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Amorphous silicon thin-film solar cells with high open circuit voltage by using textured ZnO:Al front TCO (ZnO:Al 투명전도막을 이용한 높은 개방전압을 갖는 비정질 실리콘 박막 태양전지 제조)

  • Lee, Jeeong-Chul;Ahn, Se-Hin;Yun, Jae-Ho;Song, Jin-Soo;Yoon, Kyung-Hoon
    • New & Renewable Energy
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    • v.2 no.3
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    • pp.31-36
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    • 2006
  • Superstrate pin amorphous silicon thin-film(a-Si:H) solar cells are prepared on $SnO_2:F$ and ZnO:Al transparent conducting oxides(TCO) in order to see the effect of TCO/p-layers on a-Si:H solar cell operation. The solar cells prepared on textured ZnO:Al have higher open circuit voltage VOC than cells prepared on $SnO_2:F$. Presence of thin microcrystalline p-type silicon layer(${\mu}c-Si:H$) between ZnO:Al and p a-SiC:H plays a major role by causing improvement in fill factor as well as $V_{OC}$ of a-Si:H solar cells prepared on ZnO:Al TCO. Without any treatment of pi interface, we could obtain high $V_{OC}$ of 994mV while keeping fill factor(72.7%) and short circuit current density $J_{SC}$ at the same level as for the cells on $SnO_2:F$ TCO. This high $V_{OC}$ value can be attributed to modification in the current transport in this region due to creation of a potential barrier.

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Real-time Control of Biological Animal Wastewater Treatment Process and Stability of Control Parameters (생물학적 축산폐수 처리공정의 자동제어 방법 및 제어 인자의 안정성)

  • Kim, W.Y.;Jung, J.H.;Ra, C.S.
    • Journal of Animal Science and Technology
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    • v.46 no.2
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    • pp.251-260
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    • 2004
  • The feasibility and stability of ORP, pH(mV) and DO as a real-time control parameter for SBR process were evaluated in this study. During operation, NBP(nitrogen break point) and NKP(nitrate knee point), which reveal the biological and chemical changes of pollutants, were clearly observed on ORP and pH(mV)-time profiles, and those control points were easily detected by tracking the moving slope changes(MSC). However, when balance of aeration rate to loading rate, or to OUR(oxygen uptake rate), was not optimally maintained, either false NBP was occurred on ORP and DO curves before the appearance of real NBP or specific NBP feature was disappeared on ORP curve. Under that condition, however, very distinct NBP was found on pH(mV)-time profile, and stable detection of that point was feasible by tracking MSC. These results might mean that pH(mV) is superior real-time control parameter for aerobic process than ORP and DO. Meanwhile, as a real-time control parameter for anoxic process, ORP was very stable and more useful parameter than others. Based on these results, a stable real-time control of process can be achieved by using the ORP and pH(mv) parameters in combination rather than using separately. A complete removal of pollutants could be always ensured with this real-time control technology, despite the variations of wastewater and operation condition, as well as an optimization of treatment time and capacity could be feasible.

Antioxidant and Cytoprotective Activity of the Olive Leaf (Olea europaea L. var. Kalamata) Extracts on the Mouse Embryonic Fibroblast Cell

  • Ha, Ju-Yeon;Goo, Sun-Young;Sung, Jung-Suk;Shin, Han-Seung
    • Food Science and Biotechnology
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    • v.18 no.4
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    • pp.965-970
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    • 2009
  • Oleuropein content of olive leaf extracts (OLE; ethanol extract) was evaluated by high performance liquid chromatography analysis. Oleuropein contents were $4.21{\pm}0.57$, $3.92{\pm}0.43$, $0.32{\pm}0.03$, $5.76{\pm}0.32$, and $32.47{\pm}0.25$ mg/100 g for ethanol extract, and hexane, chloroform, ethyl acetate, and butanol fraction, respectively. The removal of DPPH free radical increased in OLE and all 5 fractions of OLE in a concentration dependent manner. In order to investigate the antioxidant effect of OLE in vitro, 80%(v/v) ethanol OLE, $H_2O_2$, or combined treatment of 80%(v/v) ethanol OLE and $H_2O_2$ were applied on mouse embryonic fibroblast (MEF) cells. Cells were damaged by oxidative stress decreased their viability followed by increasing concentration of $H_2O_2$, but co-treatment of OLE and $H_2O_2$ showed an increase in cell growth about 20% compare to the cells treated with $H_2O_2$. OLE suppresses cytotoxicity induced by $H_2O_2$ in dose dependent manner. OLE treatment on MEF cells was also examined by analyzing cell cycle and apoptotic rate using flow cytometry. Apoptotic and necrotic cell accumulation was decreased in addition of OLE to $H_2O_2$ compare to the oxidative damaged cells. Taken together, these results demonstrated that OLE suppresses cytotoxicity induced by $H_2O_2$ and protect cells against oxidative stress on MEF cells.

PANCYCLIC ARCS IN HAMILTONIAN CYCLES OF HYPERTOURNAMENTS

  • Guo, Yubao;Surmacs, Michel
    • Journal of the Korean Mathematical Society
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    • v.51 no.6
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    • pp.1141-1154
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    • 2014
  • A k-hypertournament H on n vertices, where $2{\leq}k{\leq}n$, is a pair H = (V,A), where V is the vertex set of H and A is a set of k-tuples of vertices, called arcs, such that for all subsets $S{\subseteq}V$ with |S| = k, A contains exactly one permutation of S as an arc. Recently, Li et al. showed that any strong k-hypertournament H on n vertices, where $3{\leq}k{\leq}n-2$, is vertex-pancyclic, an extension of Moon's theorem for tournaments. In this paper, we prove the following generalization of another of Moon's theorems: If H is a strong k-hypertournament on n vertices, where $3{\leq}k{\leq}n-2$, and C is a Hamiltonian cycle in H, then C contains at least three pancyclic arcs.

H/V Spectral-ratio Analysis of Microtremors in Jeju Island (제주도 상시미동의 H/V 스펙트럼비 분석)

  • Hong, Myung-Ho;Kim, Ki-Young
    • Geophysics and Geophysical Exploration
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    • v.13 no.2
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    • pp.144-152
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    • 2010
  • To study the thickness variation of volcanic rocks of Jeju Island, microtremor data were recorded at eight and four sites using short-period and broadband seismometers, respectively, for 30 ~ 60 minutes with a 100 Hz sampling rate. During the daytime, these records show increased cultural noise at frequencies above 1.8 Hz. Natural noise occurs in the frequency range of 0.4 to 0.8 Hz in both daytime and nighttime data. Predominant frequencies determined by the H/V spectral-ratio method are in the range of 0.2 ~ 0.7 Hz. These frequencies decrease gradually as the central part of the Mt. Halla is approached. This may indicate that the basement is warped downward beneath the center of the island, which is consistent with previous gravimetric and magnetic models. Assuming an average shear-wave velocity of 1,800 m/s for the overburden basalts, the depths to basement are estimated to be between 640 and 2,140 m.

Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (Ⅳ). Oxotrichlorobis(substituted pyridine) molybdenum (Ⅴ) (몰리브덴의 피리딘계 착물합성과 그 성질 (제4보) 옥소삼클로로비스(치환피리딘)몰리브덴 (V))

  • Chang Su Kim;Sang Oh Oh
    • Journal of the Korean Chemical Society
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    • v.26 no.6
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    • pp.378-382
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    • 1982
  • Green crystalline salts of substituted pyridinium oxopentachloromolybdates(V) were obtained from concentrated hydrochloric acid solution of molybdenum(V)-thiocyanate extract. $MoOCl_3(X-py)_2$ (X-py were 4-and 3-cyanopyridine, 2-amino-4-picoline and 4-acetylpyridine) were obtained by reflux of the corresponding substituted pyridinium salts of oxopentachloromolybdates(Ⅴ) in absolute ethanol. ($X-pyH_2$)[$MoOCl_5$]$H_2$O containing the $MoO^{3+}$ group are dissolved and hydrolysed in water but $MoOCl_3(X-py)_2$ are insoluble in water, alcohol and acetone. The complexes are paramagnetic compounds.

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Effects of Ventilation Types on Interior Environment of the Enclosed Farrowing-Nursery Pig House (무창 분만 ${\cdot}$ 자돈사 환기 형태가 돈사내 환경에 미치는 영향)

  • Yoo, Y.H.;Song, J.I.;Kang, H.S.;Jeon, B.S.;Kim, T.I.;Kim, H.H.
    • Journal of Animal Environmental Science
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    • v.8 no.2
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    • pp.79-86
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    • 2002
  • This study was conducted to collect basic data about the effects of ventilation types on the interior environment of the enclosed farrowing-nursery pig house in Anseong, Icheon and Jeungpyong. Surveyed ventilation types in the enclosed farrowing-nursery pig house are classified in to 4 types. In V1 type, air enters through a planar slot inlet placed on the juncture of the entering wall and exit through the chimney fan outlet; in V2 type, air enters through a perforated ceiling inlet and exits chimney fan outlet(V2); in V3 type, air enters through a circular duct inlet and exit chimney fan outlet(V3); in V4 type, enters through a circular duct inlet and exits side wall exhaust fan outlet(V4). Temperature, relative humidity, air velocity and ammonia concentration($NH_3$) were measured in the interior of swine building in the summer. Interior temperature was not remarkably different in all ventilation types in this study. However, temperature of the V4 was somewhat lower than that of the other types. Air velocity of the V4 was higher and $NH_3$ concentration of the V4 was lower than those of other ventilation types. It is suggested that the V4 ventilation type be applicable in the enclosed farrowing-nursery pig house in Korea.

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The Study on the Separation of the Subsidiary Elements in Iron and Steel by Using Ion Exchangers (II). The Separation of Anions (이온 교환수지에 의한 철 및 강의 분석에 관한 연구 (제2보). 음이온 성분의 분리)

  • Byoung-Cho Lee;Myon-Yong Park;Kee-Chae Park
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.428-433
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    • 1973
  • The quantitative separations of a mixture containing equal amount of each anion such as Si(IV), As(V), P(V), S(VI), W(VI) and Cr(VI) are carried out by the elution through 20${\times}3.14cm^2$ column of anion exchange resin, Dowex 1${\times}$8. The eluents are a mixture of 0.07 M hydrochloric acid and 0.03 M sodium chloride (pH = 1.30) for Si(IV), As(V) and P(V) species, a mixture of 0.6 M sodium chloride and 0.3 M sodium hydroxide for S(VI), W(VI) and Cr(VI) species, and 0.1 N sodium sulfite (pH = 3.48) for P(V) and As(V) species. The subsidiary anions in a standard mixture such as Si(IV), As(V), S(VI), P(V) and W(VI) are separated together from large amount of Fe(III) by the elution through 30cm${\times}3.14cm^2$ column of the resin, Dowex${\times}$50w${\times}$12, using a mixture of 0.1 M sodium nitrate and 2 percent dimethylsulfoxide aqueous solution as an eluent. Si(IV), As(V), S(VI), P(V) and W(VI) eluted together are separated quantitatively under the same conditions as in the separations of the anion mixture. By the conditions obtained in the separations of the standard mixture, Fe(III) and all of the subsidiary anions in steel are quantitatively separated.

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Reasonable Design Method of Vertical Drain Depending on the Depth of Soft Ground (연약지반의 심도에 따른 연직 배수재의 합리적 설계 방안)

  • Lim, Chang-Su;Lee, Dal-Won
    • Korean Journal of Agricultural Science
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    • v.28 no.2
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    • pp.108-115
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    • 2001
  • In this study, to propose the reasonable evaluation method of degree of consolidation considering the depth of soft ground, the two soft ground areas were chosen and analyzed for the consolidation degree. One was a western coast area in which depth of soft ground was low, and the other was a southern coast area in which depth of soft ground was deep. At the area in which depth of soft ground was low, Barron's and Yoshikuni's methods showed that the evaluation of consolidation degree was large, and it is reasonable that $C_h=C_v$ be recommended to apply the Hansbo's and the Onoue's methods. At the area in which depth of soft ground was deep, it is reasonable that $C_h=C_v$ be recommended to apply the Barron's and the Yoshikuni's methods, and $C_h=(2{\sim}3)C_v$ to apply the Hansbo's and the Onoue's methods. According to the Hansbo's and Onoue's methods, degree of consolidation proved to be applicable with measured data when using the $k_s=(1/3)k_v$ at the area which depth of soft ground was low and using the $k_s=(1{\sim}1/2)k_v$ at the area which depth of soft ground was deep. According to the Hansbo's and Onoue's methods, degree of consolidation was proved to be applicable with measured data when using ds=(3~5)dm at the area which depth of soft ground was low and using ds=2dm at the area which depth of soft ground was deep.

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Kinetics for Mononuclear Heterocyclic Rearrangement of N-(5-phenyl-1,2,4-oxadiazol-3-yl)-N'-arylformamidine (I) (N-(5-phenyl-1,2,4-Oxadiazol-3-yl)-N'-arylformamidine의 Mononuclear Heterocyclic Rearrangement반응에 대한 반응속도론 (제1보))

  • Jung Ui Hwang;Jong Jae Chung;Young Zoo Youn
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.301-310
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    • 1988
  • Reaction rates for mononuclear heterocyclic rearrangement of N-(5-phenyl-1,2,4-oxadiazol-3-yl)-N'-arylformamidines into 3-acylamino-1-aryl-1,2,4-triazoles were determined spectrophotometrically in dioxane/water (50 : 50, v/v). There are two different reaction paths according to pH. One is pH-independent path, the other is pH-dependent one. In pH-independent path, the result of substituent effect by IYT equation show that N-H bond breaking as well as new N-N bond formation controls the reaction rate. In pH-dependent path, concave-upward Hammett plot was observed. It can be concluded that new N-N bond formation is more advanced than N-H bond breaking in transition state for electron-donating substituents, but N-H bond breaking is more advanced than new N-N bond formation for electron-withdrawing substituents.

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