• Title/Summary/Keyword: Volume and Surface

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Characterization of the Microporosity of Activated Carbon Fiber (활성탄소섬유의 미세기공 특성화)

  • 진항교;이정민;유승곤
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.491-500
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    • 1993
  • The adsorption of nitrogen (77K) and carbon dioxide(273K) was performed on a series of activated carbon fiber. Theadsorption iotherm of nitrogen was typical type 1 and that of carbon dioxide was convex. As the specific surface area increases, there are linear increases in BET constant C mean pore diameter, the width of pore size distribution, wide micropore volume, total micropore volume, total pore volume and external surface area, however, narrow micropore volume was nealy constant . The total micorpore volume fraction in total pore volume is above 97%.

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Adsorption properties of surface - modified activated carbon (활성탄의 표면 구조 변화에 따른 흡착 특성 연구)

  • 김정렬;서문원;신창호;김영호;이근회;지상운
    • Journal of the Korean Society of Tobacco Science
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    • v.16 no.2
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    • pp.191-197
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    • 1994
  • Relationships between surface structure and adsorption properties of smoke components were investigated in surface-modified and un-modified activated carbon filter cigarettes. Commercially available activated carbon was treated with nitric acid and hydrogen peroxide as oxidant, and their pore volume, surface structure, BET surface area, pore type and size were studied. BET surface area and pore volume were decreased by nitric acid treatment, but median pore diameter was 8.1 $\AA$, which showed better development of pore compared with that of un-modified activated carbon, 6.9 $\AA$. In case of hydrogen peroxide treatment, BET surface area and pore volume were increased. Their pore was found to be a slit type based on V-t plot analysis. Neutralization capacities for bases of different strength (NaHCO3, Na2CO3, NaOEt and NaOH) showed that the majority of the acidic surface groups are of weak acidity. Modification of the activated carbon surface led to a slight change in adsorption properties when analyzing the smoke of triple-filter cigarette with surface-modified activated carbon.

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Comparative analysis on intaglio surface trueness, wear volume loss of antagonist, and fracture resistance of full-contour monolithic zirconia crown for single-visit dentistry under simulated mastication

  • Kim, Yong-Kyu;Yoon, Hyung-In;Kim, Dae-Joon;Han, Jung-Suk
    • The Journal of Advanced Prosthodontics
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    • v.14 no.3
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    • pp.173-181
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    • 2022
  • PURPOSE. This analysis aimed to evaluate the intaglio surface trueness, antagonist's wear volume loss, and fracture resistance of full-contour crowns of (Y, Nb)-stabilized fully-sintered zirconia (FSZ), 4 mol% or 5 mol% yttria-stabilized partially sintered zirconia (4YZ or 5YZ) with high-speed sintering. MATERIALS AND METHODS. A total of 42 zirconia crowns were separated into three groups: FSZ, 4YZ, and 5YZ (n = 14). The intaglio surface trueness of the crowns was evaluated at the inner surface, occlusal, margin, and axial areas and reported as root-mean-square, positive and negative average deviation. Half of the specimens were aged for 120,000 cycles in the chewing simulator, and the wear volume loss of antagonist was measured. Before and after chewing, the fracture load was measured for each group. The trueness values were analyzed with Welch's ANOVA, and the wear volume loss with the Kruskal-Wallis tests. Effect of the zirconia type and aging on fracture resistance of crowns was tested using two-way ANOVA. RESULTS. The intaglio surface trueness measured at four different areas of the crown was less than 50 ㎛, regardless of the type of zirconia. No significant P in wear volume loss of antagonists were detected among the groups (P > .05). Both the type of zirconia and aging showed statistically significant effects on fracture resistance (P < .05). CONCLUSION. The full-contour crowns of FSZ as well as 4YZ or 5YZ with high-speed sintering were clinically acceptable, in terms of intaglio surface trueness, antagonist's wear volume loss, and fracture resistance after simulated mastication.

Combustion characteristics in small combustion chamber that has high surface to volume ratio (고 표면적-체적 비를 가지는 소형 연소실 환경에서의 연소특성)

  • Lee, Dae-Hoon;Choi, Kwon-Hyoung;Kwon, Se-Jin
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.212-216
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    • 2000
  • Combustion phenomenon in scale-downed combustor is investigated. As the combustor volume decreases surface to volume ratio increases. for increased surface to volume ratio means increased heat loss and this increased heat loss affects reaction in combustion chamber. Plastic mini combustor is made. Stoichiometricaly premixed Hydrogen I air gas is used as fuel. Initial chamber pressure and chamber size are varied and the effects are evaluated. Peak pressure decreases with the decrease in chamber height. As initial chamber pressure decreases peak pressure decreases. And this change is more important than scale down effect till the chamber height of 1mm. With this result and further information following the experiments design parameter for micro engine can be established.

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A VOLUME OF FLUID METHOD FOR FREE SURFACE FLOWS AROUND SHIP HULLS (선체주위 자유수면 유동 해석을 위한 VOF법 연구)

  • Park, I.R.
    • Journal of computational fluids engineering
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    • v.20 no.1
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    • pp.57-64
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    • 2015
  • This paper describes a volume of fluid(VOF) method, mRHRIC for the simulation of free surface flows around ship hulls and provides its validation against benchmark test cases. The VOF method is developed on the basis of RHRIC method developed by Park et al. that uses high resolution differencing schemes to algebraically preserve both the sharpness of interface and the boundedness of volume fraction. A finite volume method is used to solve the governing equations, while the realizable ${\kappa}-{\varepsilon}$ model is used for turbulence closure. The present numerical results of the resistance performance tests for DTMB5415 and KCS hull forms show a good agreement with available experimental data and those of other free surface methods.

Surface modification characteristics of activated carbon fibers for hydrogen storage (수소저장용 활성탄소섬유의 표면개질 특성)

  • Kim, Shin-Dong;Kim, Ju-Wan;Im, Ji-Sun;Cho, Se-Ho;Lee, Young-Seak
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.47-54
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    • 2006
  • Activated carbon fibers (ACFs) with high surface area and pore volume were modified with metal Ni impregnation and fluorination and investigated hydrogen storage properties by volumetric method. Micropore volume values of ACFs obtained from surface modification with Ni impregnation and fluorination were decreased 9 and 35 %, respectively. Hydrogen storage capacities of fluorinated ACFs were slightly changed, on the other hand, that of Ni impregnated ACF was considerably increased. It means that hydrogen was not only adsorbed on ACF surface, but also on Ni metal surface by means of dissociation. Although the microphone volume of ACF modified with fluorination was decreased, its hydrogen storage were found not to be changed compared with fresh ACF. These results indicated that the surface of ACF after fluorination modification may be strongly attracted hydrogen due to high electronegativity of fluorine. Therefore, it was proven that hydrogen storage capacity was related with micropore volume and surface property of carbon materials as well as specific surface area.

Development of Algorithm for Wear Volume Evaluation using Surface Pronto Analysis (표면 Profile 해석을 이용한 마멸량 계산 알고리즘 개발)

  • 김형규;김선재
    • Tribology and Lubricants
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    • v.17 no.1
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    • pp.33-39
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    • 2001
  • A method of calculating wear volume is developed using the signal processing technique. The lowpass filter with Fourier transform and the “windowing” are implemented in the method. User-defining feature is also included in determining the cutoff frequency of the low-pass filter and the baseline for the volume integration. Commercial software, MatLab, is used for the programming. Since the method uses the original wear data without simplifying the wear shape, it can give a further accurate result than the previously utilized methods, which often adopted the simplification. It becomes further powerful if the contacting body has a general shape rather than that gives well-formed surface traction (e.g., the Hertzian). The validation of applying the average surface roughness, Ra, to the “windowing” and the baseline for volume integration is discussed.

Humidity effects on surface resistivities in PE and PP mixtures (PE 및 PP혼합 재료의 표면저항에 미치는 습도효과)

  • 강전홍;유황민;김한준;한상옥;김종석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.424-426
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    • 2002
  • The surface and volume resistivity in the polymers, PE(polyethylene) and PP(polypropylene) mixtures are tested and measured by the ASTM D257(KS M3015) standard. Humidity effects on surface and volume resistivity in two polymers have been studied qualitatively at room temperature. The results of resistivity in these polymers show that the values of surface resistivity (and volume resistivity) at the humidity of 90% are remarkably small compared with those at the humidity of 50%, independing on applied voltage. When we varied the humidity in two polymers, it was found to takes many hours to recover into original surface resistivity (and volume resistivity) of these polymers.

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Physiological Effect on Changes of the Surface Area and the Volume of Limb and Their Effective Measurements (하퇴부(下腿部)의 표면적(表面積) 및 체적변화(體積變化)의 생리적(生理的) 배경(背景)과 측정(測定)에 대(對)한 연구(硏究))

  • Han, Sang-Deok;Lee, Yeong-Suk
    • Journal of the Ergonomics Society of Korea
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    • v.7 no.2
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    • pp.15-21
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    • 1988
  • Changes of the surface area and the volume of limb are important factors for designing clothes and shoes. The limb volume increases slightly in the afternoon in general, because of human activity, as a diurnal variation. Changes are also associated with menstrual cycle, pregnancy, physical exercise and environmental temperature. The most effective method for measuring the surface area of limb is the paper replacement method.

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Characteristics of Carbon Dioxide Adsorption with the Physical Property of Activated Carbon (활성탄의 물리적 특성에 따른 이산화탄소 흡착 특성)

  • Tanveer, Ahmad;Park, Jeongmin;Choi, Sinang;Lee, Sang-Sup
    • Clean Technology
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    • v.24 no.4
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    • pp.287-292
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    • 2018
  • Effect of physical property of activated carbon on its carbon dioxide adsorption was investigated for the effective control of carbon dioxide. Pinewood sawdust and coal were used as raw materials of activated carbon. Specific surface area, micropore volume and mesopore volume of the prepared activated carbons were determined, respectively. The prepared activated carbons were analyzed for their adsorption capacity of carbon dioxide. The adsorption capacity was then presented with respect to the surface area, micropore volume and mesopore volume, respectively. As a result, the specific surface area and micropore volume of both pinewood and coal activated carbon were highly related to its carbon dioxide capacity. Its mesopore volume hardly affected its carbon dioxide capacity. Preparation of activated carbon with high specific surface area and micropore volume was found to be critical to the effective control of carbon dioxide.