• Title/Summary/Keyword: Volume Substitution

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The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement (하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성)

  • Cha, Soo-Won;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.95-102
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    • 2022
  • Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

Preparation and Characterization of Alumina Thin Film by Sol-Gel Method (II); Synthesis of Alumina Sol for Coating and Preparation of Coating Films (졸겔법에 의한 알루미나 박막의 제조 및 특성(II);코팅용 알루미나 졸의 합성 및 박막 제조)

  • 이재호;최세영
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.911-919
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    • 1994
  • As the study for preparation of single-layer anti-reflective coating on glass, the conditions of synthesis of sol for coating and of reproducible coating procedure were investigated. In case of water-based sol, coating was impossible because of poor wettability of sol. The Substitution of solvent with ethanol improved the wettability of sol on the glass surface, and optimum amount of ethanol for substitution was 70 vol%. Maximum specific surface area and total pore volume of water-based sol were 268.7$m^2$/g and 0.315 cc/g, but after substitution, those values increased to 404.1 $m^2$/g and 0.376 cc/g, respectively. The upper limit withdrawl speed of coating in order to get clean coated films without aggregations or stains was 7 cm/min. In case of addition of 0.1 mol HNO3 and substitution with 70 vol% ethanol and heat-treatment at 40$0^{\circ}C$ for 1 hour, thin film with thickness of 94 nm was obtained at withdrawl speed of 4 cm/min. The thickness of thin film was independent of drying time.

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Nanocrystallization Behavior of Al-Y-Ni with Cu Additions (Cu 첨가에 따른 Al-Y-Ni의 나노결정화 거동)

  • 홍순직;천병선;강세선;이임렬
    • Journal of Powder Materials
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    • v.9 no.1
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    • pp.19-24
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    • 2002
  • This paper reports the results of an investigation into the effect of Cu additions upon the nano-crystallization behaviour of an Al-Y-Ni alloy. 1 at.% Cu was added to a base alloy of Al/sub 88/Y₄Ni/sub 8/ either by substitution for Al to form Al/sub 87/Y₄Ni/sub 8/Cu₁, or by substitution for Ni to form Al/sub 88/Y₄Ni/sub 7/Cu₁. Consistent with previous findings in the literature, the substitution of Cu for Al was found to increase the thermal stability of the amorphous phase whereas the substitution of Cu for Ni was found to decrease its thermal stability. Comparing the microstructures of these alloys after heat treatment to produce equivalent volume fractions of Al nanocrystals showed average grain sizes of 14 nm, 12 nm and 9 nm for the alloys Al/sub 88/Y₄Ni/sub 8/, Al/sub 87/Y₄Ni/sub 8/Cu₁respectively. The effect of Cu in refining the size of the nanocrystals was attributed to enhanced nucleation increasing the number density of the nanocrystals, rather than diffusion limited or interface limited growth.

Mg Atom Substitution for Nonstoichiometric Na+ β-Alumina: A First Principles Study (비화학양론적 Na+β-alumina를 위한 Mg 원자의 치환: 제일원리 계산)

  • Kim, Dae-Hyun;Kim, Dae-Hee;Jeong, Yong-Chan;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.55-59
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    • 2010
  • $Na^+$ ion conductivity can be improved by the substitution of an Mg atom for an Al atom to form a nonstoichiometric $Na^+$ $\beta$-alumina. We performed a first principles study to investigate the most stable substitution site of an Mg atom and the resulting structural change of the nonstoichiometric $Na^+$ $\beta$-alumina. Al atoms were classified as four different layers in the spinel block that are separated by conduction planes in the nonstoichiometric $Na^+$ $\beta$-alumina. The substitution of an Mg atom for an Al atom at a tetragonal site was more favorable than that at an octahedral site. The substitution in the spinel block was more favorable than that close to the conduction plane. This result was well explained by the volume changes of the polyhedrons, by the standard deviation of the Mg-O distance, and by the comparison with bulk MgO structure. Our result indicates that the most preferable site for the Mg atom was the tetrahedral site at the spinel block in the nonstoichiometric $Na^+$ $\beta$-alumina.

Comparative Analysis of Import Substitution Relations of Frozen Squid Demand -Focused on The Rotterdam Model and The Almost Ideal Demand System- (냉동 오징어 수요의 수입대체관계 비교 분석 -로테르담모형과 준이상수요체계를 중심으로-)

  • Woo, Kyeong-Won;Shin, Yong-Min
    • The Journal of Fisheries Business Administration
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    • v.53 no.1
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    • pp.55-72
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    • 2022
  • The domestic catch of squid is decreasing every year. Import volume is increasing to replace these domestic products. Import volume is expected to increase in the future, so it is necessary to study import substitution. Therefore, in this study, after selecting frozen squid, which accounts for the majority of imported squid, as the target fish species, China, Chile and Peru, which account for the majority of frozen squid imports, will be selected as the target countries for analysis. Then, the demand function of squid is estimated using the Rotterdam model, the inverse Rotterdam model, AIDS and inverse AIDS, which are the simultaneous equation demand types, and then elasticity is derived. After that, these models are compared in terms of significance, theoretical fit and practical fit.

Quality Characteristics of Domestic Wheat White Bread with Substituted Nelumbo nucifera G. Tea Powder (백련차 분말을 대체한 우리밀 식빵의 품질 특성)

  • Kim, Young-Sook;Kim, Mun-Yong;Chun, Soon-Sil
    • The Korean Journal of Food And Nutrition
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    • v.21 no.4
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    • pp.448-456
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    • 2008
  • In this study, domestic wheat white breads were prepared with the substitution of 1.5, 3.0, 4.5, and 6.0% Nelumbo nucifera G. tea powder(NNTP). The samples and a control were then compared with regard to quality characteristics, including pH, total titratable acidity, fermentation power of dough expansion, specific volume, baking loss, moisture content, color, textural characteristics, external and internal surface appearances, and sensory qualities in order to determine the optimal ratio of NNTP in the formulation. As the NNTP contents increased, the pH of dough and bread, baking loss, and lightness decreased, whereas the total titratable acidity of dough and bread increased. The fermentation power of dough expansion increased with increasing incubation time. The NNTP samples evidenced significantly higher specific volume, greenness, yellowness, resilience, and crumb consistency than were observed in the control group. However, hardness and fracturability evidenced the opposite effect. The water content and uniformity of the crumb pores were highest at a substitution level of 1.5%, and were lowest at a level of 4.5%. Crumb color, flavor, and delicious taste decreased with increasing NNTP contents, whereas lotus leaf flavor, astringency, bitterness, and off-flavor increased. Density of the crumb pore and crumb springiness were not significantly different among the samples. Softness, chewiness, and overall acceptability were maximal with the 1.5% substitution, and were minimal in the 6.0% group. In conclusion, our results demonstrate that $1.5{\sim}3.0%$ NNTP may prove quite useful as a substitute for domestic wheat flour in the production of white bread, and may evidence favorable nutritional and functional properties.

Effects of Mulberry Leaves Powders on the Quality Characteristics of Yellow Layer Cakes (뽕잎분말을 첨가한 옐로우 레이어 케이크의 품질특성)

  • Kim, Yeoung-Ae
    • Korean Journal of Food Science and Technology
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    • v.35 no.5
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    • pp.871-876
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    • 2003
  • Yellow layer cakes were prepared with flour that was partially substituted with mulberry leaf powder (at the levels of 4, 8, 12, 16 and 20%). Batter viscosity increased with increasing substitution levels while specific gravity decreased. The specific volume of the cake increased as batter viscosity increased, except at 20% substitution. Substituting mulberry leaf powder for flour also resulted in decreased lightness and yellowness and increased redness of the cake crumbs. The volume index and uniformity index were not influenced by the addition of mulberry leaf powder, while the symmetry indexes of cakes with 16% and 20% powder were lower than the control. The hardness of cakes substituted with mulberry leaf powder was lower than that of the control during 10 days of storage. Sensory characteristics, including cell size and cell uniformity, were adversely affected with substitution levels of 16% and 20%. The addition of mulberry leaf powder did not influence softness, but affected moistness significantly.

Quality Characteristics of White Bread with Barley Leaves Tea Powder (보리잎차 분말을 대체한 식빵의 품질 특성)

  • Yeom, Kyung-Hun;Kim, Mun-Yong;Chun, Soon-Sil
    • Korean journal of food and cookery science
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    • v.26 no.4
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    • pp.398-405
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    • 2010
  • In this study, white bread was prepared containing 1.5, 3.0, 4.5 or 6.0% barley leaves tea powder (BLTP). The samples along with a control were then compared regarding their quality characteristics, including pH, total titratable acidity, fermentation power of dough expansion, specific volume, baking loss, moisture content, color, textural characteristics, internal surface appearances and sensory qualities, all to determine the optimal ratio of BLTP. As the BLTP content increased, the pH of the dough and bread and the lightness decreased, whereas the total titratable acidity increased. The fermentation power of dough expansion increased with a longer incubation time. The control group was evidenced by a significantly higher specific volume and baking loss than that observed in the BLTP samples. However, greenness and yellowness evidenced the opposite effect. Hardness was highest at a substitution level of 1.5% and lowest at a level of 4.5%. Fracturability and resilience were not significantly different among the samples. For the internal surface appearance, darkness and greenness increased both increased at higher BLTP content. In the sensory evaluation, color, flavor and overall acceptability were highest in the control bread samples but minimal at a substitution level of 6.0%. Softness was the highest at the 3.0% substitution level and lowest in the control bread samples. Barley leaf flavor, astringency, bitterness and off-flavor increased as the BLTP content increased. Delicious taste was not significantly different among the samples. In conclusion, the results demonstrated that 4.5% BLTP may prove quite useful as a substitute for wheat flour in the production of white bread and may provide favorable nutritional and functional properties.

The Enhanced Magnetic Transition Temperature in Double Perovskites A2FeMoO6 (A=Ca, Sr and Ba) : Electron Doping Effects

  • Kim J.;Yang H. M.;Lee B. W.
    • Journal of Magnetics
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    • v.10 no.1
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    • pp.10-13
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    • 2005
  • We have studied effects of the partial substitution of $La^{3+}$ for $A^{2+}$ on the magnetic properties of double perovskites $A_2FeMoO_6$ (A=Ca, Sr and Ba). Polycrystalline $A_{2-x}La_xFeMoO_6(0{\leq}x{\leq}0.2)$ samples have been prepared by the conventional solid-state reaction in a stream of 5% $H_2$/Ar gas. The x-ray data indicate that A=Ca is monoclinic with the space group P$2_1$/n, A=Sr is tetragonal with the space group I4/mmm, and A=Ba is cubic with the space group Fm3m. The substitution of $La^{3+}$ for $A^{2+}$ results in a cell volume increase for A=Ca and a cell volume reduction for A=Ba. The decrease of saturation magnetization with increasing x arises from the reduction of magnetic moment associated with the electron doping and the disorder at the Fe and Mo sites. The partial substitution of magnetic $La^{3+}$ for $A^{2+}$ considerably enhances the Curie temperature $T_c$ from 316 K for x = 0 to 334 K for x = 0.2. This enhancement of $T_c$ with $La^{3+}$ doping originates from electron doping effects in addition to ionic size ones.

The Quality Characteristics of Sponge Cake with Varied Levels of Whey Protein Isolate (Whey Protein Isolate(WPI)의 대체비율을 달리한 스폰지 케이크의 품질 특성에 관한 연구)

  • Ahn, Myung-Soo;Kim, Chan-Hee
    • Korean journal of food and cookery science
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    • v.23 no.1 s.97
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    • pp.41-49
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    • 2007
  • The substitution effects of whey protein isolate(WPI) for egg in the preparation of sponge cake were determined by objective and subjective tests. Milk whey is drained from milk curd as a by-product of cheese manufacture. Whey protein is known as a good nutritional source and a functional material for many processed foods, especially baked goods. WPI contains above 90% whey protein. The specific gravity and viscosity of sponge cakes tend to be affected by WPI substitution. The cooking loss of sponge cakes with WPI substituted for egg(abbreviated as WPI cake) during oven baking was smaller than that made with egg(abbreviated as egg cake) and the specific loaf volume of WPI cake was larger than that of egg cake. The number of pores was highly increased and the size of pores was more uniformly and finely distributed in the cross section of WPI cake than those of egg cake, as observed by scanning electron microscopy(SEM). The hardness, gumminess and chewiness of WPI cake made with 10-20% WPI substitution were the lowest among all the tested cakes, including egg cake, thereby confirming the considerable improvement in their cake qualities. By the results of sensory evaluation, appearance, pore uniformity, softness, chewiness, moistness, flavor, mouth feeling, and overall acceptability of 10-20% WPI substitute cakes were evaluated as being significantly superior to those of all other cakes(p<0.05). These results support the better physicochemical characteristics and sensory evaluations of sponge cake prepared with 10-20% of WPI substitution for egg.