• Title/Summary/Keyword: Valence

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Effective Valence Shell Hamiltonian Calculations on Spin-Orbit Coupling of SiH, SiH+, and SiH2+

  • Chang, Ye-Won;Sun, Ho-Sung
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.723-727
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    • 2003
  • Recently the ab initio effective valence shell Hamiltonian method $H^v$ has been extended to treat spin-orbit coupling in atoms or molecules. The quasidegenerate many-body perturbation theory based $H^v$ method has an advantage of determining the spin-orbit coupling energies of all valence states for both the neutral species and its ions with a similar accuracy from a single computation of the effective spin-orbit coupling operator. The new spin-orbit $H^v$ method is applied to calculating the fine structure splittings of the valence states of SiH, $SiH^+$, and $SiH^{2+}$ not only to assess the accuracy of the method but also to investigate the spin-orbit interaction of highly excited states of SiH species. The computed spin-orbit splittings for ground states are in good agreement with experiment and the few available ab initio computations. The ordering of fine structure levels of the bound and quasi-bound spin-orbit coupled valence states of SiH and its ions, for which neither experiment nor theory is available, is predicted.

Music Exploring Interface using Emotional Model (감성모델을 이용한 음악 탐색 인터페이스)

  • Yoo, Min-Joon;Kim, Hyun-Ju;Lee, In-Kwon
    • 한국HCI학회:학술대회논문집
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    • 2009.02a
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    • pp.707-710
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    • 2009
  • In this paper, we introduce an interface for exploring music using emotional model. First, we survey arousal-valence factors of various music and calculate a correlation between audio fefatures of music and arousal-valence factors to build an AV model. Then, various music is aligned and arranged using the AV model and the user can explore music in this interface. To select the desired music more intuitively, we introduce new fade in/out function based on the location of the user's mouse point. We also offer several mode of selecting music so user can explore music using most suitable mode of interface. With our interface, the user can find the emotionally desired music more easily.

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Interaction between emotional content of word and prosody in the evaluation of emotional valence (정서의미 전달에 있어서 운율과 단어 정보의 상호작용.)

  • Choi, Moon-Gee;Nam, Ki-Chun
    • Proceedings of the KSPS conference
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    • 2007.05a
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    • pp.67-70
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    • 2007
  • The present paper focuses on the interaction between lexical-semantic information and affective prosody. The previous studies showed that the influence of lexical-semantic information on the affective evaluation of the prosody was relatively clear, but the influence of emotional prosody on the word evaluation remains still ambiguous. In the present, we explore whether affective prosody influence on the evaluation of affective meaning of a word and vice versa, using more ecological stimulus (sentences) than simple words. We asked participants to evaluate the emotional valence of the sentences which were recorded with affective prosody (negative, neutral, and positive) in Experiment 1 and the emotional valence of their prosodies in Experiment 2. The results showed that the emotional valence of prosody can influence on the emotional evaluation of sentences and vice versa. Interestingly, the positive prosody is likely to be more responsible to this interaction.

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Analysis of Electroencephalogram Electrode Position and Spectral Feature for Emotion Recognition (정서 인지를 위한 뇌파 전극 위치 및 주파수 특징 분석)

  • Chung, Seong-Youb;Yoon, Hyun-Joong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.35 no.2
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    • pp.64-70
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    • 2012
  • This paper presents a statistical analysis method for the selection of electroencephalogram (EEG) electrode positions and spectral features to recognize emotion, where emotional valence and arousal are classified into three and two levels, respectively. Ten experiments for a subject were performed under three categorized IAPS (International Affective Picture System) pictures, i.e., high valence and high arousal, medium valence and low arousal, and low valence and high arousal. The electroencephalogram was recorded from 12 sites according to the international 10~20 system referenced to Cz. The statistical analysis approach using ANOVA with Tukey's HSD is employed to identify statistically significant EEG electrode positions and spectral features in the emotion recognition.

The Analysis of Color Vision Defects Mechanism for the Electric Circuits (전기적 회로에 의한 색각이상 mechanism 해석)

  • Park, Sang-An;Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.1
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    • pp.81-85
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    • 2001
  • The color vision was composed of the wavelength absorption of three R. G. B cone photo-receptors and the r-g, y-b channel of an opponent process. The color vision defects mechanism for the electric circuit made up a photo cell, relay switch and transformer. This mechanism very well applied to the color vision defects mechanism owing to be y-b chromatic valence function in case of a cone R or G defects and to be r-g chromatic valence function in case of a cone B defects.

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Electronic Spectroscopy and Structure of CLF

  • Vadim A. Alekseev;D. W. Setser
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.9-22
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    • 2000
  • Optical-optical double resonance experiments have been used to identify and characterize five ion-pair states and several of the bound and repulsive valence states of ClF. This report provides a description of these experiments for $^{35}CIF$ and $^{37}CIF$, and a summary of the current knowledge of the valence and ion-pair states. The important role of perturbations among the rovibronic levels of the bound valence states and their utilization in the double resonance technique is discussed. The ion-pair states of the same symmetry, ${\Omega}$=$0^+$ (E and f) and 1( $\beta$ and G) interact very strongly and the spectroscopy of these states is anomalous and, hence, interesting. Comparison is made to some recent ab initio calculations for ClF. One possible explanation of the irregular vibrational energy levels and rotational constants of the ion-pair states of $O^+$ and 1 symmetry is a crossing of the diabatic potentials of these states. Some currently unresolved questions about ClF spectroscopy are posed for future work. Where appropriate, analogy is made between the electronic states of ClF and the corresponding valence and ion-pair states of $Cl_2.$.

The Effect of task-irrelevant affective priming on belief-bias (과제 무관련 정서 점화가 신념편향에 미치는 영향)

  • Hong, Youngji;Woo, Hyunjung;Lee, Yoonhyoung
    • Korean Journal of Cognitive Science
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    • v.28 no.1
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    • pp.43-64
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    • 2017
  • The purpose of the current study is to investigate how task-irrelevant affective priming affects higher cognitive function. In the study, we selected prime stimuli from International Affective Picture System(IAPS) and examined if they influence participants' performance of syllogistic reasoning task when they are task-irrelevant. In Experiment 1, arousal of IAPS stimuli was controlled while valence of the stimuli was manipulated. In Experiment 2, valence of IAPS stimuli was controlled while arousal of stimuli was manipulated. In both experiments, task-irrelevant affective primes were followed by syllogistic reasoning tasks consisting of three sentences and measured accuracies of task performance. The results showed that valence of affective prime affected logical validity of reasoning and belief-bias whereas arousal of affective primes did not yield any difference. That is, positive valence facilitated logical and analytic processing by reducing belief-bias while arousal did not affect reasoning task performance. These results suggest that dimensions of valence and arousal independently influence higher cognitive function.

The Effect of Inorganic Electrolyte on the Electrokinetic Features of Calcium Carbonate Particles in Aqueous Environment (수중 탄산칼슘 입자의 전기적 거동에 미치는 무기염류의 영향)

  • O, Se-Jin;Choi, Eun-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.89-95
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    • 2010
  • The electrokinetic potential of $CaCO_3$, which takes an important part in aquatic system, has been measured and the variation of total energy between $CaCO_3$ particles with the distance of particles was estimated based on DLVO theory. The electrokinetic potential of particles was observed to increase to positive direction as the charge valence of cations which was added to suspension was increased. Also, the total interaction energy between particles was estimated to be more negative as the charge valence of cation was higher and its concentrations was raised. When a mixture of cations with different charge valences was added, the influence of cation with a higher charge valence was more significant on the total interaction energy between particles. When anion was added to the suspension of $CaCO_3$, the total energy estimated by DLVO theory was examined to move to positive direction and the electrokinetic potential of particles became more negative. Likewise cations, the effect of anions on the electrokinetic potential of particles and total interaction energy between them was observed to be proportional to their charge valence and the influence of the mixture of anions with different charge valence became more remarkable as the mixing ratio of the anion with a higher charge valence was increased.