• 제목/요약/키워드: Viscosity rule

검색결과 34건 처리시간 0.019초

Effect of Electrolytes on Rheological Properties of Young-Il Bentonite Suspension

  • Shin, Wha-Woo;Lee, Kwang-Pyo
    • Archives of Pharmacal Research
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    • 제8권2호
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    • pp.91-98
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    • 1985
  • Dependence of the flow behavior of aqueous suspension of Young-Il bentonite on the concentration and the type of electrolytes was studied. Viscosity measurements were made was Rion Viscotester, using No. 3 rotor at 62.5 R. P. M. at 25.deg.C. As electrolyte concentration increased, the apparent viscosity was observed to increase. Changes in viscosity were in general agreement with predicted results based on the Hofmeister sequence and the Schulze-Hardy rule. The observed electrolyte effect on the apparent viscosity was discussed in terms of the Verwey-Overbeek theory.

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Small and Large Deformation Rheological Behaviors of Commercial Hot Pepper-Soybean Pastes

  • Choi, Su-Jin;Kang, Kyoung-Mo;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • 제15권6호
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    • pp.871-876
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    • 2006
  • Rheological behavior of commercial hot pepper-soybean paste (HPSP) was evaluated in small amplitude oscillatory and steady shear tests. Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) as a function of angular frequency (${\omega}$), and shear stress (${\sigma}$) as a function of shear rate (${\gamma}$) data were obtained for 5 commercial HPSP samples. HPSP samples at $25^{\circ}C$ exhibited a non-Newtonian, shear-thinning flow behavior with high yield stresses and their flow behaviors were described by power law, Casson, and Herschel-Bulkley models. Time-dependent flow properties were also described by the Weltman, Hahn, and Figoni & Shoemaker models. Apparent viscosity over the temperature range of $5-35^{\circ}C$ obeyed the Arrhenius temperature relationship with activation energies (Ea) ranging 18.3-20.1 kJ/mol. Magnitudes of G' and G" increased with an increase in ${\omega}$, while ${\eta}^*$ decreased. G' values were higher than G" over the most of the frequency range (0.63-63 rad/sec), showing that they were frequency dependent. Steady shear viscosity and complex viscosity of the commercial HPSP did not fit the Cox-Merz rule.

점탄성 고분자 용액의 정상유동특성과 동적 유변학적 성질의 상관관계 -비선헝 스트레인 척도를 사용한 Cox-Merz 법칙의 검증- (Relationship between Steady Flow and Dynamic Rheological Properties for Viscoelastic Polymer Solutions - Examination of the Cox-Merz Rule Using a Nonlinear Strain Measure -)

  • 송기원;김대성;장갑식
    • 유변학
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    • 제10권4호
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    • pp.234-246
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    • 1998
  • 본 연구의 목적은 고분자 농후용액의 정상유동특성(비선형 거동)과 소진폭 전단변형하에서의 동적 점탄성(선형 거동) 간에 존재하는 상관관계를 파악함에 있다. 이를 위해 Advanced Rheometric Expansion System(ARES)과 Rheometrics Fluids Spectrometer (RFS II)를 사용하여 폴리에틸렌 옥사이드, 폴리이소부틸렌 및 폴리아크릴 아마이드 농후용액의 정상류점도 및 동적 선형 점탄성을 광범위한 전단속도와 각주파수 영역에서 측정하였다. 이들 측정결과로부터 정상류점도와 동적점도 또는 동적 유동성간의 상관관계를 제시한 몇 가지 관계식의 적용성을 비교.검토하였다. 그리고 정상류점도와 복소점도의 절대치를 비교하여 양자간의 등가관계를 나타내는 Cox-Merz 법칙의 적용성에 대한 농도의 영향을 실험적으로 검증하였다. 나아가서 대변형하에서의 비선형성의 정도를 나타내는 비선형 스트레인 척도의 개념을 도입하여 Cox-Merz 법칙의 적용성에 미치는 영향을 이론적 관점에서 고찰하였다. 이상의 연구를 통해 얻어진 결과를 요약하면 다음과 같다. (1) 정상류점도의 전단속도 의존성과 동적 점탄성의 각주파수 의존성간에 제시된 여러 관계식들 중에서 정상류점도와 복소점도 절대치간의 등가관계를 나타내는 Cox-Merz법칙이 가장 우수한 적용성을 갖는다. (2) 높은 전단속도 또는 각주파수 영역에서는 정상류점도와 복소점도의 관계가 용액 농도에 따라 서로 상이하게 나타난다. 즉 낮은 농도의 용액에서는 정상류점도가 복소점도에 비해 다소 큰 값을 나타내며, 농도가 증가할수록 이러한 경향은 역전되어 높은 농도의 용액에서는 복소점도가 정상류점도에 비해 큰 값을 갖는다. (3) 비선형 스트레인 척도는 작은 크기의 변형량에서는 직선적으로 증가하다가 점차적으로 그 증가율이 감소하여 최대치에 도달한 후 그 이상의 변형량 영역에서는 변형량이 증가함에 따라 점차 감소하는 거동을 나타낸다. 이러한 거동은 스트레인 증가에 따라 진폭이 점차로 감소하는 감쇠진동함수의 형태를 갖는 이론적 예측과는 상당한 차이를 나타낸다. (4) 대변형하에서 비선형 스트레인 척도의 기울기 (고분자 용액의 비선형성의 정도)는 Cox-Merz 법칙의 적용성에 영향을 미치며, 이 값이 감소할수록 Cox-Merz 법칙은 더욱 잘 성립한다.

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Fuzzy rule을 이용한 공압 서보 제어 알고리즘의 개발 (Development of pneumatic servo control algorithm using fuzzy rule)

  • 박상덕;정규원;염영일
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 22-24 Oct. 1991
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    • pp.1127-1132
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    • 1991
  • Pneumatic control system has been used mainly for endpoint position control because of the compressibility, viscosity and low output stiffness of air which causes nonlinear flow characteristics. In this paper, pneumatic position control algorithms using fuzzy rule were developed to achieve faster and more stable response than conventional PI control algorithm. The performances of the proposed algorithms were compared by computer simulations with them of PI controller. From those simulations it was shown that the proposed algorithms are more efficient about settling time, steady state error and overshoot than PI control algorithm.

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불활성 기체 혼합물의 물성에 관한 열역학적 실험식 (Thermodynamic Empirical Equations for Physical Properties of Inert Gas Mixtures)

  • 김재덕;여미순;이윤우;노경호
    • 한국화재소방학회논문지
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    • 제17권2호
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    • pp.43-49
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    • 2003
  • 대체 소화제로 사용되는 불활성 기체 중 Ar, $N_2$, $CO_2$에 대한 혼합물에서의 물성(포화압력, 밀도, 점도)에 관한 실험식을 구하였다. Mixing rule에 의해 계산한 값을 이용하여 다항식 등의 회귀분석에 의해서 실험식을 얻었다. 포화압력은 온도에 대하여 1차 실험식으로 표시하였다. 압축인자와 포화압력을 이용하여 온도에 대한 밀도에 관한 실험식을 제시하였다. 점도는 온도에 대한 지수함수로 표시하였다. Ar, $N_2$, $CO_2$혼합물의 조성이 40/50/10(mol. %)에서 열역학적 실험식을 구하였다.

OPTIMAL LIQUIDATION OF A LARGE BLOCK OF STOCK WITH REGIME SWITCHING

  • Shin, Dong-Hoon
    • 대한수학회보
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    • 제48권4호
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    • pp.737-757
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    • 2011
  • This work is concerned with an optimal selling rule for a large position of stock in a market. Selling a large block of stock in a short period typically depresses the market, which would result in a poor filling price. In addition, the large selling intensity makes the regime more likely to be poor state in the market. In this paper, regime switching and depressing terms associated with selling intensity are considered on a set of geometric Brownian models to capture movements of underlying asset. We also consider the liquidation strategy to sell much smaller number of shares in a long period. The goal is to maximize the overall return under state constraints. The corresponding value function with the selling strategy is shown to be a unique viscosity solution to the associated HJB equations. Optimal liquidation rules are characterized by a finite difference method. A numerical example is given to illustrate the result.

숙성온도가 전통 고추장의 레올로지 특성에 미치는 영향 (Effect of Fermentation Temperature on Rheological Properties of Traditional Kochujang)

  • 유병승;노완섭
    • 한국식품영양과학회지
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    • 제29권5호
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    • pp.860-864
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    • 2000
  • The steady and dynamic shear rheological properties of traditional kochujang fermented at three different temperatures (20${^circ}C$, 25${^circ}C$ and 30${^circ}C$) were studied. Flow of kochujang samples showed time dependence, which was quantitatively described by the Weltman model, Kochujang samples were highly shear thinning fluids (n=0.25~0.27) with large magnitudes of Casson yield stresses (1.09~1.21 kPa). Consistency index (K) and apparent viscosity (${\eta}_{a,20}$) increased with increase in fermentation temperature of kochujang. Storage (G') and loss (G") moduli increased with increase in frequency (ω), while complex viscosity (${\eta}^{\ast}$) decreased. Based on dynamic shear data, kochujang samples exhibit structural properties similar to weak gels. The complex and steady shear viscosities at different fermentation temperatures followed the Cox-Merz superposition rule with the application of the shift factor (a=0.011~0.016).

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STRONG CONVERGENCE OF NEW VISCOSITY RULES OF NONEXPANSIVE MAPPINGS

  • AHMAD, MUHAMMAD SAEED;NAZEER, WAQAS;MUNIR, MOBEEN;NAQVI, SAYED FAKHAR ABBAS;KANG, SHIN MIN
    • Journal of applied mathematics & informatics
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    • 제35권5_6호
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    • pp.423-438
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    • 2017
  • The aim of this paper is to present two new viscosity rules for nonexpansive mappings in Hilbert spaces. Under some assumptions, the strong convergence theorems of the purposed new viscosity rules are proved. Some applications are also included.

The Flocculation of Veegum Suspension by Electrolytes

  • Kwang Pyo Lee;Robert C. Mason;Ree Takiyue
    • 대한화학회지
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    • 제16권1호
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    • pp.25-32
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    • 1972
  • The effect on the apparent viscosity of 2 wt. % Veegum suspensions of different types of electrolytes and of different electrolyte concentrations was studied. Measurements were made with a Brookfield Synchro-Lectric Viscometer, using no.3 spindle at 30 R.P.M. at $24^{\circ}C$. As electriolyte concentration increased, the apparant viscosity was observed to increase to a maximum and then to decrease. Changes in viscosity were in general agreement with predicted results based on the Hofmeister sequence and the Schulze-Hardy rule. The observed electrolyte effect on the apparent viscosity was discussed in terms of the Verwey-Overbeek theory.

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Measurements of the rheological properties of standard reference material 2490 using an in-line micro-Fourier rheometer

  • Smith R. S.;Glasscock J. A.
    • Korea-Australia Rheology Journal
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    • 제16권4호
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    • pp.169-173
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    • 2004
  • The control of the rheological properties of a fluid during processing is important and can determine the efficiency of the production in addition to the performance of the final product. The vast majority of process fluids are viscoelastic, hence an instrument that measures both the viscous and elastic properties of the material during processing would be of great practical use. However, most in-line instruments commercially available to date are only capable of measuring viscosity at a single shear rate. An in-line rheometer that measures both the viscous and elastic properties of fluids over a wide range of shear rates simultaneously has been described in a previous publication (Glasscock et at., 2003) in which the results of measurements on flowing sunflower oil were presented. Before this instrument can be used in an industrial situation, it must be demonstrated that the generated results are the same as, or bear some fixed relationship to, the results obtained by conventional off-line rheometers. To this end, the present investigation describes the measurements of a standard reference fluid, polyisobutylene dissolved in 2,6,10,14-tetramethylpentadecane, labelled SRM2490 by the National Institute of Standards and Technology (NIST) in the USA. The results obtained using the in-line rheometer show remarkably good correlation for viscosity, using a modified Cox­Merz rule, with the results supplied with the reference material from NIST.