• 제목/요약/키워드: Volatile Organic Compounds (VOC)

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대기중 휘발성 유기화합물의 채취 및 분석 방법 비교 (Comparison of Sampling and Analysis Methods for Volatile Organic Compounds in Ambient Air)

  • 나광삼;김용표
    • 한국대기환경학회지
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    • 제14권5호
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    • pp.507-518
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    • 1998
  • A field comparison study was carried out to quantify differences among various sampling and analytical methods for volatile organic compounds (VOCs) at a site in Vlsan in June 1997. Air sampling containers (SUMMA canisters) were used by the Korea Institute of Science and Technology (KIST) and adsorption tubes (carbotrap) were used by Yeungnam University (YN Univ.) for sampling ambient air. Duplicate samples obtained by KIST were analyzed by KIST with a GC-MS system for aromatics and halogenated hydrocarbons and by Atm AA with a GC -FID system for C2∼C9 hydrocarbons, respectively. The adsorption tube samples were analyzed by YN Univ. with a GC-FID system for aromatics. VOC levels for the duplicate canister sampls analyzed by KIST and Atm AA were in good agreement. Concentrations of aromatics by the adsroption tube method were generally higher than those by the canister sampling method by factor of 1.5 to 2.0. Differences between the two sampling methods were discussed.

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현장중심의 동시측정을 통한 환경대기 중 휘발성유기화합물의 측정방식 비교 연구 (Interlaboratory Study of Sampling and Analysis Techniques for Ambient VOCs under Field Conditions)

  • 김기현;김조천;이강웅;허귀석;이병규
    • 한국대기환경학회지
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    • 제16권6호
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    • pp.685-691
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    • 2000
  • In order to provide basis for an accurate concentration determination of volatile organic compounds(VOCs) in air, four different institutions participated in simultaneous measurements of several VOC species under the experimental scheme of the Measurement and Analysis Division(MAD) of the Korea Society for Atmospheric Environment(KOSAE). Two types of experiments were undertaken by collecting and analyzing ambient air samples from the 7th floor of Natural Science Building, Han Tang University during two day periods of the late May 1998. The first typer of experiment was conducted as five consecutive experiments at 2-hour intervals by two institutions. On the other hand. the second type of experiment was performed as two -10hr sampling by three different institutions. The data obtained from different type of experiments were examined using various statistical approaches. In general, the results of these experiments indicated that the VOC data produced by a number of Korean institutions be fairly agreeable.

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수용 모델에서 화학 반응을 고려한 휘발성 유기화합물의 배출원별 기여도 추정 (Estimation of the contributions from major sources of volatile organic compounds using receptor model with chemical loss)

  • 나광삼;김용표;문일
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.77-80
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    • 1999
  • 톨루엔, m-자일렌, o-자일렌, 1,2,4-삼메틸벤젠, 에틸렌 그리고 프로필렌 등과 같은 휘발성 유기화합물 (Volatile Organic Compounds, VOC)들은 오존 생성과 직접 관련이 있으며, 벤젠은 발암 물질로 알려져 있다. 이처럼 VOC는 인체 및 환경과 밀접한 관계가 있기 때문에 이들 성분들에 대한 효율적인 관리와 저감 대책을 수립하는 일은 매우 중요하다. 이들 배출원이 수용지점(receptor site)에 얼마만큼 영향을 주는 가를 정량적으로 파악하여 인체에 미치는 영향을 최소화하는 관리 방안을 마련해야 한다.(중략)

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인쇄업에서 배출되는 반응성 VOCs 종류와 흡착 제거 방법의 적용 (Volatile organic compounds emitted from printing processes and their removal by adsorption)

  • 안해영;이윤경;송지현
    • 실내환경 및 냄새 학회지
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    • 제17권4호
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    • pp.396-403
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    • 2018
  • In this study, volatile organic compounds (VOCs) emitted from printing industries were analyzed, and an inorganic adsorbent, ${\gamma}-alumina$, was selected for the effective control of the VOC emissions. Printing processes commonly require inks, thinners, and cleaners, and they were mixed organic solvents containing aromatic compounds, ketones, and alcohols. Therefore, toluene, methyl ethyl ketone (MEK), and isopropyl alcohol (IPA) were selected as model compounds for this study. The adsorptive properties using ${\gamma}-alumina$ were determined for the model compounds. Both batch isotherm and continuous flow column tests demonstrated that the adsorption capacity of MEK and IPA was 3~4 times higher than that of toluene. The column test performed at an inlet toluene concentration of 100 ppm showed that an 80% breakthrough for toluene was observed after 3 hours, but both MEK and IPA were continuously adsorbed during the same time period. A numerical model simulated that the ${\gamma}-alumina$ could remove toluene at a loading rate of 0.4 mg/min only for a 4-hour period, which might be too short of a duration for real applications. Consequently, lifetime enhancement for ${\gamma}-alumina$ must be implemented, and ozone oxidation and regeneration would be feasible options.

Quantitative Approaches for the Determination of Volatile Organic Compounds (VOC) and Its Performance Assessment in Terms of Solvent Types and the Related Matrix Effects

  • Ullah, Md. Ahsan;Kim, Ki-Hyun;Szulejko, Jan E.;Choi, Dal Woong
    • Asian Journal of Atmospheric Environment
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    • 제11권1호
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    • pp.1-14
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    • 2017
  • For the quantitative analysis of volatile organic compounds (VOC), the use of a proper solvent is crucial to reduce the chance of biased results or effect of interference either in direct analysis by a gas chromatograph (GC) or with thermal desorption analysis due to matrix effects, e.g., the existence of a broad solvent peak tailing that overlaps early eluters. In this work, the relative performance of different solvents has been evaluated using standards containing 19 VOCs in three different solvents (methanol, pentane, and hexane). Comparison of the response factor of the detected VOCs confirms their means for methanol and hexane higher than that of pentane by 84% and 27%, respectively. In light of the solvent vapor pressure at the initial GC column temperature ($35^{\circ}C$), the enhanced sensitivity in methanol suggests the potential role of solvent vapor expansion in the hot injector (split ON) which leads to solvent trapping on the column. In contrast, if the recurrent relationships between homologues were evaluated using an effective carbon number (ECN) additivity approach, the comparability assessed in terms of percent difference improved on the order of methanol (26.5%), hexane (6.73%), and pentane (5.24%). As such, the relative performance of GC can be affected considerably in the direct injection-based analysis of VOC due to the selection of solvent.

실내 공기 데이터 측정기 및 모니터링 시스템 (Indoor Air Data Meter and Monitoring System)

  • 전성우;임현근;박순모;정회경
    • 한국정보통신학회논문지
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    • 제26권1호
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    • pp.140-145
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    • 2022
  • 고도화된 현대사회는 도시산업화와 대중교통으로 인한 대기오염 물질 중 미세먼지는 실외에서 실내로 유입되는 현상이 있다. 실내에서 사용하는 미세먼지 측정기는 제한적인 정보 제공과 오염 수치가 다르게 측정되어 사용자에게 원하는 데이터와 모니터링을 할 수 없는 문제점이 발생하고 있다. 이러한 문제점을 해결하기 위해 본 논문에서는 실내 공기 질 데이터 미세먼지와 초미세먼지인 Dust(PM1.0, PM2.5, PM10), VOC(Volatile Organic Compounds)와 PIR(Passive Infrared Sensor)로 미세먼지 측정기와 모니터링시스템을 설계 및 구현하였다. 측정기는 지정한 구역에 설치하여 미세먼지를 실시간 측정하고 Google Cloud Platform의 App Engine을 통하여 데이터 수집 및 저장하고 시각화하여 사용자에게 제공하는 미세먼지 측정기와 모니터링시스템을 제안한다.

대기중 휘발성유기화합물의 시간적 농도 변화에 대한 연구 (The Temporal Distribution Characteristics of Some Important VOC Species from a Nonurban Site in Naju)

  • 김조천;김기현
    • 한국환경과학회지
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    • 제9권6호
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    • pp.483-488
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    • 2000
  • In this study, the distribution characteristics of volatile organic compounds (VOCs) were investigated on the seasonal basis across spring, summer, and fall during the year of 1998. According to this analysis, most VOC species investigated exhibited strong temporal trends. Over diurnal scale, there distribution characteristics were affected by seasonal factors strongly. While they showed high day/night ratio pattern during spring, the pattern was reversed during fall. When the seasonal mean values were compared between the two seasons, the spring values were systematically higher than their counterparts in most cases. In addition when our VOC measurement date were compared with those reported from elsewhere, we were able to conclude that the VOC levels in the study area are comparable to the level weakly impacted by the regional emissions of VOCs. Although our data are not sufficient enough to systematically explain the atmospheric distribution and behavior of VOCs, the findings of strong correlations among some of VOC species suggests strong need for investigating their interactions in the earth\`s atmosphere.

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