf than in the fore-chest (p<0.05). The salt-soluble, water-soluble and insoluble protein bands in sodium dodecyl sulphate-polyacrylamide gel electrophoresis (SDS-PAGE) electrophoresis, from fore-chest, thigh and calf were similar, with the most abundant bands being 35 kDa (salt-soluble protein), 35-48 kDa (water-soluble protein) and 48 kDa (insoluble protein). The results showed that the insoluble protein content in the fore-chest meat was higher than that in the thigh meat and calf meat, but the salt-soluble protein fraction was the most abundant in thigh meat. These results showed that the nutrients in different parts of bullfrog meat were different.

Effect of Molecular Structures on the Solubility Enhancement of Organic Contaminants by Amphiphiles (양수성 물질에 의한 유기오염물질의 수중 용해도 증가에 분자구조가 미치는 영향)

  • Cho, Hyun-Hee;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.755-764
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    • 2000
  • Fate and transport of hydrophobic organic contaminants can be influenced by naturally-existing humic substances and surfactants applied to wash polluted soils in the subsurface environment. The objective of this paper is to study the solubility enhancement of four PAHs (polycyclic aromatic hydrocarbon) and p,p'-DDT in humic acid and surfactant solutions. As the number of aromatic ring is increased, the extent of solubility enhancement of PAHs by humic acid increased. Although the hydrophobicity of p,p'-DDT was the largest among five organic compounds used, the extent of solubility enhancement of p,p'-DDT by humic acid was lower than that of pyrene. In case of anionic surfactants, the extent of the increased solubility of five organic compounds by SDS and SDDBS was increased linearly, but the extent of the increased solubility of p,p'-DDT by MADS-12 was lower than that of perylene.

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Textile dye wastewater treatment using coriolus versicolor

  • Sathian, S.;Radha, G.;Priya, V. Shanmuga;Rajasimman, M.;Karthikeyan, C.
    • Advances in environmental research
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    • v.1 no.2
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    • pp.153-166
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    • 2012
  • Decolourization potential of white rot fungal organism, coriolus versicolor, was investigated in a batch reactor, for textile dye industry wastewater. The influence of process parameters like pH, temperature, agitation speed and dye wastewater concentration on the decolourization of textile dye wastewater was examined by using Response surface methodology (RSM). The maximum decolourization was attained at: pH- 6.8, temperature - $27.9^{\circ}C$, agitation speed - 160 rpm and dye wastewater concentration - 1:2. From the analysis of variance (ANOVA) results it was found that, the linear effect of agitation speed and dye wastewater concentration were significant for the decolourization of textile dye wastewater. At these optimized condition, the maximum decolourization and chemical oxygen demand (COD) reduction was found to be 64.4% and 79.8% respectively. Various external carbon sources were tried to enhance the decolourization of textile dye wastewater. It was observed that the addition of carbon source enhances the decolourization of textile dye wastewater. Kinetics of textile dye degradation process was studied by first order and diffusional model. From the results it was found that the degradation follows first order model with $R^2$ value of 0.9430.

A Fluorescent Sensor Film for Detecting pH of Acidic Solutions (산성 용액의 pH를 감지할 수 있는 형광 센서막)

  • Min, Jae Young;Kim, Hyung Jin
    • Journal of the Korean Chemical Society
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    • v.64 no.2
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    • pp.74-78
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    • 2020
  • A push-pull conjugated dye (DCMP) was covalently immobilized on a silanized glass surface to produce a high sensitivity pH sensor film for operating in the acidic region. A pH-sensitive sensor film was prepared by photo-initiating copolymerization of a modified DCMP (DCMA), 2-hydroxyethyl methacrylate (HEMA) and triethylene glycol dimethacrylate on the silanized glass surface. The absorbance of the sensor film increased with increasing pH between pH 2.0 and 5.0, and the fluorescence intensity of the film also increased about 50 times with increasing pH in the same pH range. The sensor film was reversible and reproducible under acidic conditions. The sensor film showed a relatively short response time between 20-50 seconds and high selectivity for proton in the presence of various metal ions.

Effect of operational pH on anaerobic hydrogen fermentation of food waste (음식폐기물의 혐기성 수소 발효시 운전 pH의 영향)

  • Lee, Chae-Young;Lee, Se-Wook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.73-78
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    • 2011
  • The pH is one of the most important factors affecting metabolism pathway and activity of hydrogen producing bacteria. The effect of operational pH on anaerobic hydrogen fermentation of food waste was evaluated at mesophilic condition. In this batch experiment, the initial pH was 8.0 and the operational pH was controlled at 4.7~7.0 by the addition of 5N KOH solutions. At the operational pH of 4.7, the lag phase and the maximum hydrogen production were 47.9h and 534.4 mL, respectively. The lag phase and the maximum hydrogen production were decreased as the operational pH increased. At the operational pH of 7.0, the lag phase and the maximum hydrogen production were 4.2 h and 213.8 mL, respectively.