• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.465-469
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• 2013

Proton transfer reaction is one of the most fundamental processes in chemistry and life science. Excited state intramolecular proton transfer (ESIPT) has been studied as a model system of the proton transfer, since it can be conveniently initiated by light. We report ESIPT reaction dynamic of 1-hydroxy-anthraquione (1-HAQ) in solution by highly time-resolved fluorescence. ESIPT time of 1-HAQ is determined to be $45{\pm}10$ fs directly from decay of the reactant fluorescence and rise of the product fluorescence. High time resolution allows observation of the coherent vibrational wave packet motion in the excited state of the reaction product tautomer. The coherently excited vibrational mode involves large displacement of the atoms, which shortens the distance between the proton donor and the acceptor. With the theoretical analysis, we propose that the ESIPT of 1-HAQ proceeds barrierlessly with assistance of the skeletal vibration, which in turn becomes excited coherently by the ESIPT reaction.

• 한국자동차공학회논문집
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• 제2권1호
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• pp.116-127
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• 1994

A method using the linear matrix algebra is developed in order to determine unknown external forces in linear structural analyses. The method defines a matrix which represents the linearity of the vibrational analysis for a structural system. The unknown external forces are determined by the operations of the matrix. The method is applied to find an engine motion in an automobile system. For a simulation process, an exhaust system is modeled and analyzed by the finite element method. The validity of the simulation is verified by comparing with the experimental results the free vibration. Also, an experiment on the forced vibration is performed to determine the damping ratio of the exhaust sysetm. Estimated model parameters(natural frequency, mode shape) are in accord with the experimental results. Because the method merely repeats the transpose and inverse operations of a matrix, the solution is extremely easy and simple. Moreover, it is more accurate than the existing methods in that there is no artificial assumptions in the calculation processes. Therefore, the method is found to be reliable for the analysis of the exhaust system considering the characteristics of vibrations. Although the suggested method is tested by only the exhaust system here, it can be applied to general structures.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1999년도 추계학술발표회 초록집
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• pp.15-15
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• 1999

In chip plating, several parameters must be taken into consideration. Current density, solution concentration, pH, solution temperature, components volume, chip and media ratio, barrel geometrical shape were most likely found to have an effect to the process yields. The 3 types of barrels utilized in chip plating industry are the conventional rotating barrel. vibrational barrel (vibarrel), and the centrifugal type. Conventional rotating barrel is a close type and is commonly used. The components inside the barrel are circulated by the barrel's rotation at a horizontal axis. Process yield has known to have higher thickness deviation. The vibrational barrel is an open type which offers a wide exposure to electrolyte resulting to a stable thickness deviation. It rotates in a vertical axis coupled with multi-vibration action to facilitate mixed up and easy transportation of components, The centrifugal barrel has its plated work centrifugally compacted against the cathode ring for superior electrical contact with simultaneous rotary motion. This experiment has determined the effect of barrel vibration intensity to the plating thickness distribution. The procedures carried out in the experiment involved the overall plating process., cleaning, rinse, Nickel plating, Tin-Lead plating. Plating time was adjusted to meet the required specification. All other parameters were maintained constant. Two trials were performed to confirm the consistency of the result. The thickness data of the experiment conducted showed that the average mean value obtained from higher vibrational intensity is nearer to the standard mean. The distribution curve shown has a narrower specification limits and it has a reduced variation around the target value, Generally, intensity control in vi-barrel facilitates mixed up and easy transportation of components, However, it is desirable to maintain an optimum vibration intensity to prevent solution intrusion into the chips' internal electrode. A cathodic reaction can occur in the interface of the external and internal electrode. $2HD{\;}+{\;}e{\;}{\rightarrow}20H{\;}+{\;}H_2$ Hydrogen can penetrate into the body and create pressure which can cause cracks. At high intensity, the chip's motion becomes stronger, its contact between each other is delayed and so plating action is being controlled. However, the strong impact created by its collision can damage the external electrode's structure thereby resulting to bad plating condition. 1 lot of chip was divided into two equal partion. Each portion was loaded to the same barrel one after the other. Nickel plating and tin-lead plating was performed in the same station. Portion A maintained the normal barrel vibration intensity and portion B vibration intensity was increased two steps higher. All other parameters, current, solution condition were maintained constant. Generally, plating method find procedures were carried out in a best way to maintained the best plating condition. After plating, samples were taken out from each portion. molded and polished. Plating thickness was investigated for both. To check consistency of results. 2nd trial was done now using different lot of another characteristics.

• Steel and Composite Structures
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• 재36권6호
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• pp.689-702
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• 2020

The current study deals with the size-dependent free vibration analysis of graphene nanoplatelets (GNPs) reinforced polymer nanocomposite plates resting on Pasternak elastic foundation containing different boundary conditions. Based on a four variable refined shear deformation plate theory, which considers shear deformation effect, in conjunction with the Eringen nonlocal elasticity theory, which contains size-dependency inside nanostructures, the equations of motion are established through Hamilton's principle. Moreover, the effective material properties are estimated via the Halpin-Tsai model as well as the rule of mixture. Galerkin's mathematical formulation is utilized to solve the equations of motion for the vibrational problem with different boundary conditions. Parametrical examples demonstrate the influences of nonlocal parameter, total number of layers, weight fraction and geometry of GNPs, elastic foundation parameter, and boundary conditions on the frequency characteristic of the GNPs reinforced nanoplates in detail.

• Smart Structures and Systems
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• 제18권2호
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• pp.335-354
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• 2016

This contribution presents an extended one-dimensional theory for piezoelectric beam-type structures with non-ideal electrodes. For these types of electrodes the equipotential area condition is not satisfied. The main motivation of our research is originated from passive vibration control: when an elastic structure is covered by several piezoelectric patches that are linked via resistances and inductances, vibrational energy is efficiently dissipated if the electric network is properly designed. Assuming infinitely small piezoelectric patches that are connected by an infinite number of electrical, in particular resistive and inductive elements, one obtains the Telegrapher's equation for the voltage across the piezoelectric transducer. Embedding this outcome into the framework of Bernoulli-Euler, the final equations are coupled to the wave equations for the longitudinal motion of a bar and to the partial differential equations for the lateral motion of the beam. We present results for the wave propagation of a longitudinal bar for several types of electrode properties. The frequency spectra are computed (phase angle, wave number, wave speed), which point out the effect of resistive and inductive electrodes on wave characteristics. Our results show that electrical damping due to the resistivity of the electrodes is different from internal (=strain velocity dependent) or external (=velocity dependent) mechanical damping. Finally, results are presented, when the structure is excited by a harmonic single force, yielding that resistive-inductive electrodes are suitable candidates for passive vibration control that might be of great interest for practical applications in the future.

• 한국소음진동공학회논문집
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• 제20권5호
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• pp.492-501
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• 2010

Equations of motion of thin-walled composite H-type cross-section beams incorporating a number of nonclassical effects of transverse shear and primary and secondary warping, and anisotropy of constituent materials are derived. The vibrational characteristics of a composite thin-walled beam exhibiting the circumferentially asymmetric stiffness system(CAS) and the circumferentially uniform stiffness system(CUS) are exploited in connection with the bending-transverse shear coupling and the bending-twist coupling resulting from directional properties of fiber reinforced composite materials.

• Journal of Mechanical Science and Technology
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• 제14권9호
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• pp.968-977
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• 2000

The motion of an aircraft landing gear over a rough runway can be modeled by a nonclassically damped system subject to nonstationary random excitations. In this paper, the approximate analysis methods based on either the real or complex normal modes for the computation of nonstationary response covariances are proposed. It has been found by simulation involving a realistic example that, for the nonclassically damped random vibrational systems, the approximate solution method based on the complex normal mode is superior to other approaches with respect to the accuracy and computation time.

• 제어로봇시스템학회논문지
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• 제6권8호
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• pp.703-709
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• 2000

This paper proposes a compliance control strategy for the robot manipulators accidentally interact-ing with an unknown environment. In this proposed method each in the diagonal stiffness matrix corre-sponding to the task coordinate in a Cartesian space is adaptively adjusted during contact along the corresponding axis based on the contact force with its environment. This method can be used for both unconstrained and constrained motions without any switching mechanism which often causes undesirable instability and/or vibrational motion of the end-effector. The experimental results show the effectiveness of the proposed method by employing a two link direct drive manipulator interacting with an unknown environment.

• Steel and Composite Structures
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• 제26권4호
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• pp.421-437
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• 2018

Free vibration analysis of a three-layered microbeam including an elastic micro-core and two piezo-magnetic face-sheets resting on Pasternak's foundation are studied in this paper. Strain gradient theory is used for size-dependent modeling of microbeam. In addition, three-unknown shear and normal deformations theory is employed for description of displacement field. Hamilton's principle is used for derivation of the governing equations of motion in electro-magneto-mechanical loads. Three micro-length-scale parameters based on strain gradient theory are employed for prediction of vibrational characteristics of structure in micro-scale. The results show that increase of three micro-length-scale parameters leads to significant increase of three natural frequencies especially for increase of second micro-length-scale parameter. This result is according to this fact that stiffness of a micro-scale structure is increased with increase of micro-length-scale parameters.

• Steel and Composite Structures
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• 제22권2호
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• pp.277-299
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• 2016

In this paper, free vibration, forced vibration, resonance and stress wave propagation behavior in nanocomposite plates reinforced by wavy carbon nanotube (CNT) are studied by a mesh-free method based on first order shear deformation theory (FSDT). The plates are resting on Winkler-Pasternak elastic foundation and subjected to periodic or impact loading. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness and their mechanical properties are estimated by an extended rule of mixture. In the mesh-free analysis, moving least squares (MLS) shape functions are used for approximation of displacement field in the weak form of motion equation and the transformation method is used for imposition of essential boundary conditions. Effects of CNT distribution, volume fraction, aspect ratio and waviness, and also effects of elastic foundation coefficients, plate thickness and time depended loading are examined on the vibrational and stresses wave propagation responses of the nanocomposite plates reinforced by wavy CNT.