• Title/Summary/Keyword: VS reduction

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Selective Recovery of Platinum Group Metals by Solvent Extraction and Electrolysis in Non-aqueous Solution Based on Ionic Liquids (이온성액체 기반 비수계 용액에서 용매추출과 전해에 의한 백금족 금속의 분리회수)

  • Park, Gwang-won;Park, Jesik;Lee, Churl Kyoung
    • Resources Recycling
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    • v.28 no.2
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    • pp.46-53
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    • 2019
  • In this study, the extraction and reduction behavior of platinum group metals in a non-aqueous solvent based on ionic liquids was investigated in order to confirm a new extraction technology of platinum group metals. Platinum was selectively extracted using an ionic liquid $[C_4mim]PF_6$ from a mixed solution of $PdCl_2$, $PtCl_4$ and $RhCl_3$ dissolved with concentration ratio of 10:1:0.5 M. After stripping of the metals by 1 M $HNO_3$ solution, the platinum was preferentially reduced by aqueous electrolysis on gold electrode at -0.8 V (vs. Pt-QRE). The residual palladium and rhodium were transferred to ionic liquid of $[C_4mim]Cl$. The metallic palladium and rhodium could be sequentially reduced on gold and STS304 as working electrodes by non-aqueous electrolysis, respectively.

Effect of storage temperature, period, and sawdust addition on the biochemical methane potential of cattle manure (우분의 저장온도, 저장기간, 톱밥의 혼합에 따른 메탄잠재량 변화)

  • Im, Seongwon;Kim, Sangmi;Kim, Hyu hyoung;Kim, Dong-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.1
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    • pp.29-36
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    • 2021
  • In spite of the highest energy potential among all domestic organic solid wastes. the research on biogas production from cattle manure is limited. In particular, effects of organic content degradation and sawdust addition during storage on biomethane potential have never been investigated. In the present work, we investigated the change of organic content during storage of cattle manure under different temperatures (20℃ and 30℃), and its impact on biomethane potential and odor emissions. 90 days of investigation results showed that 10% of organics in terms of VS and COD were degraded at 20℃ during storage, while 30% were degraded at 30℃. This result impacted on biomethane potential, while 10-13% and 24% reduction were observed from beef and dairy cattle manure, respectively. The temperature also affected on CH4 and odor emissions during storage by 3.3-3.8 times and 29 times. The effect of sawdust on lowering down biomethane potential was found to be substantial, reducing 61-75% compared to the control.

Flattening in the Anteroposterior Direction of the Terminal Ileum or Sigmoid Colon Lying Across the Psoas Muscle on Magnetic Resonance Enterography in Patients with Crohn's Disease

  • Dong Wook Kim;Seong Ho Park;Jong Seok Lee;Hyun Jin Kim;Ah Young Kim;Byong Duk Ye;Suk-Kyun Yang
    • Korean Journal of Radiology
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    • v.22 no.10
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    • pp.1640-1649
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    • 2021
  • Objective: Flattening in the anteroposterior direction (AP flattening) of the terminal ileum (TI) or sigmoid colon (SC) lying across the psoas muscle, on magnetic resonance enterography (MRE), might mimic bowel inflammation in the coronal view. This study investigated the prevalence of AP flattening and the factors associated with its development. Materials and Methods: A total of 364 surgery-naïve patients with Crohn's disease (CD) who had undergone MRE were retrospectively reviewed. AP flattening was defined as a luminal collapse in the anteroposterior direction, with a bowel width in the axial plane < 1/4 of the normal diameter without reduction of bowel width in coronal images. The prevalence of AP flattening of the TI and SC on MRE in patients with bowel segments lying across the psoas muscle was determined. We further compared the rate of AP flattening between MRE and computed tomography enterography (CTE) in a subcohort of patients with prior CTE. The factors associated with AP flattening were analyzed using multivariable logistic regression in a subcohort of patients with endoscopic findings of TI. Results: Three hundred and twenty-two and 363 patients, respectively, had TI and SC lying across the psoas muscle. The prevalence of AP flattening on MRE was 7.5% (24/322) in TI and 5.2% (19/363) in SC. The prevalences were significantly higher on MRE than on CTE in both the TI (7.3% [12/164] vs. 0.6% [1/164]; p = 0.003) and SC (5.8% [11/190] vs. 1.6% [3/190]; p = 0.039). AP flattening of the TI was independently and strongly associated with the absence of CD inflammation on endoscopy, with an adjusted odds ratio of 0.066 (p = 0.003) for the presence versus the absence (reference) of inflammation. Conclusion: AP flattening of the TI or SC lying across the psoas muscle was uncommon and predominantly observed on MRE of the bowel without CD inflammation.

Factors Affecting Membrane Fouling in Membrane Filtration of Activated Sludge (막결합형 활성슬러지 시스템에서의 막오염 유발 인자)

  • Chang, In-Soung;Lee, Chung-Hak
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.323-329
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    • 2000
  • The coupling of an activated sludge reactor with a membrane unit, i.e., Membrane Coupled Activated Sludge (MCAS) system offers several advantages over conventional process. But the major hurdle in the extensive use of this process is the continuous reduction of permeation flux caused by membrane fouling. The aim of this study is to investigate membrane fouling characteristics in the MCAS process. During crossflow ultrafiltration(CFUF) of activated sludge, floc size decreased abruptly at the beginning of operation and thereafter decreased continuously and gradually. The floc size changed from 100~200 to $6{\sim}8{\mu}m$ depending on recirculation velocity. This floc breakage played a key role in rapid increase of $R_c$(cake layer resistance), which led to flux decline. The floc breakage stimulated biomass to release EPS(Extracellular Polymeric Substance) which has been known to be one of the major membrane foul-ants. The amounts of EPS before and after CFUF were 266 and 405(VS mg/MLSS g), respectively. The rise up of EPS concentration was another factor affecting flux decline in MCAS system.

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A Method for Determination of Nitrogen in Ruminant Feedstuffs and Products

  • Islam, M.R.;Ishida, M.;Ando, S.;Nishida, T.;Yamada, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.10
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    • pp.1438-1442
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    • 2003
  • A method for the determination of nitrogen in ruminant feedstuffs, products and excreta (e.g. milk and urine) using a spectrophotometer is developed, where samples processed for P determination are also used to determine N. Samples are digested with sulphuric acid and subsequently with hydrogen peroxide in Kjeldahl tubes. Digested solutions along with phenol and buffered alkaline hypochlorite reagents are incubated in a water bath at $37^{\circ}C$ for 30 min and presented in the spectrophotometer. The spectrophotometer set at 625 nm measures the concentration of N of each sample. Nitrogen in 261 of the samples was also determined by the classical Kjeldahl method in order to develop a relationship between N determined by the Kjeldahl method (Y) and the colorimetric method (X). The mean value of Y was as high as that of X (0.92 vs. 0.96; p>0.05). The colorimetric method predicted Kjeldahl N highly significantly (Y=0.985X-0.024, $R^2=0.993$, p<0.001; or more simply Y=0.974X, $R^2=0.993$, p<0.001). An analysis of regression found no difference (p>0.05; both t-test and F-test) between colorimetric (0.96% N) and adjusted (0.96% N) N. In comparison with the Kjeldahl method, the analytical capacity of N by colorimetric method increases greatly, where 200-300 determinations of N are possible in a working day. In addition, the system provides an opportunity to use not only the same digested solution for both N and P determination of a particular sample, but also uses the same spectrophotometer to assay both N and P. Therefore, the system may be attractive in situations where both elements of a sample are to be determined. In conclusion, the speed of N determination, low cost, efficient use of labour, time and reagents, fewer items of equipment, and the reduction of environmental pollution by reducing effluent and toxic elements are the advantages of this method of N determination.

An Investigation of the Impacts of Employer's Rewards Strategies on Employee's Commitment with Comparison of Home-based Contact Center (종업원에 대한 보상전략이 몰입에 미치는 영향: 재택근무와의 비교를 중심으로)

  • Kim, Jae-Young;Cho, Boo-Yun
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.3
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    • pp.125-137
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    • 2015
  • Information technology enables home-based working which is a new way to satisfy the firm and its employees. Firms are under pressure of cost reduction, and employees want to maintain balance of life between work and family. Considering the organization's capability can be the core competency, firm's efforts to acquire workers' commitment have been important issue in human resource management. However, researches to increase the workers' loyalty and commitment within home-base working have not been widely studied. This study tries to identify the relationships among firms' rewards supporting strategies and workers' perceived commitment with the working system as a context. Results confirm that the organization's extrinsic and intrinsic rewards affect the worker's continuous commitment, and the mediating role of normative commitment between workers' perceived affective commitment and continuous commitment has been found. Also, we empirically identify the moderating role of working systems(i.e., home-based, vs. office-based) within organization's rewards supporting strategies and workers' commitment perceptions.

The Clinical Study of Maxillofacial Bone Fracture (안면골 골절에 관한 임상적 연구)

  • Cho, Byoung-Ouck;Lee, Yong-Chan;Nam, Jong-Hun;Kim, Tae-Young;Koh, Back-Jin
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.11 no.1
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    • pp.32-40
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    • 1989
  • This study is based on 247 patients(348 cases) with facial bone fracture who were admitted to the department of oral and maxillofacial surgery, Kangnam sacred heart Hospital during the period of Jan. 1983 through sep. 1988. The patients with mandible fracture were analysed with the following items such as complications with treatment method undertaken : Bicortical osteosynthesis vs Monocortical osteosynthesis, advantages and Disadvantages. The results obtained are as follows : 1) The most common age groups for the facial bone fracture were 20 years 2) The ratio of Men to women was 5 : 1 3) The most frequent location of facial bone fractures was the Mandible(76.7%), Maxillae(10.6%), Zygoma(9.5%), Nasal bone(3.2%) 4) The ratio of Mandible to Maxillae was 7.2 : 1 5) In mandible fractures, the most frequent fracture site was Symphysis(48.7%) 6) In maxilla fractures, the most frequent case was Le fort III fracture(51.4%), followed by Le fort I fracture(29.7%), Le fort II fracture(18.9%) 7) The main contributing causes of facial bone fractures were Traffic Accident(37.7%), Fight(31.6%), Accident(27.5%) 8) In open reduction methods of mandible fracture, the frequency of postop, malocclusion was 15% in interosseous wiring, 7% in Bicortical osteosynthesis, 3% in Monocortical osteosynthesis. The miniplates show advantages over other forms of fixation, in that they are malleable and easy to insert, they achieve rigid fixation and stability.

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A Study on the Trace Analysis of Germanium in Inorganic Matrices by Differential Pulse Polarography (Differential Pulse Polarography에 의한 무기물 시료 중 Germanium의 미량 분석에 관한 연구)

  • Shin, Ho-Sang;Oh, Yun-Suk;Shin, Hak-Soo
    • Analytical Science and Technology
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    • v.9 no.3
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    • pp.253-261
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    • 1996
  • Analytical method for the determination of trace germanium in inorganic matrices by differential pulse polarography(DPP) was studied. The reduction peak of germanium(IV) in perchloric acid solution containing 1, 2, 3-trihydroxy benzene appeared at -0.45V(vs. Ag/AgCl) and the peak current for germanium complex varied linearly with concentration variation. Factors affecting sensitivity and precision for germanium quantification were studied and detection limit under the investigated parameters was 1ng/ml. Inorganic samples were decomposed by fusion with potassium pyrosulfate. Serious interferences of Se(IV), Pb(II), As(III) for the determination of germanium were discussed. Interferences of these elements could be avoided by extraction of germanium from decomposed matrices by $CCl_4$ in 10M HCl solution. The germanium contents of inorganic samples(Pb bf. dust, Cu bf. dust, gneiss, Cu anode slime) were determined by the above method.

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Microbial Enrichment and Community Analysis for Bioelectrochemical Acetate Production from Carbon Dioxide (이산화탄소로부터 생물전기화학적 아세트산 생산을 위한 미생물 농화배양 및 군집 분석)

  • Kim, Junhyung;Kim, Young-Eun;Park, Myeonghwa;Song, Young Eun;Seol, Eunhee;Kim, Jung Rae;Oh, You-Kwan
    • New & Renewable Energy
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    • v.16 no.1
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    • pp.58-67
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    • 2020
  • Microbial electrosynthesis has recently been considered a potentially sustainable biotechnology for converting carbon dioxide (CO2) into valuable biochemicals. In this study, bioelectrochemical acetate production from CO2 was studied in an H-type two-chambered reactor system with an anaerobic microbial consortium. Metal-rich mud flat was used as the inoculum and incubated electrochemically for 90 days under a cathode potential of -1.1 V (vs. Ag/AgCl). Four consecutive batch cultivations resulted in a high acetate concentration and productivity of 93 mmol/L and 7.35 mmol/L/day, respectively. The maximal coulombic efficiency (rate of recovered acetate from supplied electrons) was estimated to be 64%. Cyclic voltammetry showed a characteristic reduction peak at -0.2~-0.4 V, implying reductive acetate generation on the cathode electrode. Furthermore, several electroactive acetate-producing microorganisms were identified based on denaturing- gradient-gel-electrophoresis (DGGE) and 16S rRNA sequence analyses. These results suggest that the mud flat can be used effectively as a microbial source for bioelectrochemical CO2 conversion.

Peri- and Postnatal Study of Q-35, a Quinolone Antibiotic, in Rats (퀴놀론 유도체인 Q-35의 랫드에서의 주산 .수유기시험 연구)

  • 박귀례;한순영;김판기;신재호;조인구
    • Biomolecules & Therapeutics
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    • v.6 no.1
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    • pp.73-81
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    • 1998
  • Pregnant Sprague-Dawley rats were administered with Q-35 at the dose levels of 0, 30, 100 and 300 mg/kg/day by oral gavage from gestation day 17 to lactation period. Effects of the test chemical on general findings, reproductive performance of dams and development of Fl generation were examined. There were no treatment related changes in physical signs, body weight, necropsy findings, organ weights, delivery and nursing behavior. In 100 and 300 mg/fg/day treated groups, the food consumption of dams was decreased significantly during gestational day 19~21. The gestation length of 300 mg/tg/day treated group was increased significantly compared to the control group (22.3 $\pm$0.48 vs 22.0$\pm$0.39). Although the gestational length of all groups were in normal range of the rat, potential effect of the drug could not be ruled out. External anomaly of Fl fetus induced by Q-35 was not detected in any groups. There were no treaoent related changes in physical development, reflex functions, sensory functions, locomotor activity and motor coordinating activity. Estrus cycle, fertility and reproductive performance of Fl were not changed in all treated groups. There was no external abnormality related to the drug administration on the examination of F2. These results suggest that Q-35 has no adverse effect on the peri- and postnatal period in rats except the reduction of food consumption at the beginning of drug administration and the potential effect on the elongation of gestation length.

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