• Title/Summary/Keyword: Visible light sensitive

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Deposition Behavior and Photoelectrochemical Characteristics of Chlorophyll a Langmuir-Blodgett Films

  • Park, Hyun-Goo;Oh, Byung-Keun;Lee, Won-Hong;Park, Jeong-Woo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.3
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    • pp.183-188
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    • 2001
  • The deposition behavior and photoelectric response characteristics of chlorophyll a(Chl a) monolayers and multilayers were investigated under various film fabrication conditions. Chl a LB films were deposited onto quartz and pretreated ITO glass substrates under several fabrication conditions, including surface pressure and number of layers. The absorption spectra of Chl a in a solution state and solid-like state (LB films) were fairly consistent with each other, and two absorption peaks were found at 678 and 438nm, respectively. The prepared Chl a LB films were set into an electrochemistry cell equipped with a Pt plate as the counter electrode, and the photoelectric response characteristics were obtained and analyzed relative to the light illumination. By considering the resulting photocurrents, the optimal fabrication conditions for Chl a LB films were determined as 20mN/m of surface pressure and 20 layers. The action spectrum of the Chl a LB films was obtained in the visible region, and was found to be in good agreement with the absorption spectrum. The possible application of the proposed system as a constituent of an artificial color recognition device was suggested based on combining with the photoelectric conversion property of another light-sensitive biological pigment.

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Study of evacuation fire doors in multiple facilities (다중이용시설의 피난방화문에 관한 연구)

  • Cha, Jong-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.12
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    • pp.7380-7384
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    • 2014
  • Evacuation fire doors were manufactured by applying phosphorescent paint to the whole fire door whose performance was already recognized, and applying heat sensitive paint around the grip. The facility was improved by the evacuation and safety functions on the fire door, which has been used as only a fire facility, and the fire door is also used as an evacuation facility. The brilliance of the evacuation safety fire door manufactured in this study passed the brilliance test of Korea Fire Institute with a performance more than the brilliance (7mcd after 60 minutes) of the existing inducement sign. During a fire, the visible area is larger than the evacuation door inducement, etc. and light preventive status in the lower part of the fire door was observed during the descent of smoke. Therefore, it is considered to extend the evacuation effective time of evacuators. In heat sensitive paint applied around the grip, a color change is observed on the fire door when approaching a certain temperature ($70^{\circ}C$). Therefore, the first disaster that evacuators can encounter on the grip of a fire door during a fire can be prevented and should be helpful in recognizing the backfiring possibility and preventing safety accidents for firefighters who must enter a fire space.

Different Photosynthetic Responses of Black Cherry (Prunus serotina) with Different Sensitivities to Ambient Ozone Concentrations under Natural Conditions (자연상태에서 대기 중 오존 농도에 상이한 민감성을 가진 Black Cherry(Prunus serotina)의 상이한 광합성 반응)

  • Yun, Myoung-Hui;Chevone, Boris I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.4
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    • pp.132-140
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    • 2008
  • Two different sensitivity classes of black cherry (Prunus serotina) under the natural growing environmental conditions were assessed adjacent to Air Monitoring Station located at Horton research center in Giles County, Virginia, USA. Ambient ozone concentrations, leaf gas exchange, and visible foliar injury were measured on-site during the growing seasons of 2000, 2001, and 2002. Ambient ozone exposures were sufficient to induce typical foliar visible injury corresponding with the reduction in photosynthetic activities only in sensitive black cherry. There were positive correlations between increasing cumulative ozone concentration and percent reduction in maximum net photosynthetic rates ($Pn_{MAX}$) under saturating light conditions and in quantum yield for carbon reduction (${\Phi}CO_2$) of sensitive black cherry compared to tolerant black cherry. There was a negative correlation between chlorophyll content and percent leaf injury in sensitive black cherry. Furthermore, $Pn_{MAX}$ was inversely related to percent leaf injury.

Effect of UV Radiation on Early Growth of Korean Rice Cultivars(Oryza sativa L.)

  • Choi, Kwan-Sam;In, Jun-Gyo;Kang, Si-Yong;Bae, Chang-Hyu;Lee, Hyo-Yeon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.3
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    • pp.296-301
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    • 1999
  • The concerns on the crop damage by ultraviolet (UV) radiations is increasing owing to the decrease of their absorbing stratospheric ozone in the tropospheric. Cultivar differences on early growth of UV radiation among five Korean rice cultivars, four japonica types and one Tongil type (indica-japonica cross hybrid), were studied. Pot-seeded rice plants were grown under four different radiation conditions, i.e., visible radiation only, visible radiation with supplemented with high or low dose of UV-B (280~320 nm in wavelength) and UV-C (less than 280 nm in wavelength). The inhibitory degree on plant height, shoot and root weight and length of leaf blade and leaf sheath were determined at 40 days after seeding. UV-C showed the most severe inhibitory effect on the degree of biomass gain and leaf growth in most cultivars examined, followed by high UV-B and low UV-B. Among the cultivars used, the Kuemobyeo was the most sensitive cultivar and had not repair or showed resistance ability to continued irradiation of UV radiation. However, Janganbyeo and Jaekeon showed different responses that the elongation of leaf blades was promoted on 2nd and 3rd leaves and inhibited on 4th and 5th leaves but this inhibitory degree was reduced on 6 th and 7th leaves. Such tendency on leaf growth means that both cultivars had low sensitivity and most resistant ability to continued irradiation of UV radiation. While Tongil showed different response to enhanced UV radiation, ie., low UV-B promoted leaf growth but the inhibitory was severely increased by continued irradiation of high UV-B and UV-C, which means that Tongil had high threshold of UV radiation for response as an inhibitory light of plant growth. The results of this study indicate that the differences on sensitivity or resistant to the effects of UV radiation were existed among Korean rice cultivars.

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Use of laser fluorescence device 'DIAGNODent$^{(R)}$' for detecting caries (레이저 우식진단기기 'DIAGNODent$^{(R)}$'의 활용)

  • Lee, Byoung-Jin
    • The Journal of the Korean dental association
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    • v.49 no.8
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    • pp.461-471
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    • 2011
  • The detection of carious lesions is a key point to apply appropriate preventive measures or operative treatment of dental caries. A laser fluorescence device DIAGNOdent$^{(R)}$ (KaVo, Biberach, Germany) has also been shown to be of additional clinical value in the detection of initial caries. This report focus on the DIAGNOdent$^{(R)}$ for caries detection. DIAGNOdent$^{(R)}$ irradiate visible red light at a wavelength of 655 nm to elicit near-infrared fluorescence from caries lesion. This device is known as a reproducible method for caries detection, with good sensitivity and specificity especially for caries detection on occlusal and accessible smooth surfaces. DIAGNOdent$^{(R)}$ tended to be more sensitive method of detecting occlusal dentinal caries, however, showed more false-positive diagnoses than the visual inspection. So Clinician should not use the device as a clinician's primary diagnostic method and it is recommended that the device should be used in the decision-making process in relation to the diagnosis of caries as a second opinion in cases of doubt after visual inspection. The trend of modern dentistry would be a preventive approach rather than invasive treatment of the disease. This is possible only with early detection and respective preventive measures, DIAGNOdent$^{(R)}$ can help the changes.

Aerosol Direct Radiative Forcing by Three Dimensional Observations from Passive- and Active- Satellite Sensors (수동형-능동형 위성센서 관측자료를 이용한 대기 에어러솔의 3차원 분포 및 복사강제 효과 산정)

  • Lee, Kwon-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.159-171
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    • 2012
  • Aerosol direct radiative forcing (ADRF) retrieval method was developed by combining data from passive and active satellite sensors. Aerosol optical thickness (AOT) retrieved form the Moderate Resolution Imaging Spectroradiometer (MODIS) as a passive visible sensor and aerosol vertical profile from to the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) as an active laser sensor were investigated an application possibility. Especially, space-born Light Detection and Ranging (Lidar) observation provides a specific knowledge of the optical properties of atmospheric aerosols with spatial, temporal, vertical, and spectral resolutions. On the basis of extensive radiative transfer modeling, it is demonstrated that the use of the aerosol vertical profiles is sensitive to the estimation of ADRF. Throughout the investigation of relationship between aerosol height and ADRF, mean change rates of ADRF per increasing of 1 km aerosol height are smaller at surface than top-of-atmosphere (TOA). As a case study, satellite data for the Asian dust day of March 31, 2007 were used to estimate ADRF. Resulting ADRF values were compared with those retrieved independently from MODIS only data. The absolute difference values are 1.27% at surface level and 4.73% at top of atmosphere (TOA).

Effects of Different Dopants(B, AI, Ga, In) on the Properties of Transparent conducting ZnO Thin Films (B, Al, Ga, In의 도핑물질이 투명 전도성 ZnO 박막의 특성에 미치는 영향)

  • No, Young-Woo;Cho, Jong-Rae;Son, Se-Mo;Chung, Su-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.242-248
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    • 2008
  • The structural, optical and electrical properties of ZnO films doped with 1.5 at% of 3A materials(B, Al, Ga, In) were studied by sol-gel process. The films were found to be c-axis (002) oriented hexagonal structure on glass substrate, when post heated at 500 $^{\circ}C$. The surface of the films showed a uniform and nano size microstructure and the crystalline size of doped films decreased. The lattice constants of ZnO:B/Al/Ga increased than that of ZnO, while ZnO:In decreased. All the films were highly transparent(above 90 %) in the visible region. The energy gaps of ZnO:B/Al/Ga were increased a little, but that of ZnO:In was not changed. The resistivities of ZnO:Al/Ga/In were less than 0.1 $\Omega$cm. All the films showed a semiconductor properties in the light or temperature, however ZnO:In was less sensitive to it. A figure of merit of ZnO:In had the highest value of 0.025 $\Omega^{-1}$ in all samples.

Mass constraint and temperature estimation of eruptive plasma in X-ray

  • Lee, Jin-Yi;Raymond, John C.;Reeves, Katharine K.;Moon, Yong-Jae;Kim, Kap-Sung
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.60.2-60.2
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    • 2013
  • We investigate several eruptive hot plasma observations by Hinode/XRT. Their corresponding EUV and/or white light CME features are visible in some events. Using those observations, we determine the mass constraints of eruptive plasma by assuming simplified geometrical structures of the plasma. In some events, their associated prominence eruptions and eruptive plasma were observed in EUV observations as absorption or emission features. The absorption feature provides the lower limit to the cold mass while the emission feature provides the upper limit to the mass of observed eruptive plasma in X-ray and EUV passbands. We compare the mass constraints for each temperature responses and find that the mass in EUV and XRT are smaller in their upper or lower limit than total mass in coronagraph. About half eruptive events in XRT have no corresponding CME, which may be due to failed eruptions or low plasma density. In addition, some events were observed by a few passbands in X-ray, which allows the determination of the eruptive plasma temperature using a filter ratio method. We present the isothermal plasma temperatures by the filter ratio method. These are possibly an average temperature for higher temperature plasma because the XRT is more sensitive in higher temperature.

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Synthesis and Characterization of Temperature and pH Sensitive Graft Copolymers Based on Pluronic (Pluronic을 기초로 한 온도와 pH에 민감한 그래프트 공중합체의 합성과 특성)

  • Oh, Yeon-Jeong;Lee, Gi-Baek;Park, Sung-Young
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.223-228
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    • 2012
  • Temperature and pH sensitive graft copolymers [Pluronic-$g$-poly(NIPAAm-$co$-MMA), Polymer A] and [Pluronic-$g$-poly( NIPAAm-$co$-MAA), Polymer C] were synthesized by macro radical graft polymerization with $N$-isopropylacrylamide (NIPAAM)/$N,N$-diethylaminoethylmethacrylate (DEAEMA) and $N$-isopropylacrylamide (NIPAAm)/methacrylic acid (MAA) based on Pluronic, respectively. The chemical structure and molecular weight of the graft copolymers was characterized by $^1H$ NMR and gel permeation chromatography. The aqueous solution properties of graft copolymers were measured using a UV-visible spectrophotometer, contact angle and dynamic light scattering equipment with different temperature and pH conditions. The obtained graft copolymers showed a very sensitive phase transition in response to temperature and pH in aqueous media which suggested that the amine group of DEAEMA segment and carboxylic group of MAA had a great influence on the lower critical solution temperatures (LCST) in Polymer A and C, respectively. The graft copolymers can be utilized for drug delivery system and molecular switching applications where responses to temperature and pH changes are relevant.

Improvement of Short-Circuit Current of Quantum Dot Sensitive Solar Cell Through Various Size of Quantum Dots (양자점 입도제어를 통한 양자점 감응형 태양전지 단락전류 향상)

  • Ji, Seung Hwan;Yun, Hye Won;Lee, Jin Ho;Kim, Bum-Sung;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.16-22
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    • 2021
  • In this study, quantum dot-sensitized solar cells (QDSSC) using CdSe/ZnS quantum dots (QD) of various sizes with green, yellow, and red colors are developed. Quantum dots, depending their different sizes, have advantages of absorbing light of various wavelengths. This absorption of light of various wavelengths increases the photocurrent production of solar cells. The absorption and emission peaks and excellent photochemical properties of the synthesized quantum dots are confirmed through UV-visible and photoluminescence (PL) analysis. In TEM analysis, the average sizes of individual green, yellow, and red quantum dots are shown to be 5 nm, 6 nm, and 8 nm. The J-V curves of QDSSC for one type of QD show a current density of 1.7 mA/㎠ and an open-circuit voltage of 0.49 V, while QDSSC using three type of QDs shows improved electrical characteristics of 5.52 mA/㎠ and 0.52 V. As a result, the photoelectric conversion efficiency of QDSSC using one type of QD is as low as 0.53 %, but QDSSC using three type of QDs has a measured efficiency of 1.4 %.