• Title/Summary/Keyword: Voc

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Ozone Simulations over the Seoul Metropolitan Area for a 2007 June Episode, Part I: Evaluating Volatile Organic Compounds Emissions Speciated for the SAPRC99 Chemical Mechanism (2007년 6월 수도권 오존모사 I - 광화학측정자료를 이용한 SAPRC99 화학종별 휘발성유기물질 배출량 입력자료 평가)

  • Kim, Soon-Tae
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.5
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    • pp.580-602
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    • 2011
  • Volatile organic compound (VOC) emissions in the 2007 CAPSS (Clean Air Protection Supporting System) emissions inventory are chemically speciated for the SAPRC99 (Statewide Air Pollution Research Center 99) mechanism, following the Source Classification Code (SCC) matching method to borrow the U.S.EPA's chemical speciation profiles. CMAQ simulations with High-order Direct Decoupled Method (HDDM) are in turn applied to evaluate uncertainty in the method by comparing the simulated model VOC species to the observations in the Seoul Metropolitan Area (SMA) for a 2007 June episode. Simulations under-predicted ALK1 to ALK4 in SAPRC99 by a factor of 2 to 5 and over-predicted ALK5 by a factor of 7.5 while ARO1, ARO2, OLE1, and ethylene (ETH) are comparable to the observations, showing relative difference by 10 to 30%. OLE2 emissions are roughly 4 times overestimated. Emission rates for individual VOC model species are revised referring to the ratio of simulated to observed concentrations. Impact of the VOC emission changes on the overall ozone prediction was insignificant for the days of which 1-hr maximum ozone are lower than 100 ppb. However, simulations showed ozone difference by 5 to 10 ppb when high ozone above 120 ppb was observed in the vicinity of Seoul. This result suggests that evaluations on individual model VOC emissions be necessary to lead ozone control plans to the right direction. Moreover, the simulated ratios of ARO1 and ARO2 to $NO_x$ are roughly 50% lower than the observed ones, which imply that adjustment in $NO_x$ and VOC emission rates may be required to mimic the real VOC/$NO_x$ condition over the area.

Application of a Topic Model on the Korea Expressway Corporation's VOC Data (한국도로공사 VOC 데이터를 이용한 토픽 모형 적용 방안)

  • Kim, Ji Won;Park, Sang Min;Park, Sungho;Jeong, Harim;Yun, Ilsoo
    • Journal of Information Technology Services
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    • v.19 no.6
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    • pp.1-13
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    • 2020
  • Recently, 80% of big data consists of unstructured text data. In particular, various types of documents are stored in the form of large-scale unstructured documents through social network services (SNS), blogs, news, etc., and the importance of unstructured data is highlighted. As the possibility of using unstructured data increases, various analysis techniques such as text mining have recently appeared. Therefore, in this study, topic modeling technique was applied to the Korea Highway Corporation's voice of customer (VOC) data that includes customer opinions and complaints. Currently, VOC data is divided into the business areas of Korea Expressway Corporation. However, the classified categories are often not accurate, and the ambiguous ones are classified as "other". Therefore, in order to use VOC data for efficient service improvement and the like, a more systematic and efficient classification method of VOC data is required. To this end, this study proposed two approaches, including method using only the latent dirichlet allocation (LDA), the most representative topic modeling technique, and a new method combining the LDA and the word embedding technique, Word2vec. As a result, it was confirmed that the categories of VOC data are relatively well classified when using the new method. Through these results, it is judged that it will be possible to derive the implications of the Korea Expressway Corporation and utilize it for service improvement.

A numerical analysis of the degradation of VOC in the photocatalytic microreactors with different inner geometries (광촉매 마이크로 반응기의 내부 형상에 따른 VOC 분해특성에 관한 수치해석적 연구)

  • Yong, Jung-Kwon;Kim, Chang-Nyung;Youm, Min-Qou
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2896-2900
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    • 2007
  • A numerical analysis was carried out to investigate the degradation of Volatile Organic Compounds (VOC) in photocatalytic microreactors with different inner geometries. Two different cases of microreactor were considered, namely, one microreactor has bump on the channel and the other has no bump on the channel. The removal efficiency of VOC has been calculated by the Langmuir-Hinshelwood reaction rate equation that was obtained from the experimental results. From the numerical calculations, it was observed that the conversion ratio of VOC for the microchannel with bump is about 4.5% greater than the microchannel without bump. And the mass transfer characteristics in the microreactor are also shown in numerical results. These results can be used effectively for the photocatalytic numerical analysis.

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The Temporal Distribution Characteristics of Some Important VOC Species from a Nonurban Site in Naju (대기중 휘발성유기화합물의 시간적 농도 변화에 대한 연구)

  • 김조천;김기현
    • Journal of Environmental Science International
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    • v.9 no.6
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    • pp.483-488
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    • 2000
  • In this study, the distribution characteristics of volatile organic compounds (VOCs) were investigated on the seasonal basis across spring, summer, and fall during the year of 1998. According to this analysis, most VOC species investigated exhibited strong temporal trends. Over diurnal scale, there distribution characteristics were affected by seasonal factors strongly. While they showed high day/night ratio pattern during spring, the pattern was reversed during fall. When the seasonal mean values were compared between the two seasons, the spring values were systematically higher than their counterparts in most cases. In addition when our VOC measurement date were compared with those reported from elsewhere, we were able to conclude that the VOC levels in the study area are comparable to the level weakly impacted by the regional emissions of VOCs. Although our data are not sufficient enough to systematically explain the atmospheric distribution and behavior of VOCs, the findings of strong correlations among some of VOC species suggests strong need for investigating their interactions in the earth\`s atmosphere.

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A study on the Emission Characteristics and the Estimation of Emission for VOCs from Landfills (매립지에서의 VOCs 배출특성과 배출량 산정에 관한 연구)

  • 임지영;최용흠;신원근;김기현;홍지형;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.297-298
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    • 2003
  • 대기 광화학반응에서 오존 및 기타 광산화물을 생성하는 VOCs의 경우, 그 물질 자체가 갖는 독성도 물질에 따라 매우 큰 것으로 알려져 있다. 따라서 이와 관련된 많은 연구가 진행되어 왔으며, 이에 대한 규제방안 역시 지속적으로 논의되고 있으나, 이러한 연구 및 정책의 기본 자료인 VOCs의 배출량에 관련된 자료 및 연구가 매우 부실한 실정이다. 또한 이들 연구는 대부분 VOCs의 주요 배출원이라 할 수 있는 도장산업이나 자동차에 집중됨으로써 대기오염이 심각한 도시지역에 소규모로 넓게 분포하고 있는 VOCs의 배출원에 대한 연구가 미진하고, 이에 따라 전체 VOCs의 배출량에 많은 오차를 나타낼 수 있는 조건을 만들고 있다. (중략)

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A study on the characteristics of natural VOC emissions from pine trees in spring (봄철 소나무로부터 배출되는 자연 VOC(NVOC) 배출특성에 관한 연구)

  • 김조천;임준호;홍지형;장영기;주명칠;조규탁;강창희;선우영;전의찬
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.227-228
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    • 2002
  • 식생은 자연 VOC(NVOC)의 배출원으로써 상당부분(>90%)을 차지한다. 미국의 경우에는 NVOC의 배출량이 인위적인 것의 약 1.5배-5배에 이를 것으로 추정하고 있다. 우리나라도 전국토의 약 65%가 산림으로 이루어져 있어 자연 VOC가 인위적인 VOC의 양을 훨씬 초과 할 것이라고 예측된다. 지금까지 우리나라의 배출량 산정에 사용된 NVOC 배출계수는 주로 외국의 자료에 의존하여 사용되었기 때문에 그 신뢰성에 논란의 여지가 많았다. (중략)

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Mathematical Modeling and Analysis on the Behavior of VOC in an Indoor Environment (휘발성 유기화합물의 거동특성 예측을 위한 수학적 모델링 및 실내 환기특성 연구)

  • 이승철;최청렬;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.7
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    • pp.627-636
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    • 2001
  • This paper presents a numerical analysis of the emission process of volatile organic compound(VOC) from building material and its diffusion in a room. A polypropylene styrene-butadiene rubber(SBR) floor plate is chosen as the emission source of VOC. This study investigates spatial concentration distributions and time history of room-averaged VOC concentration for both with and without flushing. The results of this study show that for calculation based on ten-days period the room averaged VOC concentrations with and without flushing are quite different. the results thus suggest the need of flushing for new buildings.

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QA/QC for Analysis of the Ambient VOC by Using Canister and GC/MS (Canister와 GC/MS를 이용한 대기 중 VOC 분석을 위한 QA/QC)

  • Jeon, Jun-Min;Heo, Dang;Bang, Hye-Jin;Choi, Won-Wook;Kim, Dong-Sool
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.85-86
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    • 2000
  • 일반 대기환경중 미량으로 존재하는 휘발성유기화합물 (VOC)은 환경학적 측면에서 다양한 문제점을 야기한다. 즉, 인체 독성 및 발암성 물질, 오존의 전구물질, 성층권의 오존층 파괴 및 지구온난화 물질로서 영향을 주며, 한편, 대기환경 중 장기 체류하기도 한다. 최근 이들 화합물의 농도는 차량 증가 등 여러 요인들에 의해 지속적인 증가추세에 있다. 따라서 VOC로 인한 대기오염의 악화에 따라 체계적인 관리가 요구되고 있으며, 이와 더불어 VOC에 대한 정확한 측정 및 분석 능력에 입각한 신뢰성 있는 자료의 확보가 가장 절실하게 요구되고 있다. (중략)

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A Study on the Volatile Organic Compounds Analysis Method for Visible Light-Responsive Photocatalyst Treated Vehicle Interior Materials (가시광촉매가 처리된 자동차 내장재의 VOC 분석방법에 대한 연구)

  • Choi, Sei Young
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.221-224
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    • 2013
  • In this study, VOC analysis method of vehicle interior materials and parts treated to visible-light responsive photocatalyst was tested by sample bag filled with air instead of nitrogen. As a result, when analyzed VOC of vehicle interior materials and parts, sample bag filled with the nitrogen was not confirmed of effect reducing VOCs and formaldehyde. However, VOCs and formaldehyde of sample bag that was filled with air instead of nitrogen, decreased significantly. Reaction effect for visible light-responsive photocatalyst was confirmed that sample bag of vehicle interior materials and parts should be filled with air instead of nitrogen.

The study of measure the VOC using MOS Sensor (금속 산화물 센서 이용한 VOC의 측정에 관한 연구)

  • Kim, Dong-Jin;Jung, Young-Chang;Hong, Chul-Ho;Joo, Min-Sik
    • Proceedings of the KIEE Conference
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    • 2003.07d
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    • pp.2079-2081
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    • 2003
  • 현재 산업화 사회가 가속됨에 따라 인체에 유해한 물질들이 발생한다. 그 중에서 VOC(Volatile Organic Component)는 인체에 치명적인 해를 일으키는 물질이다. 본 논문은 MOS(Metal Oxide Semiconductor) 센서를 이용하여 인체에 치명적인 유해 물질인 VOC를 측정하였다. 현재 VOC의 측정은 GC(Gas Chromatograph)를 이용하는데 이는 측정 시간이 길며 숙련된 측정자에 의해서만 측정이 가능하고 그 분석이 가능하다. 그러나 MOS 센서를 이용하면 숙련되지 않은 측정자도 측정이 가능하며 인공신경망을 이용하여 그 분석을 함으로서 누구나 쉽게 분석이 가능하고 실시간으로 측정이 가능하다.

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