• 제목/요약/키워드: W/Mo

검색결과 759건 처리시간 0.027초

텅스텐 첨가에 따른 바나듐 막의 상전이 특성 변화에 대한 연구 (Phase transition properties of tungsten contained vanadium oxides film)

  • 최종범;조정호;이용현;최병열;이문석;김병익;신동욱
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.208-209
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    • 2005
  • 바나듐 산화물은 반도성-금속성으로 상전이 하는 CTR특성의 대표적인 산화물로 상전이 온도인 68$^{\circ}C$에서 저항의 급변 특성을 보인다. 여기에 Fe, Ni, Mo, Ti, W과 같은 금속성 산화물을 첨가함에 따라 상전이온도를 움직일 수 있다. 그중 $WO_3$를 첨가함으로써 상전이온도를 상온까지 낮출 수 있다. Inorgnic sol-gel 법에 의해 바나듐-텅스텐 sol을 제조 하였으며, 제조된 sol을 기판에 코팅한 후 환원분위기에서 열처리 하여 막을 얻었다. 온도-저항 특성 측정 결과 순수 바나듐 막은 상전이 온도는 68$^{\circ}C$ 전기저항 감소폭은 $10^4$order 이였으나 바나듐-텅스텐막의 상전이 온도는 38$^{\circ}C$, 전기저항 감소폭은 $10_{15}$order 로 감소함을 확인 하였다.

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희박-예혼합 저 NOx 연소기 설계에 대한 연구 (The Study for Designs of Lean-Premixed low NOx Combustor)

  • 임암호;김한석;안국영;이상민;김용모
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.83-88
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    • 2003
  • The concept of lean-premixed combustion in gas turbine combustor operation has become a standard in recent years as an effective means to meet stringent environmental standards on NOx emissions. Various types of air-fuel premixer, which affect greatly NOx emission and stability of lean-premixed low NOx combustor, were investigated experimentally to reduce the NOx emission. One type of the premixers is selected by experiments and applied it to 70kW class lean-premixed gas turbine combustor. The exit temperature and emissions of CO and NOx were measured with equivalence ratios at ambient pressure. From the results, the emissions of CO and NOx were influenced by the type of air-fuel premixer. As the mixing length of air and fuel is longer, the NOx and CO emission were decreased in the primary reaction zone. Compared with of conventional combustor, the lean-premixed low NOx combustor has low NOx emission characteristics.

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적외선 열화상 메카니즘과 Flex-PDE 열해석을 통한 STS 결함구조물 진단 (STS Defect Structure Diagonis through the Infrared Thermography Mechanism and Flex-PDE Thermal Analysis)

  • 박영훈;양성모
    • 한국자동차공학회논문집
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    • 제22권4호
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    • pp.20-29
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    • 2014
  • This research aims to study the new paradigm of NDE measurement which allows the identification of defect locations and sizes of a certain structure by measuring its surface temperature after applying heat. STS which has a certain defect is applied by the heat of 70000W by a heater. Its difference of STS surface temperature is measured by using Infrared thermography. The estimated result of STS experiment and that of theoretical analysis of Flex-PDE are compared and analyzed to diagnose STS defect. Moreover, this study can save time and money and improve accuracy in contrast to the existing ultrasonic NDE experiment. In addition, the new paradigm of NDT/NDE by reverse-engineering will be valid if the data of thermal analysis and temperature distribution from the specifications of many materials is accumulated and verified.

Epitaxial growth of Pt Thin Film on Basal-Plane Sapphire Using RF Magnetron Sputtering

  • 이종철;김신철;송종환;이충만
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.41-41
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    • 1998
  • Rare earth metal films have been used as a buffer layer for growing ferroelectric t thin film or a seed layer for magnetic multilayer. But when it was deposited on s semiconductor substrates for the application of magneto-optic (MO) storage media, it i is difficult to exactly measure magnetic cons떠nts due to shunting current, and so it n needs to grow metal films on insulator substrate to reduce such effect. Recently, it w was reported that ultra-thin Pt layer were epitaxially grown on A12O:J by ion beam s sputtering in 비떠 high vacuum and it can be used as a seed layer for the growth of C Co-contained magnetic multilayer. In this stu$\phi$, Pt thin film were epi떠xially grown on AI2D3 ($\alpha$)OJ) by RF magnetron s sputtering. The crystalline structure was analyzed by transmission electron microscope ( (TEM) and Rutherford Back Scattering (RBS)/Ion Channeling. In TEM study, Pt was b believed to be twinned on AI잉3($\alpha$)01) su$\pi$ace about Pt(ll1) plane.Moreover, RBS c channeling spectra showed that minimum scattering yield of Pt(111)/AI2O:J(1$\alpha$)OJ) was 4 4% and Pt(11J)/AI2D3($\alpha$)OJ) had 3-fold symmetry.

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Effects of Rare Earth Metals Addition and Aging Treatment on the Corrosion Resistance and Mechanical Properties of Super Duplex Stainless Steels

  • 박용수;김순태;이인성;송치복
    • 소성∙가공
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    • 제8권3호
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    • pp.309-309
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    • 1999
  • Effects of rare earth metals addition and aging treatment on corrosion resistance and mechanical properties of super duplex stainless steels were investigated using optical/SEM/TEM metallographic examination, an X-ray diffraction test, a potentiodynamic anodic polarization test and a tensile test. The performance of the experimental alloy with 0.32% REM addition was compared with commercial super duplex stainless steel such as SAF 2507 when they were exposed to solution annealing heat treatment and aging treatment. The corrosion resistance in CF environments and mechanical properties of the experimental alloy were found superior to those of the commercial duplex stainless steel. The REM with larger atomic radii than those of Cr, Mo and W may fill vacancies inside the matrix and around the grain boundaries, retarding formation of harmful intermetallic σ and χ phases. In addition, fine REM oxides/oxy-sulfides (1-3㎛) seemed to enhance the retardation effects. With REM additions, strength and ductility increased due to the phase and grain refinement caused by fine REM oxides and oxy-sulfides.

Selenization 온도가 Cu2ZnSnSe4 박막의 특성에 미치는 영향 (Influence of Selenization Temperature on the Properties of Cu2ZnSnSe4 Thin Films)

  • 여수정;강명길;문종하;김진혁
    • Current Photovoltaic Research
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    • 제3권3호
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    • pp.97-100
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    • 2015
  • The kesterite $Cu_2ZnSnSe_4$ (CZTSe) thin film solar cells were synthesized by selenization of sputtered Cu/Sn/Zn metallic precursors on Mo coated soda lime glass substrate in Ar atmosphere. Cu/Sn/Zn metallic precursors were deposited by DC magnetron sputtering process with 30 W power at room temperature. As-deposited metallic precursors were placed in a graphite box with Se pellets and selenized using rapid thermal processing furnace at various temperature ($480^{\circ}C{\sim}560^{\circ}C$) without using a toxic $H_2Se$ gas. Effects of Selenization temperature on the morphological, crystallinity, electrical properties and cell efficiency were investigated by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD), J-V measurement system and solar simulator. Further details about effects of selenization temperature on CZTSe thin films will be discussed.

냉간금형 인서트(insert)용 주강의 미세조직 (Microstructure of Tool Steel Castings for Cold-Work Die Inserts)

  • 강전연;박준영;김호영;김병환
    • 열처리공학회지
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    • 제30권5호
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    • pp.197-206
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    • 2017
  • The microstructure of a high-carbon and high-chromium cast steel (HK700) for cold-work die inserts was analyzed by advanced scanning electron microscopy. A continuous network of primary $M_7C_3$ carbide was developed among austenitic matrix after casting. A small amount of $M_2C$ was added to the carbide network owing to the enrichment of Mo and W during the solidification. After quenching in which the austenitization was performed at $1030^{\circ}C$ and double tempering at $520^{\circ}C$, the network structure of $M_7C_3$ was preserved while most of the matrix was transformed to martensite because of additional carbide precipitation. The $M_2C$ in the as-cast microstructure was also transformed to $M_6C$ due to its instability. The continuous network of coarse carbides owing to the absence of hot-working had little influence on the hardness after quenching and tempering, whereas it resulted in severe brittleness upon flexural loading.

HL-60 세포에 대한 Triterpent Acids와 Ginsenosides의 분화효과 (Effects of Triterpence Acids and Ginsenosides in Differentiation of HL-60 Promyelocytic Leckemia Cells)

  • 강창모;이호영;김신일;김규원
    • 생명과학회지
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    • 제8권2호
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    • pp.162-166
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    • 1998
  • 전 골수성 백혈병 세초인 HL-60 세포를 model로 하여, 민간요법으로 사용되어져 부작용이 극히 적은 거승로 알려진 고려인삼의 구성 성분 중 주요성분이 ginseng (Panzx ginseng C.A. Meyer) saponin 및 ginsenoside Rh1, Rh2, Rh3, 비파 (Eriobotrya japonica L.) 잎의 성분들 중에서 항발암 및 항암성분으로 알려진 ursolic acid 및 oleanolic acid, 웅담중의 중요성분 성분인 lithocholoc acid 드잉 분화능력이 있는 지를 조사하고자 본 실험을 수행아였다. Retinoic acid를 처리한 결과 타 연구자들의 연구결과들처럼 높은 분화력을 관찰할 수 있었으며, dbcAMP 단독 처리군에서도 높은 분화효과를 나타냈었다. Dexamethasone 처리군에서는 분화효과를 거의 관찰할 수 없었으나,dexamethansone과 구조적으로 유사한 ursolic acid와 oleanolic acid는 보다 높은 분화력을 보였고 웅담성분의 중요성분인 lirhocholic acid는 높은 분화력을 나타냈었다. Ginseng saponin은 0.00375% (w/v)에서 20% 이상의 분화력을 보였으며, Ginsenoside Rh2와 Rh3는 높은 분화력을 나타냈다.

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전자선 용해법에 의한 V의 정련 및 용해에 관한 연구 (A Study on Refining and Melting of V by Electron Beam Melting)

  • 김휘준;백홍구;윤우영;이진형;강춘식
    • 한국주조공학회지
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    • 제15권3호
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    • pp.235-241
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    • 1995
  • In order to improve the production process of low cost and high purity Vanadium, this study was done to reduce $V_2O_5$ into V-Al master alloy by Aluminothermic Reduction, followed by refining of V-Al master alloy electron beam melting. As melting time was increased in electron beam melting of V, the contents of interstitial impurities and Al, Fe were decreased but the contents of Si, Mo and W were increased due to lower vapor pressure of these elements than that of matrix V. Consequently, it was profitable that melting of V was done for 180 seconds. In addition, with number of melting, the purity of V did not significantly vary, because volatile impurities in V were removed mostly during the first step of melting. As a result of V refining by electron beam melting, high purity Vanadium of 3N(99.91wt%) was acquired including interstitial impurities total contents of which were maximum 400ppm.

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직접접촉식 RF MEMS 스위치에서의 미소용접 현상 억제 (Suppression of Microwelding on RF MEMS Direct Contact Switches)

  • 이태원;김성준;박상현;이호영;김용협
    • 한국항공우주학회지
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    • 제33권4호
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    • pp.41-46
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    • 2005
  • 본 연구에서는 고 전력의 RF 신호용 직접 접촉식 스위치에서 문제가 되고 있는 접촉부위에서의 미소용접에 의한 점착 현상을 감소시키기 위해, 고 융점 금속인 텅스텐(W)과 몰리브덴(Mo)을 스위치 접촉 부위에 코팅하여 스위치의 성능을 분석하였다. 스위치의 삽입손실과 신호격리도, 전력 손실 등의 변화를 네트워크 분석기, 전력 측정기 등을 통하여 측정하였다. 측정결과로부터 RF 신호 전송에 있어서 낮은 입력 전력에서는 고융점 금속이 금(Au)보다 접촉저항이 더 크지만 입력 전력이 커지면 비교적 낮은 비저항의 고융점 금속을 사용하는 것이 고전력 전송 및 수명 연장에 있어서 유리함을 밝혀냈다.