• Title/Summary/Keyword: Volatile Organic Compound

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A Study on the High Performance Waterborne Epoxy Resin for Surface Coating (표면 코팅을 위한 고성능 수용성 에폭시 수지에 관한 연구)

  • Kim, Yong-Ho;Lee, Kwang-Won;Kim, Young-Jae
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.89-97
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    • 2000
  • Waterborne epoxy resins have been developed in order to meet environmental regulations for reduction of the emission of organic solvents from coating industry As each generation has filled a performance gap in the previous technology, new waterborne epoxy resin has developed. Initially, waterborne epoxy resins were used primarily on masonry, but the subsequent generations have found utility for the protection of metallic substrates as well. Indeed, the third generation systems have been formulated to produce the high performance industrial maintenance primers which possess the desirable combination of good corrosion resistance and low volatile organic compound levels. This paper outlines the important guidelines for formulating waterborne epoxy primers from waterborne epoxy resin that has recently developed in our company. The importance of using the appropriate resin-curing agent system at the optimized epoxy to amine ratio is stressed.

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Analysis of Volatile Compounds in Bamboo and Wood Crude Vinegars by the Solid-Phase Microextracion(SPME) Method (SPME법에 의한 죽초 및 목초액 중의 휘발성 성분 분석)

  • Mun, Sung-Phil;Ku, Chang-Sub
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.4
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    • pp.80-86
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    • 2002
  • Volatile compounds in three different kinds of crude vinegars obtained from oak (Quercus serrata), bamboo (phyllostachys) and pine (Pinus densiflora) species were analyzed by the solid-phase microextraction (SPME) method. A total of 264 peaks were detected on the chromatograms obtained from the polar (CBP 20) and the nonpolar (CBP 1) columns, which were used for analyzing the volatile compounds in these vinegars. The major volatile compounds identified by using the polar column were 2-butanone, acetic acid, guaiacol, phenol, cresols, 4-ethyl guaiacol, 4-ethyl phenol, and syringol. Using the nonpolar column, seven compounds could be identified: 1,2-dimethoxybenzyl alcohol, 1-hydroxy-2-butanone, 1-(2-furanyl)-1-propane, ethisolide, furfuryl acetate, 1,2-dimethoxybenzene, phenyl acetate. The volatile compounds were classified into five groups: phenols, neutral compounds, organic acids, esters and others. The phenols were the main component and comprised 49~65% of the volatile compounds of these vinegars. In the case of bamboo vinegar, the proportion of the phenols in the volatile compounds was lower than that of the two wood vinegars. However, the proportions of the neutral compounds and the organic acids were higher than those of the wood vinegars. Therefore, it seems that these differences of the proportions of the volatile compounds would make a certain difference of a smoke flavor between the bamboo vinegar and the wood vinegars.

Study of Catalytic Filter on the Removal of Dust and HVOC (촉매필터를 이용한 먼지 및 HVOC 제거 특성 연구)

  • Jeong, Soon Kwan;Park, Young Ok
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.80-85
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    • 2008
  • Catalytic filter is capable of performing shallow bed dust filtration plus a catalytic reaction, promoted by a catalyst deposited in its inner structure. Such a feature may allow potential cost and space reduction in several environmental applications. Dust filtration and halogenated volatile organic compound (1,2-dichlorobenzene) destruction were carried out in a lab-scale reactor. $WO_3-V_2O_5/TiO_2$ supplied by MaGreen, which showed high catalytic acitivity at low temperature, was used as a catalyst. P-84 that can be operated under $250^{\circ}C$ was used as a felt. The catalytic activity and filtration efficiency of catalytic filters were investigated under the operating conditions, including temperature, face velocity, and dust concentration. The catalytic activity of catalytic filter increased with increasing temperature and the amount of catalyst loaded. The test results showed that the filtration efficiency was primarily affected by the face velocity. Pressure drop variations as a function of time were investigated for a variety of conditions. In case of virgin filter, a dramatic decrease in the pulse interval and a slightly increase in the base line pressure drop were observed. A relatively slow pressure drop build-up was recorded for the catalytic filter due to smooth and slippery surface characteristics of nanofiber. The catalytic filter indicated that high filtration efficiency over 99.98% and high catalytic activity over 90% at 1 m/min and $210^{\circ}C$.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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Effect of $\gamma$-Irradiation of Volatile Organic Compounds of Houttuynia cordata Thunb. (방사선 조사에 의한 어성초의 휘발성 유기성분 변화)

  • Ryu, Keun-Young;Shim, Sung-Lye;Jung, Min-Seok;Jun, Sam-Nyeo;Jo, Cheor-Un;Song, Hyun-Pa;Kim, Kyong-Su;Kim, Youn-Soon
    • Food Science and Preservation
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    • v.15 no.3
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    • pp.411-420
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    • 2008
  • This study was performed to examine the effect of $\gamma$-irradiation on the volatile organic compounds in Houttuynia cordata Thunb.(H. cordata). 1be volatile compounds of non-irradiated and 10 kGy $\gamma$-irradiated H. cordata were isolated using SDE apparatus and analyzed by GC/MS. For each treatment the number of volatile compounds were detected at 83 and 85, respectively, 1be predominant functional groups of volatile organic compounds from H. cordata were identified as alcohols and ketones. H. cordata was mainly composed of hexahydrofarnesyl acetone (12.81 %), phytol, decanoic acid, dodecanoic acid, octadecanol, caryophyllene oxide, 2-undecanone and menthol. Houttuynum which is characteristic compound of H. cordata was found in all samples and there was no significant difference with irradiation doses. Consequently, $\gamma$-irradiation of H. cordata would be an effective process for sanitation and to increase extraction efficiency.

Organic Acids, Free Sugars, and Volatile Flavor Compounds by Type of Jerusalem Artichoke (돼지감자의 품종별 유기산, 유리당 및 휘발성 향기성분)

  • Jung, Bok-Mi;Shin, Tai-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.7
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    • pp.822-832
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    • 2017
  • This study analyzed contents of organic acids, free sugars, and volatile flavor compounds by type of Jerusalem artichoke (Helianthus tuberosus L.). Organic acids in dried Jerusalem artichoke were mainly composed of malic acid, citric acid, and succinic acid. Sucrose, fructose, and glucose were the major sugar components of dried Jerusalem artichoke. Free sugars were more abundant in the white colored sample than in the purple colored sample. In contrast, purple colored sample contained more organic acids than the white colored one. Volatile compounds in Jerusalem artichoke were investigated using the solid-phase micro-extraction method of gas chromatography/mass spectrometry. A total of 117 volatile compounds were identified in Jerusalem artichoke, and chemical classification was as follows: 5 acids, 13 alcohols, 19 aldehydes, 12 hydrocarbons, 15 ketones, 8 miscellaneous, 27 pyrazines, and 18 terpenes in all samples. Terpene was the most abundant in Jerusalem artichoke, and ${\beta}$-bisabolene was the main component in terpenes. The second most common compound was aldehyde, and hexanal was the highest. Pyrazines were the most abundant in the roasted samples, and 2,5-dimethyl-3-ethylpyrazine was present at the highest level, followed by 2,5-dimethylpyrazine. Compared with purple samples, main compounds contained in white samples were aldehydes and hydrocarbons, whereas the major compounds in purple samples were terpenes and alcohols.

A Comparison of Quality and Volatile Components of Two Cucumber Cultivars Grown under Organic and Conventional Conditions (유기 및 관행재배 오이(청낙합, 입추낙합)의 품질특성 및 휘발성 향기성분 특성)

  • Lee, You-Seok;Seo, Hye-Young;Kim, Gwi-Duck;Moon, Jae-Hak;Lee, Young-Han;Choi, Kyeong-Ju;Lee, Youn;Park, Jang-Hyun;Kang, Jeong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.42 no.4
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    • pp.407-413
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    • 2010
  • This study was performed to compare the quality and volatile components of two cucumber (Cucumis sativus L.) cultivars (Cheongnakhab, Ipchunakhab)-grown under organic and conventional conditions. The levels of pH and soluble solids in the organic system were similar to those in the conventional system. The hardness of the pulp in the organic cucumbers was slightly higher than that in conventional cucumber regardless of cultivar. However, the contents of chlorophyll a, b, and total chlorophyll in organic cucumbers were significantly (p<0.05) higher than those in conventional cucumber. The major volatile compound of fresh cucumber was (E,Z)-2,6-nonadienal regardless of cultivar and farming system. When classified by the identified components' functional group, the rate of aldehydes was the highest of all samples. The results indicate that the quality and volatile components in organic cucumbers were similar to those in conventional cucumbers except for hardness and chlorophyll contents regardless of cultivar.

System Design Using Honeycomb Ceramic Rotor for Toluene Removal by Adsorption Method (톨루엔 흡착제거를 위한 회전식 흡착제거장치 설계)

  • 김홍수;유윤종;주국택;설용건;한문희
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2000.11a
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    • pp.205-210
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    • 2000
  • VOC는 volatile organic compound의 약자로서 toluene, benzene, MEK, MIBK등 자동차 운행, 도장산업, 인쇄업, 대형 세탁시설, 유류저장 및 출하시설에서 주로 배출되는 유기성 배기배출물을 총칭하는 개념이다. VOC는 작업현장에서 악취를 발생시켜 작업현장에서의 쾌적성을 해치기도 하지만, 태양에너지를 받아 오존을 형성하기 때문에 인체에 크게 해로운 역할을 한다. 정부에서는 대기환경보전법을 제정하여 휘발성유기화합물질 배출억제 정책을 실시하고 있으며, 배출업소에 대하여 휘발성유기화합물질 방지시설 설치를 의무화하고 있다.(중략)

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Distruction of Benzene by Using UV/$TiO_2$ Photocatalyst (자외선과 이산화티타늄계 광촉매를 이용한 벤젠의 분해)

  • 전의찬;송민종;사재환;노기완;박찬웅
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.366-368
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    • 2000
  • 휘발성유기화합물질(Volatile Organic Compound ; VOCs)은 오존등 광화학옥시단트로 인한 대도시의 대기질 악화와 함께 도시환경에서 중요한 발암성 물질이거나 만성 또는 급성의 건강장해를 일으킴으로써 공중보건상에 나쁜 영향을 주는 것으로 조사되고 있다. 특히 실내 공기중의 VOCs는 건축자재, 가구, 접착제, 카페트, 흡연 및 취사행위 및 난방을 포함한 연료의 연소 등 다양한 오염원으로부터 방출되는 건으로 알려져 있다. (중략)

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Examination of factors affecting seasonal variations of VOC concentrations (대기중 VOC의 계절적 농도에 영향을 주는 요인 관찰)

  • 나광삼;김용표
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.60-61
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    • 2000
  • 온도의 변화에 따라 계절이 뚜렷하게 구분되는 지역에서 VOC (volatile organic compound, 휘발성 유기화합물)의 계절적 농도는 겨울에 농도가 높고 여름에 낮은 거동을 나타낸다. 이러한 농도 경향에서는 단지 겉으로 나타나는 농도의 절대치로는 계절적 농도 거동에 영향을 주는 요인들을 파악하기 어렵다. 이 연구에서는 측정된 농도가 지니고 있는 계절적 특성을 유추하기 위한 간접적 방법으로 주요 성분들의 농도비를 이용하였다. (중략)

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