• Title/Summary/Keyword: Value Orientation

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Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1452-1458
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    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.

The Curved Interfacial Crack Analysis between Foam and Composite Materials under Anti-plane Shear Force (반평면 전단하중력하에서 곡면형상 접합면을 가지는 폼과 복합재료 접합부의 계면크랙에 관한 연구)

  • 박상현;전흥재
    • Composites Research
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    • v.13 no.4
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    • pp.67-74
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    • 2000
  • The general solution of the anti-plane shear problem for the curved interfacial crack between viscoelastic foam and composites was investigated with the complex variable displacement function. Kelvin-Maxwell three parameter model is used to present viscoelasticity and the Laplace transform was applied to treat the viscoelastic characteristics of foam in the analysis. The stress intensity factor near the interfacial crack tip was predicted by considering both anisotropic and viscoelastic properties of two different materials. The results showed that the stress intensity factor increased with increasing the curvature of the curved interfacial crack and it also increased and eventually converged to a specific value with increasing time. The stress intensity factor increased with increasing the ratio of stiffness coefficients between foam and composites and the effect of fiber orientation on the stress intensity factor decreased with increasing the ratio of stiffness coefficients between foam and composites.

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Energy Saving Effect and Economy Feasibility of Office Building with regard to Geometries and Orientations

  • Koh, Jae-Yoon;Zhai, John
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.1
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    • pp.15-24
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    • 2009
  • The energy usage and the economical feasibility of the typical two story office building in the three urban locations of South Korea are evaluated as the eight orientations. The smallest energy consume is shown at the true south. The ranges of the low energy consume are $-3l5^{\circ}{\sim}0^{\circ}\;and\;-135^{\circ}{\sim}-180^{\circ}$. There are obvious advantages of passive solar designs such as using a fully glazed facade at the true south in the building. The General Low voltage plan is the effective way for the office building when does not required the high voltage electricity. The energy cost of KEPCO is compared to that of XCEL ENERGY. The portion of the customer charge of XCEL ENERGY is about 10% but it is about 50% of the total tariff of KEPCO. The effective way to save the energy cost is by reducing the operating energy of XCEL ENERGY plane but the most effective way is reduce the contracting energy of KEPCO plane.

Structural and Electrical Characteristics of IZO Thin Films Deposited at Different Hydrogen Flow Rate (수소 유량에 따른 IZO 박막의 구조적 및 전기적 특성)

  • Hong, Kyoung-Lim;Lee, Kyu-Mann
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.7-11
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    • 2019
  • We have investigated the effect of the hydrogen flow rate on the characteristics of IZO thin films for the TCO (transparent conducting oxide). For this purpose, IZO thin films are deposited by RF magnetron sputtering at 300℃ with various H2 flow rate. To investigate the influences of the ambient gases, the flow rate of hydrogen in argon was varied from 0.1 sccm to 1 sccm. The IZO thin films deposited at 300℃ show crystalline structure having an (222) preferential orientation. The electrical resistivity of the crystalline-IZO films deposited at 300℃ and hydrogen gas of 0.8sccm was 3.192×10-4Ω cm, the lowest value. As the hydrogen gas flow rate increased, the resistivity tended to decrease. The XPS profiles showed that the number of oxygen vacancy decreased as the hydrogen flow rate increased. The transmittance of the IZO films deposited at 300℃ were showed more than 80%.

Homology Modeling and Molecular Docking Analysis of Streptomyces peucetius CYP125A4 as C26 Monooxygenase

  • Lee, Seung-Won;Lee, Na-Rae;Lee, Ji-Hun;Oh, Tae-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1885-1889
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    • 2012
  • Among 23 cytochrome P450s, CYP125A4 was proposed as a putative monooxygenase based on the high level of amino acid sequence homology (54% identity and 75% similarity) with the well characterized C27-steroid $Mycobacterium$ $tuberculosis$ CYP125A1. Utilizing MTBCYP125A1 as a template, homology modeling of SPCYP125A4 was conducted by Accelrys Discovery Studio 3.1 software. The modeled SPCYP125A4 structure with lowest energy value was subsequently assessed for its stereochemical quality and side-chain environment. The final model was generated by showing its active site through the molecular dynamics. The docking of steroids showed broad specificity of SPCYP125A4 with different orientation of ligand within active site facing the heme. One poses of C27-steroid with C26 facing the heme with distance of 3.734 ${\AA}$ from the Fe were predominant.

Fabrication of Silicon Angle Standard and Calibration of Rotary Encoder Using Silicon Angle Standard (각도교정용 실리콘 다면체의 제작과 이를 이용한 회전에코더의 각도교정)

  • 박진원;엄천일
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.88-92
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    • 1995
  • Higly pure silicon crystals with an almost perfect lattice structure constityte a powerful metrological tool. The streographic standard prohection for the (111) orientation of diamond structure found by the Laue method shows angles between net planes of 60°. This value is known to be certain to some 10-8 rad. We have made a six-faced silicon polygon, and the (220) lattice planes of the polygon act as a reference angular standard. The information of angles between lattice planes could be taken by the X-ray diffraction. The angle of the rotary encoder have been calibrated using the silicon angle standard. The X-ray optics was double crystal arrangement.

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A Study on the Electromagnetic Properties of $La_{1-x}Ca_xMnO_3$(x=0.33) grown by Floating Zone Method (FZ법에 의한 $La_{1-x}Ca_xMnO_3$(x=0.33)의 결정성장과 전자기적 물성에 대한 연구)

  • 정준기;송규정;조남희;김철진
    • Korean Journal of Crystallography
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    • v.13 no.1
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    • pp.41-47
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    • 2002
  • La/sub 1-x/Ca/sub x/MnO₃ manganese oxide were grown using the floating zone image furnace with halogen lamps as heat source. The growth condition was 4∼6 mm/hr growth rate in air atmosphere, 45∼50 rpm and 20∼25 rpm of rotation rate of feedrod and growing crystal, respectively. Characterization analyses of the crystal were carried out using XRD, SEM, and EPMA. Orientation of crystal was determined using EBSD. The electromagnetic properties were measured with Quantum Design PPMS by 4 point probe method and resulted MR value of 462% at 215 K.

The individual influence factors of voluntary turnover among knowledge workers in China: A case study of Huawei

  • Feng, Hua;Cao, Mengyin
    • Journal of Contemporary Eastern Asia
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    • v.16 no.2
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    • pp.3-19
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    • 2017
  • "Knowledge worker" is a term used to describe highly educated people whose role in the workforce involves the use of information and knowledge. Knowledge workers are key to the success of a great many organizations. Many Chinese companies find that the voluntary turnover rate among their knowledge workers is high. The purpose of this paper is to explore, from the perspective of knowledge workers and the characteristics peculiar to them, the factors that influence this high voluntary turnover rate. The models used in this paper, that will enable understanding of the characteristics of knowledge workers in China, are the Chinese Personality Assessment Inventory and the Five Factors Model. In the case of Huawei, analysis using these models leads to the conclusion that the main factors that influence the voluntary turnover of knowledge workers in China are: age; gender; degree of extraversion and how open the person is to new experiences; family orientation; and occupation. This study leads to the conclusion that the company should pay closer attention to three groups: female employees who put a high value on their families; employees from non-R&D departments; and younger employees who show a high degree of openness to new experiences.

A Study on the AlN Thin Film on A1$_2$O$_3$ Substrate Prepared by Reactive RF Magnetron Sputtering System for SAW Device Application (A1$_2$O$_3$기판위에 반응성 RF 마그네트론 스퍼터로 증착한 AlN 박막의 SAW소자 응용에 관한 연구)

  • 고봉철;손진운;김경석;엄무수;남창우;이규철
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.7
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    • pp.288-292
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    • 2003
  • AlM thin film has been deposited on A1$_2$O$_3$ substrate by reactive radio frequency(RF) magnetron sputtering method under various operating conditions such as working pressure, fraction of nitrogen partial pressure, and substrate temperature. Scanning Electron Microscope(SEM), X-ray Diffraction(XRD), and Atomic Force Microscope(AFM) have been measured to find out structural properties and preferred orientation of AlN thin films. SAW velocity of IDTs/AlN/Si structure was about 5038[㎧] at the center frequency of 251.9[MHz] and insertion loss was measured to be relatively low value of 35.6[dB]. SAW velocity of IDTs/AlN/A1$_2$O$_3$ structure was improved to be about 5960[㎧] at the center frequency of 296.7[MHz].

Simple Al Robust Digital Position Control of PMSM using Neural Network Compensator (신경망 보상기를 이용한 PMSM의 간단한 지능형 강인 위치 제어)

  • Ko, Jong-Sun;Youn, Sung-Koo;Lee, Tae-Ho
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.49 no.8
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    • pp.557-564
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    • 2000
  • A very simple control approach using neural network for the robust position control of a Permanent Magnet Synchronous Motor(PMSM) is presented. The linear quadratic controller plus feedforward neural network is employed to obtain the robust PMSM system approximately linearized using field-orientation method for an AC servo. The neural network is trained in on-line phases and this neural network is composed by a feedforward recall and error back-propagation training. Since the total number of nodes are only eight, this system can be easily realized by the general microprocessor. During the normal operation, the input-output response is sampled and the weighting value is trained multi-times by error back-propagation method at each sample period to accommodate the possible variations in the parameters or load torque. In addition, the robustness is also obtained without affecting overall system response. This method is realized by a floating-point Digital Signal Processor DS1102 Board (TMS320C31).

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