• 한국연소학회:학술대회논문집
• /
• 2006.04a
• /
• pp.105-110
• /
• 2006

Many previous works have been performed to provide correlations of flame length, theoretically and experimentally. Most of these results studied were conducted in vertical turbulent flame with no coaxial air condition. The present study analyzes the flame length scaling with coaxial air. In turbulent hydrogen non-premixed jet flames with coaxial air, flame length scaling theoretically proposed so far has been related with the concept of a far-field equivalent source. At high coaxial air to fuel velocity ratio, $U_A/U_F$, however, this scaling theory has some difference with experimental flame length data. This difference is understood to be due to the fact that the theory is based on far-field notion, while the effect of coaxial air on jet flame occurs in the region near the nozzle exit. Therefore, we define effective jet density $P_{eff}$ involving the concept of near-field so that effective jet diameter can be extended to the near-field region. In this condition, we modify the correlation and compare with experimental data.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2012.05a
• /
• pp.318-323
• /
• 2012

This study is conducted to scrutinize agitation effects of an ultrasonic standing wave on the dynamic behavior of methane/air premixed flame. The propagating flame is caught by high-speed schlieren images, through which flame front and local flame velocity are analyzed and obtained, too. It is revealed that the propagation velocity with ultrasonic standing wave is larger than the case without excitation except around the flammability limits. Also, vertical locations of distortions and depth of dents of the front are constant, unless the ultrasonic standing wave characteristics are not changed.

• Textile Coloration and Finishing
• /
• v.33 no.4
• /
• pp.238-249
• /
• 2021

In this study, the effect on flame retardancy and various physical properties when TiO₂ was added with a citric acid/phosphate complex acid catalyst together with Pyrovatex CP new (N-methylol dimethylphosphonopropionamide), a phosphorus-based flame retardant, was studied on cotton fibers. SEM-EDS analysis was performed to confirm the surface characteristics and surface element analysis of the flame-retardant treated cotton fibers, and a vertical carbonization test was performed to confirm the char formation capability and flame retardancy according to the phosphoric acid ratio. By comparing the LOI index before and after washing 10 times, the washing durability of the flame retardant solution containing the phosphoric acid catalyst and TiO₂ was tested by LOI index after ten washing cycles. In addition, the influence of the flame-retardant processing on the physical properties were compared including thermogravimetric analysis (TGA), tear strength and whiteness.

• Clean Technology
• /
• v.23 no.4
• /
• pp.378-387
• /
• 2017

To obtain epoxy resin with permanently attached flame-retardant groups, phosphorus compound containing di-hydroxyl group [10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ] and silicone compound containing di-hydroxyl group (polydimethylsiloxane, hydroxyl terminated, PDMS) were reacted with uncured epoxy prepolymer (diglycidyl ether of bisphenol A, DGEBA) and then cured using 4,4-diaminodiphenylmethane (DDM) as a crosslinking agent. The properties of the resulting epoxy materials were characterized using Fourier transform infrared (FTIR) spectrometer, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test/vertical burning test (UL 94-V test), tensile properties test and impact test. This study examined the effect of phosphorus/silicone compound contents on the thermal/mechanical properties and flame retardancy of cured epoxy resins containing phosphorus and silicone compounds. It was found that the thermal/mechanical properties of epoxy resins containing phosphorus and silicone components were higher than those of simple epoxy resin. The flame-retardancy (LOI: 29.9 ~ 31.8% and UL 94-V: V-0) of all samples containing phosphorus compound and phosphrous compound/silicone compound was found to be passed the flame-retardant requirements (LOI: > 30%, UL 94-V: V-0) of LOI and vertical burning tests. However, the flame-retardancy (LOI: 21.4% and UL 94-V: no rating) of simple epoxy resin was found to be failed the flame-retardant requirements.

• Composites Research
• /
• v.35 no.6
• /
• pp.456-462
• /
• 2022

Since natural fibers are highly flammable, it is not easy to make them flame retardant. In this study, a liquid flame retardant based on phytic acid, APTES, and Thiourea, which are flame retardant candidates derived from nature, was prepared and its performance was verified through flame retardant treatment and flame retardancy evaluation of bamboo fibers. When a liquid flame retardant is used, it is possible to treat a large amount of natural fibers with flame retardant treatment. Nine types of flame-retardant treated bamboo fibers were prepared according to the Taguchi design of experiment method. Thereafter, vertical burning test and microcalorimeter test were performed for flame retardancy evaluation, and the surface of natural fibers before and after flame-retardant treatment was compared using scanning electron microscope. The results show that phytic acid has a significant effect on improving the flame retardancy of natural fibers. Through microstructure analysis, it was assumed that the phytic acid helps flame retardant to uniformly adhere to the surface of natural fibers. If such research results are utilized, it is possible to make a large amount of natural fibers high flammability in an eco-friendly way, which is expected to be advantageous for the application of prototypes.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2013.05a
• /
• pp.315-317
• /
• 2013

To analyze vertical fire spreadability of aluminum composite panel, real scale test of aluminum composite panel and fire retardant aluminum composite panel was conducted as well as analysis of domestic code, test and domestic reaserch resulted in following conclusion. Fire spread risk assessment of aluminum Composite Panel is impossible with the current regulations (Cone Calorimeter Test). It need to changes of regulatory and combustion expanded risk assessment and regulatory changes in the test methods need to be judged. Also, there is quite a big different between the general aluminum Composite Panel and semi-non combustible of aluminum Composite Panel. However it is also deemed to be danger when present in the sidewall to the top consisting of fire spread. From now on, it is needed the study about interpretation of fire spread and sidewall of vertical fire spread analysis not only experiments for aluminum Composite Panel.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.15 no.6
• /
• pp.1-6
• /
• 2011

An experimental study has been conducted to scrutinize into the influence of ultrasonic standing wave field on the variation of methane/air premixed flame structure. Visualization technique utilizing the Schlieren method is employed for the observation of premixed flame propagation. The shape of flame front and local flame velocity are measured according to the variation of reactants pressure and chamber opening/closing condition. The flame fronts affected by the standing wave are clearly distorted but the vertical locations of frontal dents do not undergo any appreciable change. The influence of standing wave on the flame front becomes more prominent as the flame propagates downward. It is found that the propagation velocity of flame front with excitation of standing wave is greater than the case without the excitation. It is eventually revealed that the flame is deformed to lotus-shaped one by the vivid interaction of ultrasonic standing-wave with the reflected wave coming from the right side.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.16 no.3
• /
• pp.16-23
• /
• 2012

This study has been conducted to scrutinize agitation effects of an ultrasonic standing wave on the dynamic behavior of methane/air premixed flame. The propagating flame was caught by high-speed Schlieren images, through which local flame velocities of the moving front were analyzed in unprecedent detail. It is revealed that the propagation velocity agitated by the ultrasonic standing wave is greater than that without agitation at the stoichiometric ratio: the velocity enhancement diminishes as the equivalence ratio approaches upper flammability limit or lower flammability limit. Also, vertical locations of the wave-affected frontal distortions do not vary appreciably, unless the propagating-mode characteristics (pressure amplitude and driving frequency) of ultrasonic standing wave were not changed.

• Journal of the Korean Society of Combustion
• /
• v.4 no.2
• /
• pp.23-33
• /
• 1999

A turbulent non-premixed ethylene flame, which was set up in a vertical wind tunnel, was examined to understand the effect of turbulent mixing on formations of soot and gaseous species in the flames. Temperature and velocity profiles were measured using uncoated thermocouples and LDV system. Gaseous samples were withdrawn by using a water cooled stainless iso-kinetic gas sampling probe. The samples for inorganic compounds and light hydrocarbons were collected with sampling bottles and were analyzed by a gas chromatography. The samples for aromatic hydrocarbons were collected on a sorbent tube and were analyzed on a GC/MS system. Some of main results were followed. CO and $CO_2$ were measured relatively in early part of flame and the concentration of CO was greater than that of $CO_2$ all over the early flame region due to the scavenging of the oxidizing species OH by soot particles. Aromatic hydrocarbons were measured at x/D=122 along the radial direction and main important species were benzene, xylene, toluene, styrene, indene, naphthalene. The peak points of these compounds occurred at r/D=0.8 apart from the center of flame, around in which the concentration of $C_2H_2$ decayed relatively rapidly from the maximum value.

• Journal of the Korean Applied Science and Technology
• /
• v.17 no.4
• /
• pp.240-247
• /
• 2000

Two-component polyurethane flame-retardant coatings were prepared by blending trichloro aromatic modified polyesters(TCMPs) and polyisocyanate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid(TCBA), a flame-retardant component, with adipic acid, 1,4-butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. These new flame-retardant coatings showed various properties comparable to other non-flame-retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame-retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as 'no burn'. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index(LOI) values of 25% and 28% respectively, which implied relatively good flame retardancy.