• Title/Summary/Keyword: VOC emission

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A Study on Volatile Organic Compounds(VOCs) and Formaldehyde(HCHO) Emission Characteristics from Furniture (가구에서 발생되는 VOCs와 Formaldehyde의 방출특성에 관한 연구)

  • 김신도;서병량;윤중섭
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.163-164
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    • 2001
  • 휘발성유기화합물(VOCs)과 포름알데히드(HCHO)의 발생원은 매우 다양할 뿐만아니라 주변환경과 인체에 미치는 영향이 매우 크다. VOCs와 포름알데히드의 발생원으로는 크게 인위적인 발생원, 자연적인 발생원, 실내에서의 발생원으로 구분할 수 있다. 현대인들의 하루생활 중 80%이상이 실내에서 이루어지고 있어 실내에서의 발생되는 오염물질에 대한 특성파악과 적절한 제어방안이 요구된다. VOCs와 포름알데히드의 발생원중에서 실내에서의 발생원으로는 여러 가지가 있으나, 신축건물과 리모델링에 사용되는 건축자재에서의 방출은 매우 크다고 할 수 있다. (중략)

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A Stochastic Analysis of VOC Emissions from the Distribution Process of the Gasoline

  • Han, Wha-Jin;Song, Yanghoon;Cho, Yongsung
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E4
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    • pp.163-168
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    • 2001
  • Estimating the emission rate of VOCs from a gasoline industry at national level can be a challenging take even though the estimation is mean-based. However, using the procedures in the US EPA AP-42 guidelines, it is possible to approximate the mean industry emission rate once enough data are available. However, this estimate can be misled in the sense that there exist many stochastic factors in the EPA\\`s estimation procedures and also throughout the marketing channels of gasoline industry. Addressing the stochasticity problem in EPA\\`s procedure is hard to tackle because the detailed data needed to execute the estimation are not usually available even from refiners. Instead, this research tries to stay focused on the second type of stochasticity issue, raised from the mean0based metrological and marketing practice data collected from the 4 major refiners. To do so emission raters from each marketing channels (8 marketing points by 3 transportation types and by storage facilities of 4 refiners) are estimated monthly, following AP-42 procedures and using Tank 4.0. Once these estimates are acquired, the distribution of VOC emission rate for each marketing channel of all 4 refiners is estimated through simulation method using @Risk. The mean-based emission rates are weighted by company quantities to estimate the emission rate from the whole gasoline industry. Simple economic implication is provided, based on the result. This study found that, on the mean-bases, about 0.66% of gasoline marketed are evaporated into air. Considering the stochasticity in the estimation, about 90% of simulation results fell into the range of 0.65 to 0.68%. For 90% chance, the estimated economic loss is $54.65 million to $57.17 million, not counting the cost caused by air quality degradation and associated health impact.

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Characteristics for VOCs and aldehydes emission rates from architectural flooring (건축용 바닥재로부터의 VOCs와 Aldehydes 방출 특성)

  • Jang, Seong-Ki;Kim, Mi-Hyun;Seo, Soo-Yun;Lee, Woo-Suk;Lim, Jun-Ho;Lim, Jeong-Yun
    • Analytical Science and Technology
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    • v.19 no.6
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    • pp.544-552
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    • 2006
  • Emission tests were carried out to investigate the characteristics of concentration according to flooring sort using small chamber method. The target Volatile Organic Compounds (VOC) included 27 individual compounds of environmental concern, which were determined by adsorption sampling and thermal desorption coupled with GC/MS method and by DNPH cartridge/HPLC method. The emission factor of Total Volatile Organic Compounds (TVOC) and Formaldehyde (HCHO) was detected $0.3mg/m^2{\cdot}h$ and $0.2mg/m^2{\cdot}h$ respectively, and the floorings of 37 (9 PVC Tile, 10 PVC Sheet, 18 Flooring) were satisfied emission standard. TVOC emission factor appeared in order of concentration of PVC Sheet, PVC Tile, and floor flooring, while HCHO was detected very high emission factor (as $0.4mg/m^2{\cdot}h$) at floor flooring above PVC series (as $0.001mg/m^2{\cdot}h$).

A Study on the Comparison of Biogenic VOC (BVOC) Emissions Estimates by BEIS and CORINAIR Methodologies (BEIS와 CORINAIR 산출방법에 의한 자연식생 VOC 배출량 산출 비교 연구)

  • Cho Kyu-Tak;Kim Jo-Chun;Hong Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.2
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    • pp.167-177
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    • 2006
  • In this study, a fundamental work for developing a biogenic Volatile Organic Compounds(BVOC) emission model in Korea has been carried out. Two different approaches, Biogenic Emission Inventory System(BEIS2) and CORINAIR Methodology(CORINAIR) were compared for estimating BVOC emissions. It was found that BEIS and CORINAIR showed very similar results each other BVOC emissions estimated by two different methods were about the same on a national and regional(provincial) scale. In case of monthly emissions the difference between BEIS and CORINAIR were larger than those on a national and regional(provincial) scale, especially in summer season(June, July and August). Although BEIS and CORINAIR are quite different techniques to correct the environmental conditions, they revealed similar results. Therefore, it is proven that both the methods are able to be applied to the estimation of the BVOC emissions in Korea.

The impact of corrosion on marine vapour recovery systems by VOC generated from ships

  • Choi, Yoo Youl;Lee, Seok Hee;Park, Jae-Cheul;Choi, Doo Jin;Yoon, Young Soo
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.52-58
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    • 2019
  • Marine emissions of Volatile Organic Compounds (VOCs) have received much attention because the International Maritime Organization (IMO) requires the installation of vapour emission control systems for the loading of crude oils or petroleum products onto ships. It was recently recognised that significant corrosion occurs inside these vapour emission control systems, which can cause severe clogging issues. In this study, we analysed the chemical composition of drain water sampled from currently operating systems to investigate the primary causes of corrosion in vapour recovery systems. Immersion and electrochemical tests were conducted under simulated conditions with various real drain water samples, and the impact of corrosion on the marine vapour recovery system was carefully investigated. Moreover, corrosion tests on alternative materials were conducted to begin identifying appropriate substitutes. Thermodynamic calculations showed the effects of environmental factors on the production of condensed sulphuric acid from VOC gas. A model of sulphuric acid formation and accumulation by the characteristics of VOC from crude oil and flue gas is suggested.

VOC/HAPs Emission Characteristics & Adsorption Evaluation for Paint Products in Busan Area (부산지역 페인트제조시설의 VOC/HAPs 배출특성 및 흡착능 평가)

  • Song, Bok-Joo;Lee, Seung-Min;Cho, Gab-Je;Cho, Jeong-Gu;You, Pyung-Jong;Kim, Gi-Gon
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.5
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    • pp.316-325
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    • 2012
  • In this study, we suggested adequate control technology by analyzing emission process and main chemical of VOC/HAPs generated from four paint factories in Busan area. And we estimated whether Kapok fiber, which is a natural material, can be commercially used for an absorbent by testing adsorption ability. As a result of this sturdy, above 60% of VOC/HAPs was volatilized and dispersed inside the working place without conducting control system of facilities during manufacturing paints. Concentration profile of VOC/HAPs, which is volatile naturally outside the factories, is surveyed above 70% at Toluene, Ethylbenzene, and Xylene. And a result of evaluation of odor attribution level about the component whose Odor Threshold is known, it is estimated that major cause material of A, B, C factories is Toluene and that of D factory is m/p-Xylene. And that result presented design arguments such as facilities specifications, activated carbon filling volume, and replace cycle of activated carbon as control technology. Also, that result presented emission process improvement such as adsorption of central-controlled ventilation device, installation of inlet flenge, and potable cleaning process. The rate of pollutant adsorption of Kapok fiber, which is natural material, is indicated about 91.9%, 66.7%. That result validated the possibility as replacement of activated carbon.

Measurement of VOC in the Ambient Air of a Small Scale Municipal Landfill Site -A Case Study at the Sampung-dong Landfill in Gyungsan City- (소규모 도시 생활폐기물 매립장 대기 중 VOC의 농도 측정 -경산시 삼풍동 매립장을 대상으로-)

  • 백성옥;김배갑;서영교
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.1
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    • pp.59-68
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    • 2004
  • In this study, we investigated the concentrations of volatile organic compounds (VOC) in the ambient air of a small scale municipal waste landfill site. Seasonal sampling was carried out simultaneously at two sites, i.e. one in the center of the landfill area, and the other at a boundary site. Among 38 target VOC, toluene appeared to be the most dominant compound, followed by benzene. and xylenes. The higher levels of BTX imply that paint -containing materials and/or organic solvents are the most significant sources of the VOC in the landfill environment. Seasonal variations for the samples collected at the landfill site indicated that the VOC concentrations tend to be higher in the spring and fall season and lower in the winter season. In addition, night- time concentrations appeared to be generally higher than day-time. Such daily variation might be due to more stabilized atmosphere during the night-time. Similar patterns were also found in samples collected at a boundary site. This study demonstrated that the municipal landfill, although it is small -scaled, could be an important emission source of atmospheric VOC, particularly in the vicinities of the landfill. Thus, an appropriate control strategy is required to prevent any undesirable secondary pollutions from the environmental sanitary facilities such as landfill.

Reduction of Lean VOC Emission by Reforming with a Rotating Arc Plasma and Combustion with a Turbulent Partially-Premixed Flame (난류 부분예혼합화염과 로테이팅 아크 플라즈마를 이용한 난연성 유증기의 연소처리)

  • Ahn, Taekook;Lee, Daehoon;Park, Sunho
    • Journal of the Korean Society of Combustion
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    • v.22 no.1
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    • pp.23-31
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    • 2017
  • Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

Study on Natural VOC Emission Rates and Characteristics Emitted from Larix Leptoleis (Sieb. et Zucc.) Gordon (낙엽송으로부터 배출되는 자연 VOC 배출속도 및 배출특성 연구)

  • Kim, Ki-Joon;Kim, Jo-Chun;Lim, Jun-Ho;SunWoo, Young;Park, Hyun-Ju;Cho, Kyu-Tak
    • Journal of Environmental Science International
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    • v.16 no.2
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    • pp.151-158
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    • 2007
  • In order to investigate the compositions and the emission rates of monoterpenes emitted from coniferous trees, those from Larix leptoleis (Sieb, et Zucc.) Gordon were measured. In spring and summer, the major monoterpenes were ${\alpha}-terpinene,\;{\alpha}-pinene$, myrcene; however, ${\alpha}-pinene\;and\;{\alpha}-terpinene$ were most abundant in fall. The total mean monoterpene emission rates were $0.455\;({\mu}gC/gdw/hr)$ during the whole period. The higher monoterpene emission rates were found in fall compared to those in spring and summer. In addition, the slopes (${\beta}\;value$) between emission rate and temperature were two times lower in fall than those in spring and summer. It was also found that Larix leptoleis (Sieb. et Zucc.) Cordon had lower monoterpene emission rates than P. densiflora and P. rigida.

A Study on Estimation of Air Pollutants Emission from Agricultural Waste Burning (농업잔재물 노천소각에 의한 대기오염물질 배출량 산출에 관한 연구)

  • Kim, Dong Young;Choi, Min-Ae;Han, Yong-Hee;Park, Sung-Kyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.2
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    • pp.167-175
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    • 2016
  • In this study, we estimate air pollutants emission from agricultural waste burning. We investigated activities related to agricultural waste burning such as crop burning rates, location, and time by region. The average crop burning rates per square meter farmland of fruits, pulses, barleys, cereals, vegetables, and special crops were $273.1g/m^2$, $105.7g/m^2$, $7.4g/m^2$, $121.0g/m^2$, $290.7g/m^2$, and $392.9g/m^2$, respectively. We estimated air pollutants emissions with pre-developed emission factors. The estimated air pollutant emission of agricultural biomass burning were CO 148,028 ton/year, $NO_x$ 5,220 ton/year, $SO_x$ 11 ton/year, VOC 59,767 ton/year, TSP 21,548 ton/year, $PM_{10}$ 8,909 ton/year, $PM_{2.5}$ 7,405 ton/year, and $NH_3$ 5 ton/year. When these results compared with the entire emissions of national inventory (CAPSS), CO, VOC, $PM_{10}$ account for about 17.8%, 6.2%, 6.7% of the total, respectively.