• Title/Summary/Keyword: WAsP Engineering

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Structure and Electrical Properties of P-doped ZnO Thin Films with Annealing Temperatures (열처리 온도에 따른 P-doped ZnO 박막의 구조적 및 전기적 특성)

  • Han, Jung-Woo;Yoon, Yung-Sup;Kang, Seong-Jun;Joung, Yang-Hee
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.501-502
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    • 2008
  • In this study, P-doped ZnO thin films were prepared on sapphire substrates by pulsed laser deposition and annealing method. The electrical properties were investigated as a function of annealing temperatures at a fixed oxygen pressure. The XRD measurement showed that p-doped ZnO thin films were c-axis oriented. The Hall measurement showed that p-type ZnO thin film was observed. The carrier concentration of $1.18{\times}10^{16}cm^{-3}$ and the mobility of $0.96\;cm^{-3}/Vs$ were obtained for the P-doped ZnO thin film fabricated annealing temperature $850^{\circ}C$.

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Development of Porous Co-P Catalyst for Hydrogen Generation by Hydrolysis of $NaBH_4$ (Sodium Borohydride의 수소발생을 위한 다공성 Co-P 촉매 개발)

  • Cho, Keun-Woo;Eom, Kwang-Sub;Kwon, Hyuk-Sang
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.4
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    • pp.448-453
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    • 2006
  • Porous Co-P catalysts electroplated on Cu in chloride based solution with an addition of $NaH_2PO_2$ and glycine were developed for hydrogen generation from alkaline $NaBH_4$ solution. The microstructures of the Co-P catalysts and their hydrogen generation properties were analyzed as a function of cathodic current density and plating time during the electrodeposition. Amorphous Co-P electrodeposits with porous structure was formed on Cu at cathodic current density of $0.05\;A/cm^2$, and showed very high hydrogen generation rate in alkaline $NaBH_4$ solution due to an increase in the surface area of the catalyst as well as the catalytic activity. The Co-P catalyst, which was obtained at cathodic current density of $0.05\;A/cm^2$ for 5 min, exhibited the best hydrogen generation rate of 2290 ml/min.g-catalyst in 1 wt. % NaOH+10 wt. % $NaBH_4$ solution at $30^{\circ}C$.

Fabrication of Poly(ethylene oxide)/Ag Nanoparticles/p-benzoquinone Composite Membrane Using AgNO3 Precursor for Olefin/Paraffin Separation (올레핀/파라핀 분리용 AgNO3 전구체를 활용한 poly(ethylene oxide)/Ag nanoparticles/p-benzoquinone 복합체 분리막 제조)

  • kim, Minsu;Kang, Sang Wook
    • Membrane Journal
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    • v.28 no.4
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    • pp.260-264
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    • 2018
  • Poly (ethylene oxide) (PEO)/Ag nanoparticles (AgNPs)(precursor : $AgBF_4$)/p-benzoquinone (p-BQ) composite membrane was prepared for olefin/paraffin separation. As a result, the performance of composite membrane was observed to be maintained at selectivity of 10 and permeance of 15 GPU up to 100 hours. The performance of the membrane was maintained for 100 hours was attributable to that Ag ions could be converted into stable Ag NPs by addition of p-BQ. Furthermore, the surface was partially polarized by the electron acceptor p-BQ, resulting in the formation of olefin carrier. In this study, since the cost of $AgBF_4$ used as a precursor of Ag NPs was relatively higher, $AgNO_3$ was utilized. As a result, it was confirmed that $AgNO_3$ couldn't show the stable formation of nanoparticle, resulting in the poor separation performance.

Development of High Frequency pMUT Based on Sputtered PZT

  • Lim, Un-Hyun;Yoo, Jin-Hee;Kondalkar, Vijay;Lee, Keekeun
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2434-2440
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    • 2018
  • A new type of piezoelectric micromachined ultrasonic transducer (pMUT) with high resonant frequency was developed by using a thin lead zirconate titanate (PZT) as an insulation layer on a floating $10{\mu}m$ silicon membrane. The PZT insulation layer facilitated acoustic impedance matching at active pMUT, leading to a high performance in the acoustic conversion property compared with the transducer using $SiO_2$ insulation layer. The fabricated ultrasonic devices were wirelessly measured by connecting two identical acoustic transducers to two separate ports in a single network analyzer simultaneously. The acoustic wave emitted from a transducer induced a $3.16{\mu}W$ on the other side of the transducer at a distance of 2 cm. The transducer performances in terms of device diameters, PZT thickness, annealings, and different DC polings, etc. were investigated. COMSOL simulation was also performed to predict the device performances prior to fabrication. Based on the COMSOL simulation, the device was fabricated and the results were compared.

Optimization of diesel biodegradation by Vibrio alginolyticus using Box-Behnken design

  • Imron, Muhammad Fauzul;Titah, Harmin Sulistiyaning
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.374-382
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    • 2018
  • Petroleum hydrocarbons pollutants, such as diesel fuel, have caused ecosystem damage in terrestrial and aquatic habitats. They have been recognized as one of the most hazardous wastes. This study was designed to optimize the effect of Tween 80 concentration, nitrogen (N)/phosphorus (P) ratio and salinity level on diesel biodegradation by Vibrio alginolyticus (V. alginolyticus). Response surface methodology with Box-Behnken design was selected with three factors of Tween 80 concentration (0, 5, 10 mg/L), N/P ratio (5, 10, 15) and salinity level (15‰, 17.5‰, 20‰) as independent variables. The percentage of diesel degradation was a dependent variable for 14 d of the remediation period. The results showed that the percentages of diesel degradation generally increased with an increase in the amount of Tween 80 concentration, N/P ratio and salinity level, respectively. The optimization condition for diesel degradation by V. alginolyticus occurred at 9.33 mg/L of Tween 80, 9.04 of N/P ratio and 19.47‰ of salinity level, respectively, with percentages of diesel degradation at 98.20%. The statistical analyses of the experimental results and model predictions ($R^2=0.9936$) showed the reliability of the regression model and indicated that the addition of biostimulant can enhance the percentage of diesel biodegradation.

Fabrication of Multi-Layered Graphenes/P(S-co-BA) Nanocomposite via Sudden Heating Heterocoagulation Process

  • Choi, JinKyu;Lee, Eun-Kyoung;Shim, Sang Eun
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.272-279
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    • 2017
  • The heterocoagulation of latex is a simple and useful method to fabricate various polymer nanocomposites in which a precise control of the colloid stability is essential. In this work, a multi-layered graphenes (MLGs)/poly(styrene-co-butyl acrylate) (P(S-co-BA)) nanocomposite having an excellent dispersion of MLGs was prepared via the sudden heating heterocoagulation process. The P(S-co-BA) component was obtained by emulsion polymerization. This process can effectively shorten the process and particles growth steps. The colloid stability of these dispersions was controlled by factors such as ionic charge, temperature, and reaction times. The influence of these factors on heterocoagulation was evaluated and the properties of the nanocomposites were investigated. The conductivity of the MLGs/P(S-co-BA) nanocomposites increased from -11.53 to -5.70 S/cm for an increase in MLG content from 0.01 to 5 wt%. Moreover, percolation threshold was observed in the case of 0.01 wt% MLGs.

Hydrogen Production by Biological Processes

  • Shin Jong-Hwan;Park Tai Hyun
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2004.05a
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    • pp.101-104
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    • 2004
  • Among biological hydrogen production processes, fermentative processes have some advantages. In this research, the hydrogen producing bacterium was isolated from domestic landfill area and identified as Enterobacter sp. The strain was named Enterobacter sp. SNU-1453. Important parameters for the hydrogen process include pH, temperature, concentration of initial glucose, and kind of sugars. The pH of the culture medium significantly decreased as fermentation proceeded due to the accumulation of various organic acids, and this inhibited the $H_2$ production seriously. When pH was controlled at pH 7.0, hydrogen production was 2614.5 m1/1 in 17 hours. The increase of glucose concentration resulted in higher $H_2$ production. The productivity of this strain was 6.87 mmol $H_2/l$ per hi on concentration of 25g glucose/l. Enterobacter sp. SNU-1453 could utilize various sugars. These results indicate that Enterobacter sp. SNU-1453 has a high potential as a fermentative $H_2$ producer.

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Production of Automobile Al Wheel by Low-Pressure Die Casting (I) : Flow and Solidification Simulation (저압주조에 의한 자동차 Al Wheel의 제조(I) : 유동 및 응고해석)

  • Choo, In-Ho;Yu, Sung-Kon;Choi, Jeong-Kil
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.578-585
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    • 1998
  • A multi-purpose code MAGMA was employed for mold design and process control in producing Al wheel by lowpressure die casting. Three-dimensional solid modeling was followed by mesh generation of casting and molds(top, bottom and side). The simulation of stability of casting cycle time, mold filling simulation with pressure variation from P1 to P2, solidification simulation by solidification time and feeding criteria, and temperature distribution of molds during processes were studied in this research. The thermal stability of molds was attained after 5 cycles when molds were preheated at $400^{\circ}C$. The pressure increase from P1 to P2 for mold filling was evaluated as slightly higher, and 6 seconds were taken for the mold filling. The cycle time was believed to be designed properly judged from the solidification time of casting and open/close time of molds.

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Variation of the Nanostructural and Optical Features of Porous Silicon with pH Conditions (pH 조건에 따른 기공성 실리콘의 나노구조 및 광학적 특성의 변화)

  • Kim, Hyo-Han;Cho, Nam-Hee
    • Journal of the Korean Ceramic Society
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    • v.50 no.4
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    • pp.294-300
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    • 2013
  • The effect of chemical treatments of porous silicon in organic solvents on its nanostructural and optical features was investigated. When the porous Si was dipped in the organic solvent with various PH values, the morphological, chemical, and structural properties of the porous silicon was sensitively affected by the chemical conditions of the solvents. The size of silicon nanocrystallites in the porous silicon decreased from 5.4 to 3.1 nm with increasing pH values from 1 to 14. After the samples were dipped in the organic solvents, the Si-O-H bonding intensity was increased while that of Si-H bonding decreased. Photoluminescence peaks shifted to a shorter wavelength region in the range of 583 to 735 nm as the pH value increased. PL intensity was affected by the size as well as the volume fraction of the nanocrystalline silicon in the porous silicon.

A highly integrable p-GaN MSM photodetector with GaN n-channel MISFET for UV image sensor system

  • Lee, Heon-Bok;Hahm, Sung-Ho
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.346-349
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    • 2008
  • A metal-semiconductor-metal (MSM) ultraviolet (UV) photodetector (PD) is proposed as an effective UV sensing device for integration with a GaN n-channel MISFET on auto-doped p-type GaN grown on a silicon substrate. Due to the high hole barrier of the metal-p-GaN contact, the dark current density of the fabricated MSM PD was less than $3\;nA/cm^2$ at a bias of up to 5 V. Meanwhile, the UV/visible rejection ratio was 400 and the cutoff wavelength of the spectral responsivity was 365 nm. However, the UV/visible ratio was limited by the sub-bandgap response, which was attributed to defectrelated deep traps in the p-GaN layer of the MSM PD. In conclusion, an MSM PD has a high process compatibility with the n-channel GaN Schottky barrier MISFET fabrication process and epitaxy on a silicon substrate.