• Title/Summary/Keyword: Viscose agent

Search Result 9, Processing Time 0.028 seconds

An Approach to the Influence of Particle Size Distribution of Leuco Vat Dye Converted by a Reducing Agent

  • Shim Woo-Sub;Lee Jung-Jin;Shamey Renzo
    • Fibers and Polymers
    • /
    • v.7 no.2
    • /
    • pp.164-168
    • /
    • 2006
  • Three vat dyes have been applied to regular viscose rayon and their dyeing and wash fastness properties were evaluated. Particle size determination was undertaken to obtain information about the size of dye particles converted by a reducing agent, to see if dye particle size has an affect on dyeing properties of regular viscose rayon. It is observed that viscose rayon exhibits more dyeability with reducing agent concentrations between 5-7.5 g/l. Also, we found that the vat dyeing system is greatly affected by the particle size of the vat dye converted to leuco form by a reducing agent.

The One Bath One Step Dyeing of Cationized Nylon/Viscose Rayon Mixture Fabrics With Acid Dyes and Reactive Dyes (산성염료와 반응성염료에 의한 카티온화 나일론/비스코스레이온 교직물의 1욕1단 염색)

  • Sung, Woo-Kyung
    • Fashion & Textile Research Journal
    • /
    • v.7 no.3
    • /
    • pp.339-345
    • /
    • 2005
  • It is difficult to dye nylon/viscose rayon mixture fabrics by one-bath one-step dyeing method, because acid dyes and reactive dyes require acidic dyebath for adsorption and alkaline dyebath for fixation respectively. In order to overcome the disadvantage of the conventional two bath two step dyeing method of nylon/viscose rayon mixture fabric, it was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. The pretreated nylon/viscose rayon mixture fabrics produced cationized fabrics that could be dyed with acid dyes and reactive dyes under neutral condition. This study was carried out to investigate dyeing possibilities, surface reflectance spectra and color characteristics of cationized nylon/viscose rayon mixture fabrics with acid dyes and reactive dyes in a non-electrolytic and neutral dyebath by one bath one step dyeing method.

Preparation of Eco-friendly and High Strength Paper for Viscose Rayon Yarn (친환경 고강도 인견사용 종이 제조)

  • Hwang, Sung-Jun;Kim, Hyoung-Jin;Bae, Paek-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.47 no.6
    • /
    • pp.154-163
    • /
    • 2015
  • Because of acute or chronic intoxication by carbon disulfide, viscose rayon industry is strictly subjected to environment regulatory approval. Recently, non-wood fibers are frequently considered as a raw materials for the manufacture of specialty paper for the higher physical strength and functionality. Among the non-wood fibers, hemp bast fiber is one of the most widely used materials in viscose rayon yarn industries. In this study, the handsheet for manufacturing the viscose rayon yarn was prepared with wood pulp fibers and hemp bast fibers. The proper mixing ratio of wood fibers and hemp bast fibers with dry-strength agent and nano-celluloses was analysed in terms of physical and mechanical strength of sheet for viscose rayon yarn. The papermaking conditions for high mechanical strength of sheet were obtained by mixing the SwBKP and HwBKP fibers with freeness level of 200 mL CSF. The dual polymer system by controlling the addition ratio of PVAm and anionic PAM was also important. The addition of nano-cellulose into wet-end furnishes increased the physical strength of sheet, and improved the paper structure for the production of viscose rayon yarn.

A Study on the High-Flowing Concrete with Low Unit Weight of Cement

  • Si Woo Lee;Hong Shik Choi;Sang Chel Kim;Gweon Heo
    • The Korean Journal of Ceramics
    • /
    • v.6 no.3
    • /
    • pp.318-321
    • /
    • 2000
  • Most compressive strengths commonly used in the construction field are in a range of 240 to 300 kgf/$\textrm{cm}^2$ at 28 days. To get this rage of strengths, however, high-flowing concrete requires cementitious binders more than 400 to 450 kg/$\textrm{cm}^2$ for preventing segregation and sedimentation of aggregates. This amount of cementitious binder generates a large emission of excessive hydration heat, which may consequently induce harmful cracks in concrete structure. In order to reduce excessive hydration heat, thus, this paper aims at fabricating a high-flowing concrete under the condition that cement content is kept as low as 350kg/$\textrm{cm}^3$ by using viscose agents. In a parametric study, effects of cement types such as a ternary blended cement and Type V on he physical characteristics of high-flowing concrete were evaluated. In addition, the influence of viscosity was also investigated by applying two different viscose agents, one in a range of 6,000 to 10,000 cps and the others of 10,000 to 14,000 cps. In terms of chemical admixtures used in concrete mixture, the superplasticizer was Sulfonated Melamine-Formaldehyde Condensate with about 30,000 of molecular weight, and main component of viscose agent was HPMC (Hydroxy Propyl Methyl Cellulose). Slump flow was fixed at 50cm with different dosages of superplasticizer in weight.

  • PDF

The mechanical and antimicrobial properties of chitosan crosslinked rayon fabric - Effect of chitosan and epichlorohydrin(ECH) concentration - (키토산 가교처리된 레이온 직물의 역학적특성과 항균성 - 에피클로로히드린과 키토산 농도의 영향 -)

  • Ahn, Jung-Mi;Kim, Min-Ji;Lee, Shin-Hee
    • Textile Coloration and Finishing
    • /
    • v.18 no.6 s.91
    • /
    • pp.16-24
    • /
    • 2006
  • The purpose of this study is to improve the defects of chitosan crosslinked viscose rayon by ECH and to describe the change of hand of chitosan crosslinked viscose rayon fabrics. The chitosan crosslinked viscose rayon were manufactured by crosslinking process using ECH as crosslinking agent, 2 wt% aqueous acetic acid as a solvent of chitosan and ECH, and 20 wt% aqueous sodium hydroxide as crosslinking catalyst. Viscose rayon were first immersed in the pad bath of the mixed solution of chitosan and ECH, padded up to 100 wt% wet pick-up on weight of fiber(owf), precured on pin frames at $130^{\circ}C$ for 2 minutes, immersed in NaOH solution and finally wash and dry. Antimicrobial properties of the viscose rayon treated with chitosan were measured by the shake flask C.T.M. 0923 test method with staphylococcus aureus(ATCC 6538) as the microorganism. When the concentration of chitosan was increased chitosan crosslinked viscose rayon's LT, WT, B, 2HB and MIU were increased and G, 2HG, SMD, T and $T_m$ were decreased. On the other hand, WT, EM were decreased and RT was increased at $1{\times}10^{-2}M$ ECH. The optimum condition for crosslinking was that ECH concentration was between $1{\times}10^{-2}M\;and\;5{\times}10^{-2}M$. Antimicrobial effects of rayon fabric treated with chitosan was excellent.

Dyeing and Fastness Properties of Vat Dyes on a Novel Regenerated Cellulosic Fiber

  • Lee Jung Jin;Shim Woo Sub;Kim Ik Soo;Kim Jae PH
    • Fibers and Polymers
    • /
    • v.6 no.3
    • /
    • pp.244-249
    • /
    • 2005
  • enVix is a novel regenerated cellulosic fiber, which is prepared from cellulose diacetate fiber using environmentally friendly manufacturing process. Vat dyeing properties of the enVix were investigated and compared with those ofregular viscose rayon. The enVix exhibited better dyeability than viscose rayon. The colour yields of vat dyes on the enVix were found to be dependent on dyeing temperature as well as the amount of levelling agent and salt. Good build-up and good to excellent fastness properties were obtained on the en Vix fabric.

Coloring Effect and Functionality of Rayon Based Cool Fabrics Treated by Various Mordant and Gallnut Extract (레이온계 여름용 직물에서 매염제 종류에 따른 오배자 염색의 색채발현 및 기능성에 관한 연구)

  • Hong, Kyung Hwa
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.41 no.2
    • /
    • pp.296-305
    • /
    • 2017
  • Gallnuts are known to exert various pharmaceutical properties that include anti-inflammatory, antimicrobial, antioxidant, and detoxifying effects. Gallnut extract is thought to be a particularly safe antimicrobial agent for textile application due to its natural origins. Hence, textiles were dyed with gallnut to develop multi-functional clothing material with no harmful effects. In this study, three kinds of cool touch woven fabrics, each comprised of 100% viscose rayon filament, viscose rayon filament/high absorption & quick dry (polyester) filament, and viscose rayon $filament/tencel^{(R)}$ spun yarn, were prepared and used as substrates for gallnut dyeing to especially develop functional cool touch textiles for summer clothing material. On the other hand, gallnut dyeing was conducted with mordanting with iron, lime or alum, which induced different colors on the dyed textiles. Dyed textiles were then investigated by SEM, FTIR, antibacterial test, and antioxidant test. Subsequently, gallnut dyed textiles indicated excellent antibacterial ability and deodorization activity regardless of mordant species. However, only gallnut dyed textiles mordanted with iron and alum showed significant antioxidant ability. In addition, the dyeing processes impair the cool touch feeling of the textiles by changing the micro structure of the textile surface.

Surface and Adsorption Properties of Activated Carbon Fabric Prepared from Cellulosic Polymer: Mixed Activation Method

  • Bhati, Surendra;Mahur, J.S.;Dixit, Savita;Choubey, O.N.
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.2
    • /
    • pp.569-573
    • /
    • 2013
  • In this study, activated carbon fabric was prepared from a cellulose-based polymer (viscose rayon) via a combination of physical and chemical activation (mixed activation) processes by means of $CO_2$ as a gasifying agent and surface and adsorption properties were evaluated. Experiments were performed to investigate the consequence of activation temperature (750, 800, 850 and $925^{\circ}C$), activation time (15, 30, 45 and 60 minutes) and $CO_2$ flow rate (100, 200, 300 and 400 mL/min) on the surface and adsorption properties of ACF. The nitrogen adsorption isotherm at 77 K was measured and used for the determination of surface area, total pore volume, micropore volume, mesopore volume and pore size distribution using BET, t-plot, DR, BJH and DFT methods, respectively. It was observed that BET surface area and TPV increase with rising activation temperature and time due to the formation of new pores and the alteration of micropores into mesopores. It was also found that activation temperature dominantly affects the surface properties of ACF. The adsorption of iodine and $CCl_4$ onto ACF was investigated and both were found to correlate with surface area.

A study on the Development of Antimicrobial Finished and Water Repellent Nonwoven Fabrics using Organic Silicon Quaternary Ammonium Salt (항균성 및 발수성 부직포 소재의 개발에 관한 연구 - 유기실리콘 제 4 차 암모늄염의 이용 -)

  • Cho Gil Soo;Cho Jeong Sook;Sohn Mi Young
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.14 no.3 s.35
    • /
    • pp.216-221
    • /
    • 1990
  • This study was performed for the development of antimicrobial finished nonwoven fabrics with water repellency. And it was aimed to examine the changes of moisture related properties and air permeability of the finished fabrics. Viscose rayon nonwoven fabrics were treated with organic silicon quaternary ammonium salt having carbon numbers of 16, which was synthesized for this study Antimicrobial activity was evaluated by shake flask method and the reactivity of antimicrobial agent was measured by degree of luminescence from inductively coupled plasma. Water repellency of treated specimen was evaluated by dynamic water absorption measurement and air permeability was measured by Frazier method. The results obtained from this study were as follows: 1. Excellent antimicrobial activity was obtained for the high concentration of treatment and the durability of finishing after laundering was better as the treatment concentration was higher 2. Silicon contents taken up by specimen increased with increased treatment concentration. 3. Dynamic water absortion of treated specimen decreased compared to that of untreated. And, it was lowered as the treatment of concentration increased and as the silicon content increased. 4. Moistuie regain and uptake with lapse of time of treated specimen increased compared to those of untreated. But, air permeability of treated specimen decreased.

  • PDF