• Title/Summary/Keyword: Variation of permeability

Search Result 273, Processing Time 0.038 seconds

Characteristics of Coated Carbon Paper with PTFE Emulsion Have Different Particle Size (PTFE 입자 크기 변화와 Carbon Paper 발수 코팅 특성 변화)

  • Jeon, Hyeon;Song, Ki-Se;Jeong, Moon-Gook;Lee, Hye-Min;Cho, Tae-Hwan;Choi, Weon-Kyung
    • Journal of Hydrogen and New Energy
    • /
    • v.20 no.5
    • /
    • pp.424-431
    • /
    • 2009
  • Treatment for water repellency on the carbon supports of GDL which composed a part of MEA has been suggested as a solution to prevent flooding. PTFE is a fluoropolymer that has hydrophobic property and a PTFE emulsion was selected as waterproof agent in this investigation. Carbon paper was coated by PTFE emulsion with different particle size of 5~500 nm and 3~$5\;{\mu}m$ as various concentration. PTFE coated carbon paper has difference in weight variation changed proportionally at PTFE concentration and coating times. Then gas permeability of the coated carbon paper with emulsion of 3~$5\;{\mu}m$ PTFE was changed vastly. Characteristics of carbon paper coated with different PTFE emulsion were analyzed by FE-SEM, FT-IR spcetroscopy and were evaluated by weight variations, gas permeability and water contact angle.

Liquid Uptake and Methanol Transport Behaviour of PVDF/SPEEK/TiO2 Hybrid Membrane for DMFC (DMFC용 PVDF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상)

  • You, Sun-Kyung;Kim, Han-Joo;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.8 no.4
    • /
    • pp.177-180
    • /
    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nano particles content. Their liquid uptake, methanol permeability and proton conductivity as a function of inorganic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and liquid uptake. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

The Analysis of the Seepage Quantity of Reservoir Embankment using Stochastic Response Surface Method (확률론적 응답면 기법을 이용한 저수지 제체의 침투수량 해석)

  • Bong, Tae-Ho;Son, Young-Hwan;Noh, Soo-Kack;Choi, Woo-Seok
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.55 no.3
    • /
    • pp.75-84
    • /
    • 2013
  • The seepage quantity analysis of reservoir embankment is very important for assessment of embankment safety. However, the conventional analysis does not consider uncertainty of soil properties. Permeability is known that the coefficient of variation is larger than other soil properties and seepage quantity is highly dependent on the permeability of embankment. Therefore, probabilistic analysis should be carried out for seepage analysis. To designers, however, the probabilistic analysis is not an easy task. In this paper, the method that can be performed probabilistic analysis easily and efficiently through the numerical analysis based commercial program is proposed. Stochastic response surface method is used for approximate the limit state function and when estimating the coefficients, the moving least squares method is applied in order to reduce local error. The probabilistic analysis is performed by LHC-MCS through the response surface. This method was applied to two type (homogeneous, core zone) earth dams and permeability of embankment body and core are considered as random variables. As a result, seepage quantity was predicted effectively by response surface and probabilistic analysis could be successfully implemented.

The utilities of U-shape EM sensor in stress monitoring

  • Wang, Guodun;Wang, Ming L.
    • Structural Engineering and Mechanics
    • /
    • v.17 no.3_4
    • /
    • pp.291-302
    • /
    • 2004
  • In this paper, load monitoring technologies using U-shape Magnetoelastic (EM or ME) sensors have been exploited systemically for the first time. The steel rod to be tested is the Japan 7 mm piano steel rod. The load dependence of the magnetic properties of the piano steel rod was manifested. Two experimental designs of U-shape magnetoelastic sensors were introduced, one with double pick-up concentric coils wound on the rod to be tested, the other with pick-up coil on one yoke foot. The former design is used to derive the correlation of the relative permeability with elastic tension, while the latter is aimed to reflect the stress induced magnetic flux variation along the magnetic circuit. Magnetostatic simulations provide interpretations for the yoke foot sensing technology. Tests with double pick-up coils indicate that under proper working points (primary voltages), the relative permeability varies linearly with the axial load for the Japan 7 mm piano steel rod. Tests with pick-up coil on the yoke foot show that the integrated sensing voltage changes quadratically with the load, and error is more acceptable when the working point is high enough.

Separation of Aqueous Ethanol Solution Using a PAA-PAN Composite Membrane Through Pervaporation (PAA-PAN 복합막을 이용한 에탄올 수용액의 투과증발 분리)

  • 원장묵;하백현;최호상
    • Membrane Journal
    • /
    • v.6 no.3
    • /
    • pp.182-187
    • /
    • 1996
  • Hydrophilic poly(acrylonitrile) [PAN] membrane with good molecular weight cut-off characteristics were prepared by using the phase inversion method. Permeability and molecular weight cut-off of the membranes were measured through the ultrafiltration test. On the surface of the PAN support membranes, poly(acrylic acid) [PAA] was deposited by dip-coating. The water permeability of the PAN support membrane had $0.17~31\textrm{mm}^3/m^{2} \cdot s \cdot Pa$, the molecular weight cut-off 42, 000~150, 000. The transport characteristics of the prepared composite membranes were significantly affected by the variation of the support membrane mophology. The permeability of the composite membrane was decreased with increasing molecular weight cut-off of the support membrane, and the separation factor was slightly changed depending on the feed concentration.

  • PDF

Development of Rail-transport Operation Control in Consideration of the Stability Variation of Railway Embankment under Rainfall (강우시 사면안전성 변화를 고려한 열차운전규제 개발)

  • 신민호;김현기;김정기
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2003.06a
    • /
    • pp.13-22
    • /
    • 2003
  • Train speed and infiltration of rainfall causes railway embankment to be unstable and may result in failure. Therefore, the variation in the safety factor of railway embankment should be analyzed as the function of rainfall intensity, rainfall duration, and train speed and the study is accomplished using numerical analysis program. Based on unsaturated soil engineering, the variables in the shear strength function and permeability function are also defined and used for the numerical model for evaluation of railway embankments under rainfall. As a result of the study, in order to secure the safety of train under rainfall, the variation in the safety factor of railway embankment is predicted as the function of rainfall intensity, duration time and the train load as a function of train speed. It is possible to ensure the safety of train under rainfall. Thereafter, the feasibility of the rail-transport operation control with engineering basis was established.

  • PDF

Variation of Slope Stability under rainfall considering Train Speed (열차의 속도 하중을 고려한 강우시 성토사면의 안정성 변화)

  • 김정기;김현기;박영곤;신민호;김수삼
    • Proceedings of the KSR Conference
    • /
    • 2002.10a
    • /
    • pp.601-607
    • /
    • 2002
  • Infiltration of rainfall causes railway embankment to be unstable and may result in failure. Basic relationship between the stability of railway embankment and rainfall introducing the partial saturation concept of ground are defined to analyze the stability of embankment by rainfall. A pressure plate test is also peformed to obtain soil-water characteristic curve of unsaturated soils. Based on this curve, the variables in the shear strength function and permeability function are also defined. These functions are used fur the numerical model for evaluation of railway embankments under rainfall. As comparing the model and case studies, the variation of shear strength, the degree of saturation and pore-water pressure for railway embankment during rainfall can be predicted and the safety factor of railway embankment can be expressed as the function of rainfall amount namely rainfall index. Therefore, the research on safety factor on railway embankment considering train speed and rainfall infiltration with the variation of rainfall intensity and rainfall duration was carried out in this paper.

  • PDF

The Effect of the Characteristics of Tipping Paper, Plug Wrap and Glue on the Cigarette Ventilation (팁페이파, 필터권지 및 접착제 특성이 제품담배 공기희석율에 미치는 영향)

  • 김정열;김종열;신창호
    • Journal of the Korean Society of Tobacco Science
    • /
    • v.24 no.1
    • /
    • pp.60-66
    • /
    • 2002
  • The ventilation rate of a ventilated filter cigarette depends on the details of its construction and on the properties of its components such as tobacco column pressure drop, filter pressure drop, tipping paper and plug wrap permeability, and vent position. Also, It was affected by the condition of adhesion of glue between tipping paper and plug wrap. This study was carried out to find the effect of surface properties of tipping paper and plug wrap, and a characteristics of glue on the ventilation rate of cigarettes. Our results indicated that the surface properties of tipping paper and plug wrap affected on the ventilation rate of cigarette. Also, the variation of ventilation rate was affected by the surface properties of tipping paper and the size of glue particles. We also found that the surface properties of tipping paper and plug wrap, and the emersion size of glue were the major factors to concern in the design for materials of cigarettes.

Experimental Study on the Characteristics of Water Flow Through Sand Layer (모래층에서의 수류의 특성에 관한 실험적 연구)

  • 남궁달;김철기
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.17 no.3
    • /
    • pp.3833-3839
    • /
    • 1975
  • The object of this experiment is to find out some flow characteristics of water through sand layer, to prevent moving sands in the filters of the fill Dam, infiltration gallery, well and Deversion Weir. This experiment was accomplished with different particle Sizes of Six Samples and different hydraulic gradient. The results obtained are Summarized as follows. 1. The critical hydraulic gradients for laminar flow was found to be between 1 and 2 when the sand used had the effective diameter, D10 of between 0.18cm and 0.45cm. 2. The critical hydraulic gradients for different particle sizes of sands were varied considerably. 3. There was a negative correlation between critical hydraulic gradient and critical Velocity, and between effective particle diameter D10 and critical hydraulic gradient respectively. 4. In spite of relatively small variation of void ratio of sands used, the values of the coefficient of permeability varied considerably. There was a negative correlation between coefficient of permeability and void ratio.

  • PDF

Studies on Spinel Ferrites (I) Effects of Addition of Rare-Earth Oxides on the Magnetic Properties of Mn-Zn Ferrites (Spinel Ferrite에 관한 연구 (I) Mn-Zn계 Ferrite의 자기특성에 대한 희토류산화물의 첨가효과)

  • 김태옥
    • Journal of the Korean Ceramic Society
    • /
    • v.14 no.2
    • /
    • pp.78-81
    • /
    • 1977
  • The effects of variation in composition and the addition of small amount of the rare-earth oxides La2O3, CeO2 and Sm2O3 on the magnetic properties of Mn-Zn system ferrites, 0.5MnO.0.5ZnO.(1+0.1X) Fe2O3(X=-1, 0, 1, 2), were investigated in the range of frequencies of 0.1~100 kHz. It was shown that the magnetic permeability of the specimens with the composition Mn 0.5 Zn 0.5 Fe2O4 was maximum in the Mn-Zn system ferrites, and that the addition of a small amount of the rare-earth oxides to the composition 0.5 MnO.0.5ZnO.0.9 Fe2O3 caused the sharp increase of magnetic permeability and the decrease of the loss factors.

  • PDF