• 제목/요약/키워드: Volume Electrical conductivity

검색결과 169건 처리시간 0.035초

New Functional Conductive Polymer Composites Containing Nickel Coated Carbon Black Reinforced Phenolic Resin

  • Farid El-Tantawy;Nadia Abdel Aal;Yong Kiel Sung
    • Macromolecular Research
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    • 제13권3호
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    • pp.194-205
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    • 2005
  • The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

간척지 토양의 제염과정중 수리전도도의 변화 (Changes of Hydraulic Conductivity During Desalmization of Reclaimed Tidelands)

  • 구자웅;은종호
    • 한국농공학회지
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    • 제30권4호
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    • pp.85-93
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    • 1988
  • This laboratory study was carried out in order to produce fundamental data for analyzing salt movement and desalinization effects, using samples of silt loam soil collected in Gyehwado and Daeho reclaimed tidelans, and samples of silty clay loam soil collected in Kimie tideland. Desalinization experiments with gypsum treatment were performed to analyze changes of the hydraulicc conductivity with changes of the soil property and the salt concentration during the desalinization of reclaimed tideland soils by leaching through the subsufface drainage, and correlations between factors infl uencing the reclamation of salt affected soils were analyzed by the statistical method. The results were summarized as follows: 1. The reclaimed tideland soils used in this study were saline-sodic soils with the high exchangeable sodium percentage and the high electrical conductivity. 2. Changes of the hydraulic conductivity with the amount of leaching water and the leaching time elapsed were affected by the amount of gypsum except exchangeable sodium and clay contents. The regression equation between the depth of water leached per unit depth of soil (Dw / Ds : X) or the square root of the leaching time elapsed (T $^1$ $^2$ : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a . bx. 3. The more exchangeable sodium and clay contents regardless of the amount of gypsum, the more the leaching time was required until a given volume of water was leached through the soil profile. The regression analysis showed that the relationship between the depth of water leached per unit depth of soil(Dw /Ds:X) and the square root of the leaching time elapsed(T$^1$$^2$ :Y) could be described by Y=a . Xb. 4. The hydraulic conductivity was influenced to a major degree by the salt concentration provided that the electrical conductivity was below 10 mmhos / cm during the desalinization of reclaimed tideland soils. The regression equation between the relative electrical conductivity ( ECr : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a + b . X-$^1$. 5. In conclusion, the hydraulic conductivity, leaching requirements and the leaching time elapsed can be estimated when the salt concentration decreases to a certain level during the desalinization of reclaimed tidelands, and the results may be applied to the analysis of salt movement and desalinization effects.

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전기이중층에 의한 나노유체의 열전달율 향상 (Enhancement Thermal Conductivity of Nanofluids with Electric Double Layer (EDL))

  • 정정열;유정열
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2160-2164
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    • 2007
  • In this study, the mechanism of enhanced thermal conductivity is elucidated on the bases of both electric double layer (EDL) and kinetic theory. A novel expression for the thermal conductivity of nanofluids is proposed and verified by applying to $Al_2O_3$ nanofluids with regard to various temperatures, volume fractions and particle sizes. In dilute nanofluids, the effects of Brownian motion and particle interaction on enhancing the thermal conductivity of nanofluids are quite comparable while the effect of particle interaction due to EDL is more prominent in dense nanofluids. The model presented in this paper shows that particle interaction due to the electrical double layer is the most responsible for the enhancement of thermal conductivity of nanofluids.

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Effects of Tungsten Particle Size and Nickel Addition in DC arc Resistance of Cu-W Electrode

  • Kim, Bong-Seo;Jeong, Hyun-Uk;Lee, Hee-Woong
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권2호
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    • pp.68-72
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    • 2004
  • The performance of copper-tungsten for electrodes used in an ultra high voltage interruption system was evaluated by means of an interruption test, which requires a large-scale apparatus and high cost. In this study, prior to the interruption test, the characteristics of a Cu-W electrode were estimated through the DC arc test, which is a simple, low cost procedure. The DC arc characteristics of a 20wt%Cu-80wt%W electrode were investigated with the change of tungsten powder size distribution and the addition of nickel. In specimens containing a high volume fraction of large sized tungsten particles, the relative density and hardness of sintered Cu-W electrodes increased while the electrical conductivity and the DC arc resistance decreased. Furthermore, the relative density became enhanced with the increase of the amount of nickel while the hardness and electrical conductivity diminished and the DC arc resistance worsened.

비파괴적 방법에 의한 입자 강화 복합재료의 부피분율 평가: 와전류법 (Nondestructive Determination of Reinforcement Volume Fractions in Particulate Composites : Eddy Current Method)

  • 정현조
    • 비파괴검사학회지
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    • 제18권2호
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    • pp.112-120
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    • 1998
  • 입자 보강 복합재료의 부피분율을 평가하기 위한 와전류 비파괴 방법을 제시하였다. 제안된 방법은 복합재의 미시구조를 설명할 수 있는 이론 모델과 와전류에 의한 전기전도도 측정을 필요로 한다. 측정한 전도도를 이론 예측값과 같게 두면 미지의 입자 부피분율이 계산된다. Mori-Tanaka 방법에 기초한 전도도 해석 모델이 소개되어 있다. 이러한 접근 방법을 SiC 입자 보강 Al 기지 ($SiC_p/Al$) 복합재에 적용하였다. 이방법으로 보강재의 부피분율을 비교적 정확하게 결정할 수 있었다. 금속간 화합물이 부피분율 평가에 미치는 영향을 논하였으며, 또한 금속간 화합물의 전도도와 기하학적 성질이 보강 입자와 같은 경우, 이 두 상의 총 부피분율을 결정할 수 있는 방법을 제시하였다.

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Change of Percolation Threshold in Carbon Powder-Filled Polystyrene Matrix Composites

  • Shin, Soon-Gi
    • 한국재료학회지
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    • 제25권3호
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    • pp.119-124
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    • 2015
  • This paper investigates the change of the percolation threshold in the carbon powder-filled polystyrene matrix composites based on the experimental results of changes in the resistivity and relative permittivity of the carbon powder filling, the electric field dependence of the current, and the critical exponent of conductivity. In this research, the percolation behavior, the critical exponent of resistivity, and electrical conduction mechanism of the carbon powder-filled polystyrene matrix composites are discussed based on a study of the overall change in the resistivity. It was found that the formation of infinite clusters is interrupted by a tunneling gap in the volume fraction of the carbon powder filling, where the change in the resistivity is extremely large. In addition, it was found that the critical exponent of conductivity for the universal law of conductivity is satisfied if the percolation threshold is estimated at the volume fraction of carbon powder where non-ohmic current behavior becomes ohmic. It was considered that the mechanism for changing the gaps between the carbon powder aggregates into ohmic contacts is identical to that of the connecting conducting phases above the percolation threshold in a random resister network system. The electric field dependence is discussed with a tunneling mechanism. It is concluded that the percolation threshold should be defined at this volume fraction (the second transition of resistivity for the carbon powder-filled polystyrene matrix composites) of carbon powder.

Study on the Electrical Conductivity and Catalytic Property by Structural Change of 70V2O5-10Fe2O3-13P2O5-7B2O3 Glass with Crystallization

  • Jeong, Hwa-Jin;Cha, Jae-Min;Ryu, Bong-Ki
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.406-412
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    • 2017
  • $70V_2O_5-10Fe_2O_3-13P_2O_5-7B_2O_3$ glasses were prepared to study the electrical conductivity and catalytic properties of the structural change with crystallization. The structural changes were analyzed by determining the molecular volume from the sample density; using X-Ray Diffraction (XRD) analysis, which indicated that $V_2O_5$, $VO_2$ and $B_2O_3$ crystals in heat-treated more than 1h samples. Especially a new crystalline phase of non-stoichiometric $Fe_{0.12}V_2O_5$ was formed after 6 h heat treatment. The V-O bonding change after crystallization was analyzed by Fourier Transform Infrared Spectroscopy (FTIR); V ion change from $V^{5+}$ to $V^{4+}$ was shown by XPS. Conductivity and catalytic properties were examined based on the polaronic hopping of V and Fe ions, which exhibited different valence states with crystallization.

고체 절연체의 도전율 변화에 따른 GIS 내부 전계분포 해석 (Analysis of Electric Fields Distribution Inside G IS By Changing Conductivity of Spacer)

  • 민석원;김용준;김응식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.528-530
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    • 2000
  • In this paper, electric field distribution of GIS by changing conductivity of spacer is analysed by the use of 3 dimensional Surface Charge Method. We find electric field distribution inside GIS was much influenced when volume resistance are lower than $10^7[\Omega-cm]$.

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Characteristics of fluoride/glass as a seed layer for microcrystalline silicon film growth

  • Choi, Seok-Won;Kim, Do-Young;Ahn, Byeong-Jae;Yi, Jun-Sin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.65-66
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    • 2000
  • Various fluoride films on a glass substrate were prepared and characterized to provide a seed layer for crystalline Si film growth. The XRD analysis on $CaF_2/glass$ illustrated (220) preferential orientation and showed lattice mismatch less than 5 % with Si. We achieved a fluoride film with breakdown electric field of 1.27 MV/cm, leakage current density about $10^{-6}$ $A/cm^2$, and relative dielectric constant less than 5.6. This paper demonstrates microcrystalline silicon $({\mu}c-Si)$ film growth by using a $CaF_2/glass$ substrate. The ${\mu}c-Si$ films exhibited crystallization in (111) and (220) planes, grain size of $700\;{\AA}$, crystalline volume fraction over 65 %, dark- and photo-conductivity ratio of 124, activation energy of 0.49 eV, and dark conductivity less than $4{\times}10^{-7}$ S/cm.

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Y2O3-카본 복합체의 전기전도성에 미치는 소결온도의 영향 (Effects of Sintering Temperature on the Electrical Conductivities of the Y2O3-Carbon Composites)

  • 최관영;오윤석;김성원;김형순;박종훈;이성민
    • 한국세라믹학회지
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    • 제49권2호
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    • pp.173-178
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    • 2012
  • The $Y_2O_3$ ceramics have been widely used as plasma resistant materials in the semiconductor industry. In this study, composites made of plasma resistant $Y_2O_3$ and electrically conductive carbon have been produced. The electrical properties of this composite were measured with respect to the size, volume fraction of the conductive carbon phase, and sintering temperature. When micro-sized carbon was used, the composites were insulating up to 5 wt% addition of the carbon. However, when nano-sized carbon of around 60 ~100 nm was used, the composites became conductive over threshold volume fraction of carbon, which increased with increasing sintering temperature. This behavior of electrical conductivity of the composites was discussed in terms of the percolation theory. The percolation threshold of the conductivity seemed to be affected by the grain growth and coalescences of dispersed conductive carbon phases with grain growth of matrix $Y_2O_3$.