• 대한기계학회논문집 C: 기술과 교육
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• 제3권4호
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• pp.299-305
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• 2015

미래에너지의 해법으로 원자력에너지를 이용한 물분해 수소생산시스템의 핵심기술을 개발하였다. 안전성을 보장할 수 있는 제4세대 원자로인 초고온가스로의 고열을 이용하여 황요오드 열화학적인 방법으로 물을 분해하여 수소를 생산하는 기술이다. 원자력수소생산 핵심기술은 초고온에서의 열을 공급하는 것을 모사하는 초고온 실험기술, 초고온가스로의 안전성을 모사하는 연구, 초고온가스로의 노심과 안전성을 해석할 수 있는 도구의 개발, 초고온가스로에 사용하는 연료제조기술, 물을 분해하여 열화학적인 방법으로 수소를 생산하는 기술로 구성된다. 원자력수소생산에 필요한 핵심기술을 개발하고 실험실 규모로 입증하였으며, 대규모 실용화를 위해서 선결되어할 미완성 기술을 제시하였다. 본 기술은 제4세대 원자로개발 국제공동연구로 수행한 기술로서 향후 미래의 원자로 기술이다.

• 한국세라믹학회지
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• 제50권6호
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• pp.446-450
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• 2013

TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{\circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.

• Nuclear Engineering and Technology
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• 제41권6호
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• pp.831-840
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• 2009

In order to evaluate the start-up behavior and to identify, through abnormal operation occurrences, the transient behaviors of the Sulfur Iodine(SI) process, which is a nuclear hydrogen process that is coupled to a Very High Temperature Gas Cooled Reactor (VHTR) through an Intermediate Heat Exchanger (IHX), a dynamic simulation of the process is necessary. Perturbation of the flow rate or temperature in the inlet streams may result in various transient states. An understanding of the dynamic behavior due to these factors is able to support the conceptual design of the secondary helium loop system associated with a hydrogen production plant. Based on the mass and energy balance sheets of an electrodialysis-embedded SI process equivalent to a 200 $MW_{th}$ VHTR and a considerable thermal pathway between the SI process and the VHTR system, a dynamic simulation of the SI process was carried out for a sulfuric acid decomposition process (Second Section) that is composed of a sulfuric acid vaporizer, a sulfuric acid decomposer, and a sulfur trioxide decomposer. The dynamic behaviors of these integrated reactors according to several anticipated scenarios are evaluated and the dominant and mild factors are observed. As for the results of the simulation, all the reactors in the sulfuric acid decomposition process approach a steady state at the same time. Temperature control of the inlet helium is strictly required rather than the flow rate control of the inlet helium to keep the steady state condition in the Second Section. On the other hand, it was revealed that the changes of the inlet helium operation conditions make a great impact on the performances of $SO_3$ and $H_2SO_4$ decomposers, but no effect on the performance of the $H_2SO_4$ vaporizer.

• 한국세라믹학회지
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• 제48권5호
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• pp.426-432
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• 2011

The oxidation behavior of CVD ${\beta}$-SiC was investigated for Very High Temperature Gas-Cooled Reactor (VHTR) applications. This study focused on the surface analysis of the oxidized CVD ${\beta}$-SiC to observe the effect of impurity gases on active/passive oxidation. Oxidation test was carried out at $950^{\circ}C$ in the impurity-controlled helium environment that contained $H_2$, $H_2O$, CO, and $CH_4$ in order to simulate VHTR coolant chemistry. For 250 h of exposure to the helium, weight changes were barely measurable when $H_2O$ in the bulk gas was carefully controlled between 0.02 and 0.1 Pa. Surface morphology also did not change based on AFM observation. However, XPS analysis results indicated that a very small amount of $SiO_2$ was formed by the reaction of SiC with $H_2O$ at the initial stage of oxidation when $H_2O$ partial pressure in the CVD ${\beta}$-SiC surface placed on the passive oxidation region. As the oxidation progressed, $H_2O$ consumed and its partial pressure in the surface decreased to the active/passive oxidation transition region. At the steady state, more oxidation did not observable up to 250 h of exposure.

• Corrosion Science and Technology
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• 제6권2호
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• pp.37-43
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• 2007

Iodine sulfur (IS) process is one of the promising processes for a hydrogen production by using a high temperature heat generated by a very high temperature gas cooled reactor(VHTR) in the nuclear power industries. Even though the IS process is very efficient for a hydrogen production and it is not accompanied by a carbon dioxide evolution, the highly corrosive environment of the process limits its application in the industry. Corrosion tests of selected materials were performed in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Fe-Cr alloys, Fe-Ni-Cr alloys, Fe-Si alloys, Ni base alloys, Ta, Ti, Zr, SiC, Fe-Si, etc. The test environments were 50 wt% sulfuric acid at $120^{\circ}C$ and 98 wt% at $320^{\circ}C$. Corrosion rates were measured by using a weight change after an immersion. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. Corrosion behaviors of the materials were discussed in terms of the chemical composition of the materials, a weight loss, the corrosion morphology, the precipitates in the microstructure and the surface layer composition.

• 한국세라믹학회지
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• 제50권1호
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• pp.37-42
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• 2013

Tristructural-isotropic (TRISO)-coated particles were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for use in a very high temperature gas-cooled reactor (VHTR). ZrC as a constituent layer of TRISO coating layers was deposited by a chloride process using $ZrCl_4$ and $CH_4$ source gases in a temperature range of $1400^{\circ}C$ and $1550^{\circ}C$. The change in the microstructure of ZrC depending on the deposition temperature and its effect on the hardness were evaluated. As the deposition temperature increased to $1500^{\circ}C$, the grain size of the ZrC increased and the hardness of the ZrC decreased according to the Hall-Petch relationship. However, at $1550^{\circ}C$, the ZrC layer was highly non-stoichiometric and carbon-rich and did not obey the Hall-Petch relationship in spite of the decrease of the grain size. A considerable amount of pyrolytic carbon at the grain boundaries of the ZrC as well as coarse granular pyrolytic carbon were locally distributed in the ZrC layer deposited at $1550^{\circ}C$. Therefore, the hardness decreased largely due to the formation of a large amount of pyrolytic carbon in the ZrC layer.