• Title/Summary/Keyword: Volatile Organic Compound

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A Numerical Analysis of the Abatement of VOC with Different Photocatalytic Honeycomb Filters (광촉매 필터형상에 따른 휘발성 유기화합물의 제거에 관한 수치해석적 연구)

  • 류무성;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.1-7
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    • 2004
  • This study has been numerically conducted to investigate the removal efficiency of Volatile Organic Compound (VOC) for different photocatalytic honeycomb filters. Recently, the photocatalysis is being applied to air-cleaner, air-conditioner and vacuum-cleaner with the capability of air-purification, sterilization and antibiosis. However, photocatalysis is less efficient than other methods for removing VOC except in the case of low concentration. So far most of studies have focused on an improvement of the photocatalytic materials, but this study have placed emphasis on the improvements of shape of photocatalytic honeycomb filter. UV irradiation, concentration profile and pressure drop have been investigated for different cross sections of filters and for different filter lengths. Light intensity is dropped sharply with increasing distance from the UV-lamp, and becomes very low in the middle of the filters. Since photocatalytic reaction rate is a function of light intensity, VOC concentration gradient might be small in the middle of long filters. Thus, most of reaction have risen within only three times of dimensionless axial distance. These results can be used effectively for the design of advanced photocatalytic honeycomb filters.

The synthesis and the structural analysis of advanced PVC plasticizer, 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate

  • Cho Myo-Kyung;Ko Dong-Hyun;Lim Young-Hee;Jung Min-Hwan;Cho Hye-Sung;Ok Jong-Hoa
    • Journal of the Korean Magnetic Resonance Society
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    • v.9 no.2
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    • pp.103-109
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    • 2005
  • New PVC plasticizer, 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate was synthesized via simple esterification with butyric acid and Texanol(a trademark of Eastman Chemicals), the mixture of 2,2,4-trimethyl-1,3-pentanediol-3-isobutyrate and 2,2,4-trimethyl-1,3-pentanediol-1-isobutyrate. The analysis of $^1H-1D,\;^{13}C-1D$ NMR and HMBC spectra identified internal-ester-transfer of 2,2,4-trimethyl-1,3-pentanediol-1-isobutyrate during the reaction. 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate gave better properties in PVC than 2,2,4-trimethyl-1,3-pentanediol diisobutyrate(TXIB, a trademark of Eastman Chemicals) such as lower viscosity, higher tensile strength and better elongation. In particular, remarkably reduced migration compared with TXIB suggested a reduced emission of VOC(volatile organic compound) from PVC.

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유기용제의 Gel화 특성

  • 강영구;김정훈
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.05a
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    • pp.462-467
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    • 2003
  • Organic solvent를 원료로 한 액상 세척제는 가전제품, 컴퓨터용품, 전기기구 세척등의 민수 용품과 산업용 정밀 기계부품과 같은 대상물 세척 등에 사용되고 있다. 그러나 일반 유기용제를 주성분으로 한 유기용제형 세척제의 경우 장기 오염물질에 따른 세척력 저하, 공정상 VOC(Volatile Organic Compound)가 과도 발생할 뿐만 아니라 비생분해성, 높은 증기압, 화재 및 폭발 위험성, 냄새 성분 발생 등 안전 및 보건상 치명적인 결함이 있다.(중략)

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The Analysis of Volatile Organic Compounds in Water by Using the Purge-and-Trap and the Gas Chromatography/Mass Selective Detector with Modified Indirect Coupling (퍼지-트랩장치와 변형된 간접 결합기를 부착한 기체크로마토그래피/질량 선택성 검출기를 이용한 물중의 휘발성 유기화합물의 분석)

  • 정영자
    • The Korean Journal of Food And Nutrition
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    • v.12 no.2
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    • pp.191-191
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    • 1999
  • A Purge & Trap Concentrator was used to analyze various volatile organic compounds(VOCs) in wat-er. The object of this study was to observe the purge efficiency of 40 VOCs in water according to the change of parameters (purge time drypurge time sample temperature) and to determine the optimum condition for VOCs using the purge & Trap concentrator interfaced with a narrow capillary connected to a gas chromatography/mass spectrometry. The optimum condition of purge and trap is as follows: purge time at 11min drypurge time at 5min sample temperature at 6$0^{\circ}C$ at constant purge flow (40mol/min) constant desorption flow(20ml/min) desorption temperature(2$25^{\circ}C$) and desorption time (1min) At this analytical condition the detection limits of VOCs was in the range of 0.1~0.5$\mu$g/ml and the purge efficiency of each compound was over 70%.

An Effects of Air-Assisted-Catalyst Element for Reducing Density of Formaldehyde in a New House (신축주택에서 포름알데히드 농도저감에 대한 공기 촉매제의 효과에 관한 연구)

  • Jo, Hyeon-U;Park, U-Yeol;Jo, Hun-Hui;Jo, Ho-Gyu;Gang, Gyeong-In
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.3
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    • pp.161-167
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    • 2004
  • The sick house syndrome is occurred from the harmful elements that the building interior materials are given off after building construction or renovation. The appropriate methods, which is to prevent sick house syndrome from spreading have to be selected before building construction or renovation. Thus, this study is to measure the density of formaldehyde, one of the volatile organic compounds after sprinkling air-assisted-catalyst on the building interior space. As a result, the emit value of formaldehyde is measured 0.07ppm that is lower than the standard of Environmental Protection Agency and World Health Organization, 0.1ppm, and the standard of Ministry of Health, Labour, and Welfare of Japan, 0.08ppm.

Simultaneous Analysis of Semi-Volatile Organic Acid Priority Pollutants in Soil (토양 중의 비휘발성 산성 유기 Priority Pollutants 동시분석에 관한 연구)

  • Lee, Seung Seok;Park, Gyo Beom;Lee, Seong Geun
    • Journal of the Korean Chemical Society
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    • v.38 no.3
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    • pp.246-253
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    • 1994
  • The simultaneous analysis of 11 semi-volatile organic acid compound which are listed as priority pollutants by EPA, were performed by GC/MS-SIM(selected ion monitoring). Two extraction procedures, sonication extraction and Soxhlet extraction, were studied as an extraction and concentration method for priority pollutants in soil. Accurecy and precision of the methods were measured by the calculation of mean recovery, mean relative standard deviation, and method detection limit. Finally, limitations and prospects were discussed.

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A Trend of VOC(Volatile Organic Compound) Control and Patent Analysis on the VOC Control Technical (국내의 VOC 제거 및 회수에 대한 연구동향 및 특허분석)

  • Kim, Pilh-Hwan;Hua, Jin-Mei;Lee, Byung-Ho;Jeong, Hyo-Min;Chung, Han-Shik
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.132-135
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    • 2007
  • VOCs(Volatile Organic Compounds) have been recently enacted by several regulations to the environment since the end of 1990's. So, it need to control emissions of VOCs from industrial cite. VOC controls include all technologies which either collect the VOCs for recovery and reuse or destroy the VOCs. In this study, the VOC control technical trend was searched. Additionally, it was compared to the number of patent along to the year in Korea.

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Degradation of Volatile Organic Compound Mixtures Using a Biofiltration System (생물여과 시스템을 이용한 다성분계 휘발성 유기화합물의 분해)

  • 윤인길;박창호
    • KSBB Journal
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    • v.15 no.5
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    • pp.501-506
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    • 2000
  • A bench-scale air biofilter was evaluated for the removal of volatile organic compounds (VOCs) from a gas stream. Compost and peat were used as the biological attachment media. Biofilter operating parameters such as incoming VOCs concentrations, temperature, and packing materials were examined. After 26 days of acclimation periods, at 25$^{\circ}C$ and 45$^{\circ}C$, the biofilter removed more than 90% of 30 to 72 mg/㎥ of total VOC. After 40 days of operation, the concentrations of isoprene, toluene, and m-xylene were reduced to 96∼99, 91∼93, and 91∼93% of the original concentrations. VOC removal efficiency was not affected by the temperature. The medium pH was maintained near neutral (pH 6.5∼7.1). After 37 days of operation, the total bacteria count in the biofilter media increased to 1.12${\times}$10(sup)8 cells/g of medium.

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Properties of Gel-like Compounds Containing Flammable Solvents (Gel형 인화성 용제 Compound의 특성)

  • 강영구;김정훈
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.94-100
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    • 2003
  • Gel-like compounds containing flammable solvents were prepared to use fur cleaning agents in field of innovative industries and general purposes. And experiments were conducted to improve the defects of liquified flammable solvents from the view point of safety and health hazards. Flammable solvents used in this study were several single component flammable solvents(turpentine oil, N-methyl-2-pyrrolidone(NMP), d-limonene) and multi component flammable solvent(gasoline and ethanol). For gelation of flammable solvents, commercially Known as Aerosil(equation omitted) 200 fumed silica and triethanolamine(TEA) were used as gelation agent dispersant. The analyses on properties of gel-like compounds was studied by gelation and viscosity test pH test, volatility test and differential scanning calorimetry(DSC) measurement. The experimental results indicate that gel-like compounds containing flammable solvents have pH stability, high viscosity, volatile organic compounds(VOC) control by the decrease of volatility and odor component generation, fluidity control etc. From the experimental values, it can be predicted that the safety in the working place is improved by manufacturing flammable solvents into gel-like compounds.

Odor Characteristics and Concentration of Malodorous Volatile Organic Compounds Emitted from a Sewer and Its Outlet (하수관거 및 토구에서 발생하는 휘발성 유기화합물 악취 특성)

  • Park, Sang Jin;Kwon, Soo Youl
    • Journal of Environmental Health Sciences
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    • v.43 no.6
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    • pp.457-466
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    • 2017
  • Objectives: This study was carried out to investigate the characteristics of volatile organic compounds (VOCs) emitted from sewerage facilities such as a sanitary sewers, outlets, and catch basins. In addition, the dominant malodorous VOCs among the compounds in this study were studied. Methods: Waste gas samples were collected at 27 points in a sanitary sewer in commercial and residental areas. The concentrations of seven volatile organic compounds, including benzene and toluene, in the samples were analyzed by gas chromatograph mass spectrophotometer (GC/MS). Odor concentrations were estimated using the concentration data of the VOCs and each compound's threshold limit value. Results: As a result, it appeared that the average concentration of total observed data for acetaldehyde was 15.98 ppb and benzene 1.87 ppb, toluene 82.31 ppb, ethyl benzene 63.12 ppb, m+p-xylene 15.66 ppb, oxylene 18.73 ppb, and styrene 4.39 ppb. VOC concentrations in the commercial area were higher than those in the residential area. VOC concentrations of waste gas emitted from sewer lines was also higher than those at the outlet and in the catch basins. It was estimated that the main malodorous VOC among the seven VOCs was acetaldehyde. Conclusions: As there is little data on VOC concentrations inside sewer facilities in Korea, these data will be helpful for estimating impact assessment of VOCs and establishing a counter-plan for the abatement of VOCs from sewer facilities in the future.