• Title/Summary/Keyword: VOC(volatile organic compound)

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Photodegradation of Volatile Organic Compound (VOC) Through V-Doped or CuOx-grafted $TiO_2$ nanoparticles

  • Kim, Beum Woo;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.271.1-271.1
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    • 2013
  • Titania is usually used in sun-screens, tooth paste, and other daily used objects as a pigment. However, scientists have focused on titania as photocatalyst due to its excellent activities. By fabricating vanadium doped TiO2 and CuOx co-catalyzed TiO2 nano-size filter, the degradation level of the volatile organic compound (VOC) concentration was tested using 365nm UV LED as light source in a closed chamber. Main purpose for this test is to evaluate the activities of various catalysts for degrading the VOCs which are detrimental to human body and toluene and p-xylene were chosen in the VOC removal test. Target gas materials were injected into the test chamber with dry air as carrier gas which was flowed into the gas washer bottle filled with liquid form of VOC substance. When the VOC gas flows into the chamber, it is circulated by 200 mm fan in order to contact with the set-up filter on the aluminum holder. Target gas concentration in the chamber was monitored using VOC detector (miniRae3000, Raesystems) which was also placed inside the chamber. With the measured concentration, the VOC degradation efficiency and the degradation rate were evaluated and used to compare the catalytic activities.

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Trends and Control Technologies of Volatile Organic Compound (국내의 휘발성유기화합물(VOC) 현황 및 관리기술)

  • Kim, Jo-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.743-757
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    • 2006
  • Volatile organic compound (VOC) has been well-known to Korea since the end of 1990's however, it has not been well documented until now. In this study, present ambient VOC levels, VOC emission sources, and VOC control technologies were reviewed and discussed. In addition, VOC management strategies to cut down ozone concentrations were suggested based on the present VOC database. For anthropogenic VOC reduction, VOC emitted from painting processes and automobiles should be controlled in the first place in large cities such as Seoul, Daegu, and Incheon. For natural VOC management, low emission trees need to be planted in those cities. It is also very significant to keep updating present and future VOC emission inventories for efficient VOC control strategies. As a conclusion, more systematic VOC control road-map based on BACT (best available control technology) needs to be made up. and more economical and efficient VOC control techniques have to be developed under strong national support in order to lower toxic VOC and photochemical oxidant levels.

Analysis of Higher Temporal Moments for Breakthrough Curves of Volatile Organic Compounds in Unsaturated Soil (불포화 토양에서 유동하는 가스상 Volatile Organic Compounds의 출현곡선에 대한 고차 Temporal Moment의 분석)

  • Kim, Heon-Ki
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.60-69
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    • 2007
  • Understanding the behavior of gas phase VOCs (volatile organic compounds) in unsaturated soils is of a great environmental importance for public health concerns. Moment analysis for the breakthrough curves (BTCs) during transport of chemicals in porous media was known to be a useful tool to evaluate the velocity, spreadness, and the skewness of the plume of the chemicals. In this study, the temporal moments of the BTCs of a group of VOCs were analyzed for the gaseous transport in an unsaturated soil. BTCs were measured using lab-scale column experiments for four different VOCs at the water saturation range of 0.04-0.46, and for eleven VOCs at a water saturation of 0.21. The central second and third moments of the VOCs were compared with the water saturation and the first moment. It was found that both central second and third moments increased with the first moment. The central third moment was, however, found to be more sensitive to the first moment.

A Numerical Analysis of the Abatement VOC in a Photocatalytic Micro-reactor (마이크로 광촉매 반응기의 VOC 제거에 관한 수치해석적 연구)

  • Youm, Min-Qou;Jeong, Jin;Kim, Chang-Nyung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.4
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    • pp.285-290
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    • 2007
  • This study has been numerically conducted to investigate the removal efficiency of Volatile Organic Compound (VOC) in photocatalytic micro-reactor. This study has placed emphasis on the improvements of the working condition of photocatalytic micro-reactor. The micro-reactor consists of 19 microchannels with a rectangular cross-section. For the validation of the current numerical study, a computation has been carried out to simulate an existing experimental study on the cylindrical reactor, which has shown a good agreement. The degradation characteristics with different inlet concentrations and velocities have been obtained. The current results can be used for the design of advanced photocatalytic micro-reactor.

Photodegradation of Volatile Organic Compound (VOC) Through Pure TiO2 and V-Doped TiO2 Coated Glasses

  • Moon, Jiyeon;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.425.2-425.2
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    • 2014
  • $TiO_2$ possesses great photocatalytic properties but absorbs only UV light owing to high band gap energy (Eg = 3.2 eV). By narrowing the band gap through doping a metal ion, the photocatalytic activity can be enhanced in condition of the light of a higher than 365 nm wavelength. Main purpose for this study is to evaluate the activities of metal doped $TiO_2$ for degrading the volatile organic compounds (VOCs); p-xylene is chosen in the VOC removal test. Vanadium is selected in this study because an ionic radius of vanadium is almost the same as titanium ion and vanadium can be easily doped into $TiO_2$. V-doped $TiO_2$ was synthesized by sol-gel methods and compared with pure $TiO_2$. Pure TiO2 powder and V-doped $TiO_2$ powder were coated on glasses by spray coating method. UV-Visible spectrophotometer was used for the measurement of the band gap changes. VOC concentration degradation level was tested with using various UV light sources in an enclosed chamber. Catalytic activities of prepared samples were evaluated based on the experimental results and compared with coated pure $TiO_2$ sample.

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Evaluation of Atmospheric Volatile Organic Compound Characteristics in Specific Areas in Korea Using Long-Term Monitoring Data

  • Jo, Wan-Kuen;Chun, Ho-Hwan;Lee, Sang-Ok
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.103-110
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    • 2012
  • This study was performed mainly to examine whether a city with a metal industrial presence presents different characteristics in ambient volatile organic compound (VOC) concentrations compared to residential (RES) and commercial/residential combined (CRC) areas of another city by using long-term monitoring data (from January 2006 to February 2009). For most target VOCs, ambient concentrations in the metal-industrialized city were lower than for the RES and CRC areas. Aromatic compounds were the predominant VOC groups for the metal industry city as well as for other land uses. The ambient concentrations of aromatic VOCs were higher in the winter and spring seasons than in the summer and fall seasons, whereas those of chlorinated VOCs did not show any distinctive variations. In addition, higher concentrations were observed during daytime hours. The correlations between the ambient target compounds were statistically significant, except for the correlation between benzene and ozone.

A Trend of VOC(Volatile Organic Compound) Control and Patent Analysis on the VOC Control Technical (국내의 VOC 제거 및 회수에 대한 연구동향 및 특허분석)

  • Kim, Pilh-Hwan;Hua, Jin-Mei;Lee, Byung-Ho;Jeong, Hyo-Min;Chung, Han-Shik
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.132-135
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    • 2007
  • VOCs(Volatile Organic Compounds) have been recently enacted by several regulations to the environment since the end of 1990's. So, it need to control emissions of VOCs from industrial cite. VOC controls include all technologies which either collect the VOCs for recovery and reuse or destroy the VOCs. In this study, the VOC control technical trend was searched. Additionally, it was compared to the number of patent along to the year in Korea.

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Principle and Commercialization of Biofilter for Treatment of Volatile Organic Compounds (VOC 처리를 위한 Biofilter 개발 원리 및 상업화)

  • Lee E. Y.;Hwang J. W.;Kang Y. S.;Moon C. H.;Park S.
    • 한국생물공학회:학술대회논문집
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    • 2004.07a
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    • pp.85-106
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    • 2004
  • Styrene as volatile organic compounds(VOC) has come under strict regulatory control as they cause serious health and environmental problems. Biofiltration offers a number of economical and environmental advantages over conventional technologies, such as incineration, catalytic adsorption, and chemical scrubbing. In this presentation, recent progresses on the development of lab-scale biofilter for the treatment of gas-phase styrene are reviewed, The potentials of commercialization of biofilter systems are also discussed.

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A Study on Concentration Change of Volatile Organic Compounds; VOCs by using Mock-up Test (실물실험을 통한 개별 VOC의 농도변화에 관한 연구)

  • Kim Chang-Nam;Lee Yun-Gyu
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.5
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    • pp.487-495
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    • 2005
  • Recently, due to the airtightness of buildings or the misuse of building materials, we have been witness SHS (Sick House Syndrome) which can have bad influences on the resident in an existing apartment house as well as newly constructed apartment house start to attract public attention. As a result of this situation, we went to restrict the TVOC (Total Volatile Organic Compound) and formaldehyde. But these guidelines concentrated on only TVOC although TVOC are consist of many individual VOC. Therefore, in this study, we will look about concentration change of VOCs (Volatile Organic Compounds) by using Mock-up test. As result of test, the concentration of four individual VOC (Benzene, Toluene, Ethylbenzene, Styrene) showed quitely low level after 7 days. On the other hand the concentration of Xylene and formaldehyde showed low level after 14 days.