• Title/Summary/Keyword: Various reducing conditions

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Dyeing Properties of Cotton Fabrics Dyed with Extract from Dry Leaf of Indigo Plant (건조 쪽잎 추출액에 의한 면직물 염색성)

  • Song, Sung-Won;Cho, Kyung-Rae
    • Textile Coloration and Finishing
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    • v.20 no.3
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    • pp.18-24
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    • 2008
  • The purpose of this study is to develop the dyeing method with dry leaves of indigo plant. Coloring matter was extracted from dry leaves of indigo plant with hot sodium hydroxide solution. The extract was reduced with sodium dithionite, and it was used for dyeing cotton fabrics under various conditions. UV-visible absorption spectra of extract, reduction rate of extracts by reducing agent, and the surface color of dyed cotton, lightfastness were examined. For the initial 20 minutes, the absorbance of indigo solution rapidly decreased. However, several hours later, the decreasing rate retarded. By repeating the dyeing process, the shade looked deeper and deeper. At $30-40^{\circ}C$, the value of K/S reached the highest point. The concentration of indigo solution in dye bath seemed to playa critical role for the reaction of the reducing agent. It was observed that the surface color of cotton fabrics was getting bluish and its degree of value and chroma seemed slightly decreased as the K/S value was increasing. The lightfastness was clearly enhanced by increasing the K/S value.

The effect of various surface coatings on microleakage and microhardness of light-cured glass ionomer restoration (수종 표면 보호재의 도포가 광중합형 유리 아이오너머 수복물의 변연 누출 및 미세 경도에 미치는 영향)

  • Kim, Gi-Seob;Kim, Yong-Kee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.3
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    • pp.495-510
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    • 1997
  • The purpose of this study was to evaluate the efficacy of several surface coating agents in preventing microleakage and increasing microhardness of light-cured glass ionomer restoration. 50 and 25 sound molar teeth were used for the microleakage test and microhardness test respectively. Data were analyzed statistically using Kruskal-Wallis and/or Mann-Whitney test. The results of the present study were as follows: 1. The effect of surface coating in reducing microleakage was proven only at the gingival margin of restorations with statistical significance(p<.05). 2. The distribution of microleakage score at gingival margin was shown to be better than that of occlusal margin in general but with no statistically significant differences(p>.05). 3. No statistically significant differences in microhardness could be found between groups (p>.05) regardless of depth of measurement. 4. Under the present experimental conditions, the types or application of surface coating agents did not impose any significant effect on microhardness of glass ionomer restorative material whereas the protective effect of surface coating in reducing microleakage was partly proven.

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Investigation of Gold and Silver Nanoparticles as Acid-base pH Indicators and Their Transition pH Ranges

  • Jung, Byoung Gue;Jo, Jihee;Yu, Jin Won;Lim, Jong Kuk
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3595-3600
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    • 2014
  • Monitoring of pH, especially under highly alkaline conditions, is necessary in various processes in the industrial, biotechnological, agricultural, and environmental fields. However, few pH indicators that can function at highly alkaline levels are available, and most of which are organic-based pH indicators. Several years ago, it was reported that gold nanoparticles prepared using trisodium citrate dihydrate were rapidly aggregated at pH values higher than ~12.7. A shift of surface plasmon resonance for such aggregated gold nanoparticles can be applied to pH indicators, allowing for the substitution of traditional organic-based pH indicators. The most important characteristic of pH indicators is the transition pH range. Herein, gold and silver nanoparticles are prepared using different reducing agents, and their transition pH ranges are examined. The results showed that all nanoparticles prepared in this study exhibit similar transition pH ranges spanning 11.9-13.0, regardless of the nanoparticle material, reducing agents, and concentration.

Effect of Addition of Mushroom and Sea Tangle Extracts and Mustard Leaf on Anti-oxidant Properties of Kimchi (버섯 및 다시마 추출물과 갓의 첨가가 김치의 항산화 특성에 미치는 영향)

  • Ha, Seon-Hye;Kang, Soon Ah
    • The Korean Journal of Food And Nutrition
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    • v.31 no.4
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    • pp.471-477
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    • 2018
  • The antioxidant properties of mushroom and sea tangle extracts and mustard leaf added to Kimchi were investigated by total phenolic content, DPPH radical scavenging, ABTS anion scavenging, FRAP reducing power, and ORAC value. Total phenolic content of functional Kimchi (FK) was significantly higher than that of control Kimchi (CK). DPPH radical and ABTS anion scavenging activities of functional Kimchi were significantly higher than those of control Kimchi by 2.7 and 1.7 fold, respectively (p<0.05). Also, the FRAP reducing power and ORAC value of functional Kimchi increased compared to those of the control Kimchi by 1.6 and 1.1 fold, respectively (p<0.05). Our results suggest that functional Kimchi made by mushroom and sea tangle extracts and mustard leaf may be a potent antioxidant source and could be developed as a antioxidant functional food that may be for the effective treatment of oxidant conditions. Through continuous research and development of functional Kimchi by the use of mushroom and sea tangle extracts, it will be necessary to try to identify other functions that could be useful for preventing various diseases.

Unsteady Intermittent Spray Characteristics of PEI Gasoline Injector (PEI용 가솔린 인젝터의 비정상 간헐 분무 특성)

  • Kim Beomjun;Lee Jaiho;Cho Daejin;Yoon Suckju
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.5
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    • pp.64-74
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    • 2005
  • The effect of fuel injection spray on engine performance has been known as one of the major concerns for improving fuel economy and reducing emissions. In general, reducing the spray droplet size could prevent HC emission in gasoline engine. As far as PFI gasoline engine is concerned, the mixture of air and fuel may not be uniform under a certain condition, because breakup and production of spray droplets are made in a short distance between the fuel injector and intake valve. This study, by constituting PFI gasoline spray system, was performed to study the transient spray characteristics and dynamic behavior of droplets from two-holes two-sprays type injector used in DOHC gasoline engine. Mean droplet size and optical concentration in accordance with various conditions were measured by LDPA and CCD camera. Through this study, the variation of drop size and optical concentration could be used for understanding the behavior of unsteady spray was declared and the existing the small droplets between each pulse spray could be estimated caused to the development of wall film was conformed.

Polyphenol Contents of Rumex crispus Root Extract with Hot Water and its Antioxidative Effect (소리쟁이 뿌리 열수 추출물의 폴리페놀 함량 및 추출물의 항산화 효과)

  • Yun, Young-Sim;Jeong, Kap-Seop
    • Journal of Environmental Science International
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    • v.21 no.10
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    • pp.1265-1274
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    • 2012
  • This study was conducted to investigate the extraction characteristics including total polyphenol compound content (TPC) and the antioxidative effect of Rumex crispus root extract on commercial corn oil. Extraction yield was increased with extraction temperature but decreased with extraction ratio. No significant differences in aromatics content were found among the extracts prepared with various extraction conditions; extraction ratio, extraction temperature, extraction pH and composition of extractant. Total flavonoid content of the extract was increased with extraction temperature and extraction pH, and highest value of it was found when extractant composition of ethanol in water was 75%. Total polyphenol compound content (TPC) of the extract with 10 fold extraction ratio showed the highest value, but no significant difference in TPC was found with extraction temperature. Reducing power and DPPH (${\alpha}$,${\alpha}$-diphenyl-${\beta}$-picrylhydrazyl) radical scavenging ability (RSA) of the extract in spectrophotometric absorbance were decreased with extraction ratio but increased with extraction temperature and showed 63.1%~98.4% and 67.6%~86.7% of those of ascorbic acid in reducing power and DPPH RSA, respectively. The antioxidative effects of the extract on corn oil were 84.8~93.0% of that of commercial butylated hydroxytoluene, the antioxidant index value was highest when the ethanol composition to water in extractant was equal ratio.

A Novel Asymmetrical Half-type IPM BLDC Motor Structure for Reducing Torque Ripple (토크 리플 저감을 위한 새로운 비대칭 하프-타입 영구자석 매입형 브러시리스 직류 모터 구조)

  • Sim, Yosub;Niguchi, Noboru;Hirata, Katsuhiro
    • The Transactions of the Korean Institute of Power Electronics
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    • v.21 no.2
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    • pp.134-143
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    • 2016
  • This paper proposes a novel asymmetrical interior permanent magnet (IPM) brushless DC (BLDC) motor structure, which utilizes half-type permanent magnet (PM) configuration and has asymmetrical side gaps (slot next to the PMs) for reducing torque ripples. This structure uses 24% less volume of PMs than conventional IPM BLDC motor with a full set of magnets. The characteristics of the proposed motor are compared with three other half-type IPM BLDC motors through finite elements method (FEM) analysis, and the usefulness of the proposed motor was verified through experimental evaluation on prototypes of the conventional motor and proposed motor under various torque load conditions. This research obtained a high-performance IPM BLDC motor while decreasing manufacturing cost at the same time.

Improving the Reactivity and Harmlessness of Recalcitrant Contaminants by Reduction-oxidation-linked Process (환원-산화 연계처리를 통한 니트로벤젠의 반응성 향상 및 무해화 연구)

  • Kwon, Hee-Won;Hwang, Inseong;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.29 no.12
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    • pp.1205-1211
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    • 2020
  • In this study, the applicability of reduction-oxidation-linked treatment was evaluated for nitrobenzene and a by-product by analyzing the reaction kinetics. Nitrobenzene showed very low reactivity to persulfate that was activated using various methods. Nitrobenzene effectively reacted through the reduction process using Zero-Valent Iron (ZVI). However, aniline, a toxic substance, was produced as a by-product. Reduction-oxidation-linked treatment is a method that can allow the oxidative degradation of aniline after reducing nitrobenzene to aniline. The experimental results show improved reactivity and complete decomposition of the by-product. Improved reactivity and decomposition of the by-product were observed even under conditions in which the reduction-oxidation reaction was induced simultaneously. No activator was injected for persulfate activation in the process of reducing oxidant linkage, and the activation reaction was induced by ferrous iron eluted from the ZVI. This indicates that this method can be implemented relatively simply.

Reducing sugar contents of potato tubers and potato chip color by pretreated methods (감자의 전처리 방법에 따른 환원당 함량과 potato chip의 색상)

  • Nam, Kyung-Ah;Noh, Wan-Seob
    • Applied Biological Chemistry
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    • v.35 no.6
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    • pp.437-442
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    • 1992
  • In order to develop color of potato chip made from Superior variety and Irish Cobbler variety, various conditions on NaCl and $CaCl_2$ contents, heat treatment and soaking time were applied. The content of reducing sugar decreased by $30{\sim}40%$ in blanching without NaCl and $CaCl_2$. In NaCl soaking case, reducing sugar content decreased by $15{\sim}30%$, however, partial colorization was appeared that the sample turned to brown. In the sample that were soaking in NaCl solution and heat treated, reduction of reducing sugar was 40% and desirable time for heat treatment was 5 min and 7 min. In the sample treated $CaCl_2$ solution, reduction of reducing sugar was $25{\sim}30%$ and then color was not acceptable. In the sample soaking $CaCl_2$ solution and heat treated, reducing sugar content rapidly by 50% and the color development was the most ideal.

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Establishment of Washing Conditions for Salad to Reduce the Microbial Hazard (샐러드의 미생물학적 위해 감소를 위한 세척 조건 확립)

  • Kim, Jeong-Weon;Kim, Soo-Hee
    • Korean journal of food and cookery science
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    • v.21 no.5
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    • pp.703-708
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    • 2005
  • The purposes of this study were to establish washing conditions for vegetable salad to reduce the microbial hazard by using sodium hypochlorite solution and eventually to implement HACCP for salad processing. By using the salad production line of Shinkeum Co. located in Gwacheon, Gyunggi-do, salad samples were washed under several washing conditions (chlorine dip period, chlorine concentration, rinse time, etc.) to determine the most effective conditions. The original washing line consisted of 3 baths (100 ppm chlorine water dip, water rinse, and water rinse), each with a capacity of 100 L of tap water and 5 kg of salad. First, the salad samples were washed with 100 ppm of sodium hypochlorite solution for various dip times (3, 6, 9, 12 min); however, only a 1 log- or less-reduction in total microbial counts was achieved in all groups and the time of chlorine water dip was not a significant factor in reducing the microbial hazard. When another water bath was added before the chlorine water dip (4-bath washing), a 2 log-reduction in total microbial counts was achieved. This result suggested the importance of pre-dipping salad materials in water before chlorine treatment to reduce the organic load on the surface of the vegetables. Coliforms were not detected at all after washing. As the concentration of chlorine $(50{\sim}150\;ppm)$ and rinse time $(0.5{\sim}2\;min)$ increased, greater microbial reduction was achieved; however, physical damage of the salad was observed. Finally, the optimum washing conditions for salad were determined as 3 min-water dip, 3 min-chlorine (100 ppm) dip, 2 min-rinse, and 2 min-rinse.