• 제목/요약/키워드: VOCs(Volatile Organic Compounds)

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공정 조건에 따른 톨루엔 및 MEK에 대한 ACF의 흡·탈착 특성 (Adsorption/Desorption Properties of ACF on Toluene and MEK with Operation Condition)

  • 백근호;김정수;장현태;차왕석
    • 한국산학기술학회논문지
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    • 제12권6호
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    • pp.2898-2903
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    • 2011
  • 휘발성 유기화합물인 저 농도의 MEK와 톨루엔을 사용하여 고정층 반응기에서 활성탄소섬유의 흡착 및 탈착특성을 조사하였다. 활성탄소섬유의 성능은 평형흡수량, 평형에 도달하는 시간, 그리고 탈착효율로 파악하였다. 다양한 실험을 통해 흡착공정에 있어 중요한 공정변수인 유입가스농도, 유량, 수분함량, 흡착제 주입량에 대한 영향을 연구하였다. 흡착층의 온도, 유량 그리고 유입가스농도가 증가할수록 파과시간이 감소하였다. 그리고 흡착제의 충전높이가 증가할수록 파과시간은 길어짐을 알 수 있었다. MEK와 톨루엔으로 흡착된 활성탄소섬유는 일정속도 가열과정을 통해 만족스럽게 재생되었으며 두 휘발성 유기화합물 중 MEK가 $150^{\circ}C$이하의 온도에서 훨씬 손쉽게 재생됨을 알 수 있었다.

포항과 구미의 대규모 산단지역 대기 중 휘발성 유기화합물 농도 분포 특성에 관한 연구 (Characterization of Atmospheric Concentrations of Volatile Organic Compounds in Industrial Areas of Pohang and Gumi Cities)

  • 백성옥;김수현;김미현
    • Environmental Analysis Health and Toxicology
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    • 제20권2호
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    • pp.167-178
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    • 2005
  • This study was carried out to evaluate the temporal, spatial, and seasonal variations of VOC, and to characterize the VOC concentrations in two large industrial complexes located in Pohang and Gumi cities. Twenty -four hours continuous sampling of selected VOC was made with STS 25 sequential tube samplers and double-bed adsorbent tubes. Air samples were collected every three hour interval for 7 consecutive days in each site during summer and winter. VOC were determined by thermal desorption coupled with GC/MS. A total of 27 VOCs of environmental concern were determined, including aliphatic, aromatic and halides. Generally. concentrations of toxic VOC were higher in Gumi than Pohang, and VOC levels in industrial areas were typically several-fold higher than those in residential areas. The most abundant VOC appeared to be toluene for both cities. However, chlorinated VOC were higher in Gumi than Pohang, while aromatic VOC were more abundant in Pohang than in Gumi. Two cities showed relatively different variations of VOC concentrations within a day. It is likely that traffic related sources are major factors affecting the VOC in Pohang, and industrial solvents usages are important sources in Gumi. These results imply that the occurrence and levels of atmospheric VOC are strongly dependent on the type of industries in each city. Therefore, in order to develop any control strategies or to establish the priority rankings for VOC in large industrial complexes, the type of industries and the occurrence of VOC in the atmosphere should be taken into consideration.

Expression pattern of floral scent genes in different flowering stages of Chrysanthemum cultivars

  • Mekapogu, Maniulatha;Ahn, Myung Suk;Yoo, Jong Hee;Jeong, Jae Ah;Park, Jong Taek;Kwon, Oh Keun
    • 한국자원식물학회:학술대회논문집
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    • 한국자원식물학회 2018년도 추계학술대회
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    • pp.114-114
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    • 2018
  • Among the various volatile organic compounds (VOCs) emitted by the plant, floral scent plays a key role in attracting pollinators for reproduction and mediates ecological interactions. Floral scent is an important trait and industry drives the competition for flowers with novel scents. Chrysanthemum is one of the well-known ornamental plants and is a popular cut flower across the world. Floral scent and the genes responsible for the floral scent emission are poorly studied in chrysanthemum. In the present study, floral scent and the expression pattern of floral scent genes were analyzed in two chrysanthemum cultivars 'Golden Egg' and 'Gaya Glory'. Initially, intensity of the floral scent in five developing stages of flower including 'budding (B), bud developing (BD), initial blooming (IB), almost open (AO) and open flower (OF)' was analyzed using electronic nose (E-nose) with six metal oxide sensors. Based on the distance analysis, different stages of flower showed different relative intensity of scent according to the sensory evaluation. Although the scent pattern differed by stage, scent intensity was strongest in the OF stage in the completely opened flower in both the cultivars. Further, expression pattern of six genes in the floral scent pathway including FDS, IDI, ISPH, TPS2, TPS5 and TPS6 was observed in all the five stages of the flower in both the cultivars. The expression pattern of all the six genes differed by stage and the terpene synthase genes TPS2, TPS5 and TPS6 showed good expression levels in the $5^{th}$ flower stage compared to other stages. This study provides a preliminary data for understanding the regulation of floral scent in chrysanthemum.

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도시녹지 유형에 따른 휘발성유기화합물 농도 특성 - 서울시 동대문구를 중심으로 - (Characteristics of Volatile Organic Compounds (VOCs) Concentration by Type of Urban Green Space - focused on Dongdaemun-gu, Seoul, Korea -)

  • 조예슬;박수진;노관평
    • 한국환경보건학회지
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    • 제44권4호
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    • pp.330-339
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    • 2018
  • Objectives: The occurrence characteristics of BTEXS and phytoncides were investigated by type of urban forest. Methods: Four types of urban green space (Hongneung Forest, Mt. Chunjang, residential park, and traffic island) and Gwangneung Forest were selected. Monitoring of phytoncides and BTEXS was conducted considering the activity times of urban residents (five times per day) using a Tenax TA tube and suction pump in June 2017 (one day). Results: Phytoncide concentrations were ranked as Gwangneung Forest>Hongneung Forest>Mt. Cheonjang>traffic island>residential park. Relatively high concentrations of phytoncides were also identified in the urban forest. There was no significant difference between Gwangneung Forest and the urban forest. BTEXS concentrations were ranked as traffic island>residential park>Hongneung Forest>Gwangneung Forest>Mt. Cheonjang. Traffic island and residential park showed high levels of BTEXS depending on the inflow of vehicles. The difference in concentration by time was significant for the traffic island in particular. Pollutant levels in Hongneung Forest were as low as in Gwangneung Forest. Conclusion: The concentrations of phytoncides and BTEXS were different by types of urban green space, and the potential for health and hygiene of urban forests were able to be investigated. This study is expected to provide as basic data for the creation of urban forest spaces in the future.

고정층 활성탄 흡착반응기에서 기상 톨루엔의 흡착특성 (Adsorption Characteristics of Toluene Vapor in Fixed-bed Activated Carbon Column)

  • 임진관;이송우;감상규;이동환;이민규
    • 한국환경과학회지
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    • 제14권1호
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    • pp.61-69
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    • 2005
  • Adsorption characteristics of toluene vapor, which is one of important source of volatile organic compounds (VOCs), by activated carbon were investigated using a fixed bed adsorption column. The operating parameters such as breakthrough curve, adsorption capacity, mass transfer zone (MTZ), and length of unused bed (LUB) were studied. The experimental results showed that the breakthrough time decreased with increasing inlet toluene concentration and gas flow rate. MTZ and LUB increased with the increase of inlet concentration, gas flow rate, and particle size of activated carbon. The adsorption capacity increased with the increase of inlet toluene concentration, while it decreased with increasing particle size. However, it was kept at constant value regardless of the increase of gas flow rate. Adsorption isotherm of toluene vapor could be represented by the Freundlich adsorption equation fairly well. From the adsorption experiments using some VOC gases such as toluene, xylene, butyl acetate. butanol and acetone, it was also found that the adsorption capacity was higher in the case of gas with higher boiling point and lower vapor pressure.

센서 네트워크를 이용한 실내 공기질 관리 및 제어에 관한 연구 (A Study of Environment Monitoring System based on Sensor Network)

  • 김기태;김동일
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2010년도 추계학술대회
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    • pp.389-392
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    • 2010
  • 특수한 작업장이외의 주택실내나 일반 사무실 등에서의 공기오염 문제는 인간이 주거시설에 거주한 이례로 계속되어온 문제로서 그 대책이 시급하다. 쉽게 외부의 신선한 공기와 충분한 양의 환기로서 해결이 가능하나 사람이 계속해서 관리해 주기에는 불편한 상황이다. 네트워크상에서 센서 네트워크를 이용한다면 쉽게 관리 및 제어가 가능하다. 유비쿼터스 센서 네트워크는 부착된 태그와 센서로부터 사물 및 환경 정보를 감지, 저장, 가공, 전달하여 인간 생활에 폭넓게 활용되며, 환경오염에 대해서도 사람이 직접 측정 및 모니터링 하기 힘든 지역에 설치되어 활용되고 있다. 다른 네트워크에 비해 초소형, 저전력, 저비용으로 쉽게 구성 가능하기 때문에 꾸준히 연구되어지고 있으며 환경과 IT의 전략적 융합을 통한 그린 IT의 네트워크 접목 또한 중요한 연구분야로 조명되고 있다. 본 논문에서는 네트워크 기반하에 실내 공기질 관리를 구성하고 관리 및 제어하여 활용 방안에 대하여 제시한다.

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유비쿼터스 센서 네트워크 기반 환경 모니터링 시스템에 관한 연구 (A Study of Environment Monitoring System based on USN)

  • 최삼길;김기태;김동일
    • 한국정보통신학회논문지
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    • 제14권6호
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    • pp.1488-1492
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    • 2010
  • 유비쿼터스 센서 네트워크는 부착된 태그와 센서로부터 사물 및 환경 정보를 감지, 저장, 가공, 전달하여 인간 생활에 폭넓게 활용되며, 환경오염에 대해서도 사람이 직접 측정 및 모니터링 하기 힘든 지역에 설치되어 활용되고 있다. 기존 네트워크에 비해 초소형, 저전력, 저비용으로 쉽게 구성 가능하기 때문에 꾸준히 연구되어지고 있으며 환경과 IT의 전략적 융합을 통한 그린 IT의 네트워크 접목 또한 중요한 연구 분야로 조명되고 있다. 본 논문에서는 네트워크 기반하에 실내 공기질 관리 센싱 메커니즘 구성도를 구현하고 환경요소를 측정하여 향후 환경 모니터링 시스템의 활용방안을 제안한다.

오피스 건물의 실내 환경 실태 조사 (The Field Survey of Indoor Environment of the Office Building)

  • 양영권;강인성;정민희;문진우;박진철
    • KIEAE Journal
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    • 제16권3호
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    • pp.71-76
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    • 2016
  • Purpose: This study aimed at improving the indoor environment of the office building by measuring the indoor environment and conducting a survey. Method: The measurement was conducted from January 13 to March 16 in 2012, targeting 44 sites in same office building located in Seoul, South Korea. The lists of measurement such as dry-blub temperature, relative humidity, formaldehyde (HCHO), asbestos, carbon monoxide (CO), carbon dioxide (CO2), volatile organic compounds (VOCs) and particle pollution (PM10) were measured. In addition, illuminance which belongs to light environment and noise in sound[acoustical] environment were measured respectively. Result: The buildings showed overall pleasant conditions. In terms of the thermal, air, sound, and visual environment, each measurements were satisfied with the requirements in standard, within pleasant ranges, except several sites. However, the survey results were revealed that the office workers were mostly dissatisfied with their indoor environment. Given that the measured values were mostly within standards, the results of survey might have resulted from a compensation mentality biased toward the subjects in psychological terms.

Ecotoxicological effects of ballast water effluent teated by an electrolytic method on marine environment

  • Kim, Tae Won;Kim, Keun-Yong;Shon, Myung-Baek;Kim, Young-Soo;Lee, Ji Hyun;Moon, Chang Ho;Son, Min Ho
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권8호
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    • pp.1010-1020
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    • 2014
  • Ballast water effluent treated by an electrolytic method contains reactive chlorine species and disinfection by-products (DBPs). In this study, we conducted whole effluent toxicity (WET) testing and ecological risk assessment (ERA) to investigate its ecotoxicological effects on marine environment. WET testing was carried out for three marine pelagic organisms, i.e., diatom Skeletonema costatum, rotifer Brachionus plicatilis and fish Paralichthys olivaceus. The biological toxicity test revealed that S. costatum was the only organism that showed apparent toxicity to the effluent; it showed no observed effect concentration (NOEC), lowest observable effect concentration (LOEC) and effect concentration of 50% (EC50) values of 12.5%, 25.0% and 83.3%, respectively, at brackish water condition. In contrast, it showed insignificant toxicity at seawater condition. B. plicatilis and P. olivaceus also showed no toxicities to the effluent at the both salinity conditions. Meanwhile, chemical analysis revealed that the ballast water effluent contained total residual oxidants (TROs) below $0.03{\mu}g/L$ and a total of 20 DBPs including bromate, volatile halogenated organic compounds (VOCs), halogenated acetonitriles (HANs), halogenated acetic acids (HAAs) and chloropicrin. Based on ERA, the 20 DBPs were not considered to have persistency, bioaccumulation and toxicity (PBT) properties. Except monobromoacetic acid, the ratio of predicted environmental concentration (PEC) to predicted no effect concentration (PNEC) of the other 19 DBPs did not exceed 1. Thus, our results of WET testing and ERA indicated that the ballast water effluent treated by electrolysis and subsequently neutralization was considered to have no adverse impacts on marine environment.

lectrospinning Method 기반 CNF의 물성분석과 전기분해 공정에서 전극으로의 응용 (Electrospinning Method-based CNF Properties Analysis and Its Application to Electrode in Electrolysis Process)

  • 황인혁;최성열;이상현;이예환;이상문;김성철;김성수
    • 공업화학
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    • 제28권2호
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    • pp.257-262
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    • 2017
  • 본 연구에서는 electrospinning method의 공정변수를 다르게 하여 CNF (carbon nanofiber)를 제조하였다. 제조된 CNF의 섬유의 형태, 직경 등의 변화를 SEM 분석을 통해 관찰하였으며 인가전압, TCD (tip to collecor distance), 고분자 용액의 농도, 열처리 단계가 CNF 물성을 형성함에 있어 주요한 영향인자임을 확인하였다. 또한 서로 다른 물성으로 제조된 CNF를 전기분해 공정의 전극으로 적용하여 toluene의 제거 효율을 비교하였고, 이를 통해 anode 뿐만 아니라 cathode 역시 전기분해 효율에 직접적인 영향을 미침을 확인하였다.