• Food Science and Biotechnology
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• 제14권4호
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• pp.450-455
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• 2005

This study was conducted to determine firstly the composition of the essential oil from fresh changpo (Acorus calamus var. angustatus Bess) roots quantitatively and qualitatively by use of two internal standards, and secondly volatile compounds which are primarily responsible for the aroma of changpo roots. Simultaneous steam distillation and extraction method was used for essential oil extraction, and aroma extract dilution analysis (AEDA) and sniffing test by gas chromatography/olfactometry (GC/O) were used to detect the characteristic impact odorants. According to the instrumental analysis of changpo root essential oil, cis, trans-famesol (47.56 mg/kg of fresh wt), octanoic acid (23.73 mg/kg of fresh wt), trans-2-dodecenal (20.28 mg/kg of fresh wt) and trans, trans-farnesol (13.81 mg/kg of fresh wt) were the most abundant compounds. Geranyl acetate, trans-nerolidol and trans, trans-farnesyl acetate were evaluated as the characteristic impact odorants of changpo roots from results of AEDA and sniffing test. Especially, geranyl acetate was considered as the most similar odor component to changpo roots by organoleptic evaluation with GC/O.

• 한국식품영양과학회지
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• 제36권12호
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• pp.1637-1642
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• 2007

생마늘과 열처리에 따른 마늘의 향기 특성과 향기추출물의 항산화활성을 확인하고자 국내산 한지형 마늘 3종(단양, 서산, 의성마늘)과 난지형 마늘 3종(남해, 남도, 대서마늘), 중국산 마늘에 대하여 simultaneous distillation and extraction(SDE) 방법으로 향기 성분을 추출하여 GC/MS로 동정하고 항산화활성을 측정하였다. 생마늘의 주요 향기성분은 allyl methyl sulfide, methyl-2-propenyl disulfide, diallyl disulfide, 2-ethylidene-1,3-dithiane, methyl-2-propenyl trisulfide, di-2-propenyl trisulfide 및 2-vinyl- 4H-1,3-dithiin 등으로 나타났다. 항산화활성이 우수한 것으로 알려진 diallyl disulfide, methyl-2-propenyl trisulfide 및 di-2-propenyl trisulfide 등은 중국산 마늘보다 한지형 마늘이 많이 함유하고 있었다. 향기성분은 열처리시 2-propanone, allyl mercaptan, methyl formic acid, 2-methyl butanal 2-methyl thiophene, methyl pyrazine, 2,2-dimethyl-1,3-dithiane 및 2-propenyl propyl disulfide 등이 새롭게 생성되었으며, allyl methyl sulfide, allyl alcohol 및 allyl sulfide 등의 분자량이 작은 화합물의 함량이 증가하였다. 산지별 생마늘의 향기 추출물에 대한 항산화활성은 농도 의존적으로 증가하였으며, 단양, 남해 및 중국산은 각각 20.07, 34.62 및 9.71%의 항산화활성을 나타내었고, 열처리 후에는 각각 79.90, 93.59 및 77.26%로 증가하였다.

• Food Science and Biotechnology
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• 제18권5호
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• pp.1288-1292
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• 2009

Volatile flavor compounds were isolated from the flowers of Chrysanthemum indicum L. (gamguk) produced in Korea and China by the hydro distillation, and were analyzed by gas chromatography-mass spectrometry (GC/MS). The yield of oils from Korean and Chinese gamguk were 2.0 and 0.5%(v/w), respectively. Sixty-three volatile compounds of Korean gamguk representing 89.28% of the total peak area were tentatively identified, including 35 hydrocarbons, 12 alcohols, 6 ketones, 3 esters, 5 aldehydes, 1 oxide, and 1 miscellaneous component. Thirty-six volatile components of Chinese gamguk constituted 58.15% of the total volatile composition were tentatively characterized, consisting of 19 hydrocarbons, 7 alcohols, 2 ketones, 2 esters, 4 aldehydes, 1 oxide, and 1 miscellaneous component. The predominant components of Korean oil were ${\alpha}$-pinene, 1,8-cineol, and chrysanthenone. Whereas, camphor, ${\alpha}$-curcumene, and ${\beta}$-sesquiphellandrene were the main aroma compounds of Chinese gamguk.

• 한국축산식품학회지
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• 제34권5호
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• pp.700-708
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• 2014

The volatile composition of veal has yet to be reported and is one of the important factors determining meat character and quality. To identify the most important aroma compounds in veal from Holstein bull calves fed one of three diets, samples were subjected to solid-phase microextraction (SPME) combined with gas chromatography-quadrupole mass spectrometry (GC-MS). Most of the important odorants were aldehydes and alcohols. For group A (veal calves fed entirely on milk for 90 d before slaughter), the most abundant compound class was the aldehydes (52.231%), while that was alcohols (26.260%) in group C (veal calves fed starter diet for at least 60 d before slaughter). In both classes the absolute percentages of the volatile compounds in veal were different indicating that the veal diet significantly (p<0.05) affected headspace volatile composition in veal as determined by principal component analysis (PCA). Twenty three volatile compounds showed significance by using a partial least-squared discriminate analysis (PLS-DA) (VIP>1). The establishment of the global volatile signature of veal may be a useful tool to define the beef diet that improves the organoleptic characteristics of the meat and consequently impacts both its taste and economic value.

• Preventive Nutrition and Food Science
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• 제14권1호
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• pp.76-85
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• 2009

This study determined the effect of refrigerated and thermal storage on the volatile profile of commercial aseptic soymilk. Volatile components in commercial aseptic soymilk stored either under refrigerated ($4^{\circ}C$) or thermal ($55^{\circ}C$) conditions for 30 days were periodically analyzed by combined solvent-assisted flavor evaporation-gas chromatography-mass spectrometry (SAFE-GC-MS). The concentrations of most of the volatile components, including aldehydes, ketones, alcohols, acids, nitrogen- and sulfur-containing compounds, alkylfurans, furan derivatives and phenolic compounds, were affected to a greater extent by thermal storage compared with refrigerated storage. Profound increases in some volatile compounds with low odor detection thresholds, such as hexanal, octanal, (E)-2-octenal, (E,E)-2,4-decadienal, 1-octen-3-ol, 3-ethyl-2,5-dimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 2-pentylfuran, 4-hydroxy-2,5-dimethyl-3(2H)-furanone, dimethyl trisulfide, guaiacol, 4-vinylguaiacol and 4-vinylphenol, were observed in thermal stored soymilk. The volatile profile changes caused by thermal storage may influence the aroma quality of thermal-stored aseptic soymilk.

• 한국식품영양과학회지
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• 제28권5호
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• pp.973-979
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• 1999

Volatile compounds from twigs, needles and sprouts in Pinus densiflora were extracted with n hexane, diethyl ether or ethanol for 24 hours, and the extracted compounds were separated and identified by gas chromatography and mass selective detector. The kinds and amount of volatile compounds extracted from three parts of Pinus densiflora were different in solvent extraction and the extraction by the modified Liken Nickerson apparatus. The contents of volatile compounds of twigs contained more than those of needles and sprouts, and the volatile compounds were extracted more in n hexane than the others. In the extraction with hexane, the main volatile compounds of twigs were 18.5% pinene, 14.5% limonene, 12.7% pinene and 3.2% myrcene. Sprouts were 16.8% limonene, 4.4% pinene, 4.3% pinene and 1.7% myrcene. Needles contained 14.7% pinene, 5.4% pinene, 2.2% limonene and 0.8% myrcene. The highest yield for pine aroma was shown in the extraction from pine twigs with n hexane, and in this extraction the amounts of pinene, pinene and limonene were 742 g, 1108 g and 922 g per gram sample, respectively.

• Food Science and Biotechnology
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• 제18권6호
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• pp.1322-1329
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• 2009

The present study focused on the effects of peel contact on the volatile compounds of orange wines. The volatile compounds were analyzed by sensory and instrumental analyses. Solid-phase microextraction (SPME) was used for extraction of volatile compounds. A total of 19 and 27 volatile compounds were identified in without and with peel contact wines respectively. Esters were quantitatively the dominant group of volatile compounds in without peel contact wines, while terpenes were the most abundant compounds in peel contact wines. Totally 11 and 14 new formed compounds were found in without and with peel contact wines, mainly were esters, alcohols, and acids. According to sensory analysis, the peel contact wine showed a more citrus-like and fruity aroma than the wines without peel contact.

• Preventive Nutrition and Food Science
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• 제16권1호
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• pp.45-54
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• 2011

Volatile components in commercial pine needle (Pinus densiflora S. and Z.) powder were extracted using simultaneous steam distillation and a solvent extraction (SDE) apparatus, and were analyzed by gas chromatography-mass spectrometry (GC-MS). A total of 230 compounds divided into 13 groups were identified, which included alcohols (42), ketones (39), aldehydes (32), terpenes (30), alkenes (17), esters (14), furans (14), benzenes (10), alkanes (8), napthalenes (7), acids (6), miscellaneous compounds (6), and phenols (5). Among the 230 compounds identified, 96 compounds were positively confirmed and quantified, and the rest of the compounds were tentatively identified. The major volatile components identified at relatively high levels were dodecanoic acid, hexadecanoic acid, hexanal, benzaldehyde, (Z)-3-hexen-1-ol, 1-penten-3-one, limonene, and $\beta$-caryophyllene oxide. Among the groups, terpenes accounted for 60.18% of the total concentration of all the volatile components. Some volatile components might account for the unique aroma and the biological activity of the sample.

• 한국연초학회지
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• 제20권1호
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• pp.115-123
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• 1998

The semi-volatile fraction of cigarette mainstream smoke contains the most important aroma and taste that enhance smoke flavor. The components in mainstream smoke were analysed for commercially available cigarettes. To compare the semi-volatile components delivered from mainstream smoke of domestic cigarette with imported cigarette, we analyzed three types of filter cigarettes such as cellulose acetate mono filter, carbon dual filter and slim filter cigarette. Mainstream smoke was collected with a combination of Cambridge filter pad and liquid trap containing a small amount of acetone cooled by dry ice-methanol. We have identified 43 components from mainstream smoke by GC and GC/MS and found that benzene, toluene, 4-hydroxy-4-methyl-2-pentanone, 5-methyl-2-furaldehyde, acetic acids nicotine and triacetin were the main peaks in mainstream smoke. Also we have compared the relative amounts of semi-volatile compounds delivered from the domestic and imported cigarettes with three different filters. From the results of this study, the relative amounts of limonene, acetic acid, 5-methyl-Lfuraldehyde delivered from the imported cigarettes were generally higher than those of the domestic one's.

• 한국식품과학회지
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• 제47권2호
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• pp.137-144
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• 2015

인스턴트커피는 보통 커피크리머 또는 탈지분유와 설탕을 섞어서 커피믹스라는 불리는 형태로 사용된다. 커피믹스의 맛은 커피에 혼합하는 성분에 의해서 영향을 받는다. 본 연구의 목적은 커피믹스의 제조 시에 혼합하는 성분이 커피의 향기와 맛에 미치는 영향을 GC-HS-SPME로써 분석하고, 맛을 평가하는데 있었다. 8종의 시판 커피믹스와 각각에 사용된 블랙커피 8종을 제조회사로부터 제공받아 분석에 사용하였다. 커피믹스에 사용하는 대표적인 혼합 성분인 커피크리머나 탈지분유 등 커피 whitener 는 자체의 향기는 매우 약해서 향기성분의 정체를 확인할 수 없었으나, 이들을 블랙커피에 넣었을 때에는, 블랙커피일 때와 비교하여 휘발성 향기성분이 증가 또는 감소하는 변화를 확인하였다. 이러한 효과는 두 가지 종류의 커피 whiteners에서 확인하였으나 탈지분유보다는 지방이 많고 점성이 높은 커피크리머에서 더 잘 보여주었다.