• Title/Summary/Keyword: VOCs(Volatile Organic Compounds)

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Characteristics of TVOCs Emission Factors from Chemical and Natural Coating Materials (화학 및 천연페인트에서 발생되는 TVOCs의 방출강도 특성 연구)

  • Kim Shin Do;Kim Jeong Ho;Park Jin Soo;Lee Jeong Joo
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.487-492
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    • 2004
  • Building materials are composed of very complex chemical compounds, and these indoor building materials discharge very much Volatile Organic Compounds(VOCs). We performed the environmental chamber test to investigate the Total VOCs(TVOCs) emission characteristics and emission factors about chemical and natural coating materials. As the result, we concluded that TVOCs emission are high at initial time and decreased in course of time. Natural paint was low emission level for TVOCs than chemical paint by small chamber test. The TVOCs emission factor-time profile showed a good fit with the results from the measured and predicted value.

The Temporal and Spatial Distribution of Volatile Organic Compounds(VOCs) in the Urban Residential Atmosphere of Seoul, Korea

  • Anthwal, Ashish;Park, Chan-Goo;Jung, Kweon;Kim, Min-Young;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.42-54
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    • 2010
  • Automobile emissions have caused a major hydrocarbon pollution problem in the ambient air of many cities around the world. This study was conducted to measure the pollution status of volatile organic compounds (VOCs) in some urban residential areas in Seoul, Korea. A total of 20 VOCs (11 aromatic and 9 chlorinated species) were identified at 4 urban residential sites in Seoul, Korea from February 2009 to July 2009. Comparison of total VOC (TVOC) concentration data indicated the dominance of the aromatic species with the maximum (72.2 ppbC) at Jong Ro (JR) and the minimum at Yang Jae (33.4 ppbC). The peak concentration of TVOC occurred during spring at all sites with an exception at Gang Seo (GS), where it was recorded during winter. The distribution of individual VOCs at the study sites was characterized by high toluene concentration. A strong correlation of benzene was also observed with other VOCs and criteria pollutants at all sites (except YJ). The overall results of this study suggest that vehicular emissions have greatly contributed to the increase in VOC pollution at all the study sites.

Heat Effects for the Volatile Organic Compounds emitted from Garlic and Kimchee (열처리가 마늘과 김치에서 발생되는 휘발성 유기화합물에 미치는 영향)

  • 김병순;양성봉
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.615-622
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    • 1998
  • The volatile organic compounds(VOCs) emitted from raw garlic and Kimchee were analyzed with thermal desorption or purge & trap/gas chromatography/mass selective detection method. Very offensive compounds such as methyl allyl sulfide, dimethyl sulfide, dimethyl disulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide and dimethyl trisulfide were detected, and among them, dimethyl disulfide and dimethyl trisulfide were confirmed to be generated during the precocity of Kimchee or emitted from the stuff of Kimchee other than the garlic. Malodorous compounds emitted from the garlic or Kimchee were detected in the breath of a Korean and the refregirator keeping Kimchee. It was confirmed that the disufides emitted from the garlic or Kimchee were major components of offensive odor in the alveolar air and the refregirator. It was clarfied that heat process is very effective to reduce odorous VOCs in garlic or Kimchee.

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Characterization and Assessment of Indoor Air Quality in Newly Constructed Apartments -Volatile Organic Compounds and Formaldehyde- (신축공동주택의 실내공기질 특성 및 평가 -휘발성 유기화합물 및 포름알데히드 중심으로-)

  • Sim, Sang-Hyo;Kim, Yoon-Shin
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.275-281
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    • 2006
  • Indoor air quality is the dominant contributor to total personal exposure because most people spend a majority of their time indoors. Especially exposure to indoor air can potentially pose a greater threat than exposure to ambient air when indoor environments have sources of contaminants. In this study, volatile organic compounds (VOCs) and formaldehyde (HCHO) within newly constructed apartment have been determined in 27 houses of apartment in Seoul from December 2004 to March 2005. The measured indoor air pollutants were HCHO, volatile organic compounds including benzene, toluene, styrene, xylene, ethylbenzene and sampled on the standard method of Ministry of Environment in Korea. The indoor levels for benzene, xylene, toluene, ethylbenzene, styrene, and HCHO have significant increase trend after 5 hours closing of windows and doors. Levels of measured air pollutants concentrations between living rooms and bedrooms have not shown significant difference. Spearman correlation coefficient among the measured air pollutants ranged from 0.303 to 0.946, indicating similar source in building materials.

Adsorption of volatile organic compounds using activated carbon fiber filter in the automobiles

  • Moon, Hyung Suk;Kim, In Soo;Kang, Sin Jae;Ryu, Seung Kon
    • Carbon letters
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    • v.15 no.3
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    • pp.203-209
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    • 2014
  • The adsorption of volatile organic compounds (VOCs) was carried out using an activated carbon fiber (ACF) filter in an automobile. The adsorption capacities of formaldehyde, toluene, and benzene on an ACF filter were far better than those of a polypropylene (PP) mat filter and combined (PP+activated carbon) mat filter by batch adsorption in a gas bag. In a continuous flow of air containing toluene vapor through an ACF packed bed, the breakpoint time was very long, the length of the unused bed was short, and sharp "S" -type breakthrough curve was plotted soon after breakpoint, showing a narrow mass transfer zone of toluene on the ACF. The adsorption amount of toluene on the ACF filter was proportional to the specific surface area of the ACF; however, the development of mesopores 2-5 nm in size on the ACF was very effective with regard to the adsorption of toluene. The ACF air clarifier filter is strongly recommended to remove VOCs in newly produced automobiles.

Concentrations of $C_2$~$C_9$ Volatile Organic Compounds in Ambient Air in Seoul (서울 대기 중에서 $C_2$~$C_9$ 휘발성 유기화합물의 농도)

  • Na, Gwang-Sam;Kim, Yong-Pyo;Kim, Yeong-Seong
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.95-106
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    • 1998
  • Volatile organic compounds (VOCs) from Ca to C9 were investigated with nine ambient air samples collected in April 26, August 17, 1996 and January 23, 1997 in a Seoul site. On each sampling day, three 2-hr integrated canister samples were collected in early morning, early afternoon and late afternoon, respectively to study temporal . variation of VOCs. Most of VOC species showed diurnal variation with higher concentrations in the early morning and lower concentrations in the afternoon. The concentrations of light alkanes were high, probably due to the emission from liquefied petroleum gas (LPG) and evaporation of gasoline. Especially, the concentration of propane was the highest in the morning samples. The concentrations of propane, ethylene, acetylene, and toluene were prominent in their hydrocarbon groups, respectively. These components were the main source of car exhaust, gasoline evaporization, LPG, or solvent usage.

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A Study on Indoor Air Pollutants Reduction Effect by Plants per Season (식물에 의한 계절별 실내공기오염물질 저감효과에 관한 연구)

  • Song, Jeong Eun;Kim, Yong Shik;Sohn, Jang Yeul
    • KIEAE Journal
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    • v.8 no.1
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    • pp.25-30
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    • 2008
  • This study aims at examining the reduction of indoor air contaminants by plants placed in an indoor space. The effect of reducing the concentration of air contaminants by three species of plants was studied in a full-scale mock-up model. Field measurements were performed using Aglaonema brevispathum, Pachira aquatica and Ficus benjamiana which were verified as air-purifying plants by NASA. Their positions and amount were controlled. Two conditions for the amount of plants(10%, 5%) and positions(sun-shine, scatter) were used in two separate rooms whose dimensions are identical. The concentration of Volatile Organic Compounds(VOCs) was monitored three hours after the plants were placed and three days after the plants were placed. The variations of concentration of Benzene, Toluene, Etylbenzene, Xylene, Stylene and Formaldehyde, which are all known as the major elements of Volatile Organic Compounds were monitored. The more plants were used, the more a reduction of indoor air contaminants occurred. The effect of reducing the concentration of air contaminants increased when the amount of plants increased.

Estimation of Source Emission Rate on Volatile Organic Compounds and Formaldehyde Using Indoor Air Quality Modeling in New Apartment (실내공기질 모델을 이용한 신축공동주택의 VOCs 및 HCHO 배출량 추정)

  • Sim, Sang-Hyo;Kim, Yoon-Shin;Yang, Won-Ho
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.929-933
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    • 2006
  • Indoor air quality is the dominant contributor to total personal exposure because most people spend a majority of their time Indoors. Especially when indoor environments have sources of contaminants, exposure to in-door air can potentially pose a greater threat than exposure to ambient air. In this study, estimations of volatile organic compounds and formaldehyde omission rate in indoor environments of new apartments were carried out using mass balance model in indoor environment, because indoor air quality can be affected by source generation, outdoor air level, ventilation, decay by reaction, temperature, humidity, mixing condition and so on. Considering the estimated emission rate of volatile organic compounds and formaldehyde, it Is suggested that new apartment should be designed and constructed in the aspect of using construction materials to emit low hazardous air pollutants.

Quality Assurance and Quality Control method for Volatile Organic Compounds measured in the Photochemical Assessment Monitoring Station (광화학측정망에서 측정한 휘발성유기화합물의 정도관리 방법)

  • Shin, Hye-Jung;Kim, Jong-Choon;Kim, Yong-Pyo
    • Particle and aerosol research
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    • v.7 no.1
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    • pp.31-44
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    • 2011
  • The hourly volatile organic compounds(VOCs) concentrations between 2005 and 2008 at Bulgwang photochemical assessment monitoring station were investigated to establish a method for quality assurance and quality control(QA/QC) procedure. Systematic error, erratic error, and random error, which was manifested by outlier and highly fluctuated data, were checked and removed. About 17.3% of the raw data were excluded according to the proposed QA/QC procedure. After QA/QC, relative standard deviation for representing 15 species concentrations decreased from 94.7-548.0% to 63.4-125.8%, implying the QA/QC procedure is proper. For further evaluation about the adequacy of QA/QC procedure, principal components analysis(PCA) was carried out. When the data after QA/QC procedure was used for PCA, the extracted principal components were different from the result from the raw data and could logically explain the major emission sources(gasoline vapor, vehicle exhaust, and solvent usage). The QA/QC procedure based on the concept of errors is inferred to proper to be applied on VOCs. However, an additional QA/QC step considering the relationship between species in the atmosphere needs to be further considered.

Design Standard of Activated Carbon Vessel for the Intermittent Emission Sources of Volatile Organic Compounds (휘발성 유기화합물의 간헐적 배출원에 대한 활성탄 흡착 시스템 설계기준)

  • Lee, Si-Hyun;Lim, Jeong-Whan;Rhim, Young-Jun;Kim, Sang-Do;Woo, Kwang-Je;Son, Mi-Sook;Park, Hee-Jae;Seo, Man-Cheol;Ryu, Seung-Kon
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.250-260
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    • 2007
  • It was investigated that the emission characteristics of volatile organic compounds (VOCs) from small and medium companies located on industrial complexes in Metropolitan area. The emission characteristics are intermittent sources in which VOCs emissions are highly depends on the working condition. Optimized ventilation system to improve air quality in working area for the three typical companies were installed. Adsorption characteristics of major VOCs such as MEK, IPA, and toluene emitted front the companies were investigated for design of the activated carbon vessel as a VOCs control facility in each company. Concentration of total hydrocarbon and gas amounts needed to ventilation were also used as a design parameter. Mixed adsorbent to improve adsorption characteristics of problematic solvents like IPA and the design guideline of the activated carbon vessel have been suggested.