• Carbon letters
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• v.10 no.2
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• pp.101-108
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

• Carbon letters
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• v.10 no.2
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• pp.109-113
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB). The vulcanization characteristics, the processability, and the mechanical properties are measured. In soft clay/CB filled CIIR system, there are no significant changes in Mooney viscosity among compounds. Vinyl silane added compound shows a low extrusion torque. All the silane added compounds shows an increased modulus. The mechanical properties are significantly increased when the S2 is added into CIIR/soft clay/CB compounds.

• Carbon letters
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• v.10 no.3
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• pp.190-197
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• 2009

Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

• Journal of the Korea Safety Management & Science
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• v.6 no.1
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• pp.301-309
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• 2004

An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

• Macromolecular Research
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• v.11 no.3
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• pp.202-205
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• 2003

The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.79-83
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• 2005

• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.421-428
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• 1998

The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

• Elastomers and Composites
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• v.38 no.3
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• pp.227-234
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• 2003

Silicone composites for high voltage insulator (HVI SC) were prepared by adding aluminum trihydrate(ATH) treated by surface treatment agent to base silicone compound at the ratio oi 100:20, 100:40, 100:60, 100:80, and 100:100, respectively And also, ATH was treated by various surface treatment agents, such as stearic arid, acryl silane, and vinyl silane under compounding process. Mechanical properties and electrical properties were investigated for the various contents of ATH and surface-treatment agents. Mechanical properties such as tensile strength, elongation, and tear strength decreased as the load of ATH increased. Volume resistivity, AC break down strength, and tracking resistance for HVI SC containing ATH treated by vinyl silane were better than those for HVI SC containing ATH treated by other surface treatment agents, such as stearic acid and acryl silane. Polymer-filler interaction of silicone composites according to surface treatment agents was studied by measuring bound rubber contend(BR). From the experimental results, BR of silicone composite containing ATH treated with vinyl silane was higher than that of the others. The degree of rule for silicone composite was investigated using Rheometer. Maximum torque of silicone composites contaning ATH treated with vinyl silane was higher than that of silicone composite contaning ATH treated with other surface agents.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.206-209
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• 2002

The purpose of this research was to find influence of compounding materials on electrical properties of silicone rubber such as tracking characteristic. The tracking characteristic was tested through controlling the ATH, a widely use anti-tracking agent. Regarding the particle size and coupling agent of ATH, compound silicone rubber with ATH of coupling agent and larger diameter showed better anti-tracking properties. It can be included that ATH of coupling agent use vinyl silane, dispose of tracking characteristic was achieve excellant results.

• Korean Journal of Materials Research
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• v.30 no.6
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• pp.273-278
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• 2020

This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.