• Title/Summary/Keyword: V2C

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Synthesis and Characterization of Vanadium(Ⅲ) Complexes with N, P, O-donating Ligands(Ⅱ) (질소, 산소, 인 주개 리간드를 갖는 바나듐(Ⅲ) 착물의 합성과 특성 (제 2 보))

  • Oh Sang-Oh;Lyou Eun-Young
    • Journal of the Korean Chemical Society
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    • v.37 no.6
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    • pp.612-617
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    • 1993
  • Some vanadium(III) complexes have been prepared from the reaction of VC$l_3$ with N, P, O-donating ligands and characterized by elemental analysis, $^1$H-NMR infrared and UV-Visible spectroscopy. 3,5-Lutidine, 1,2-phenylenediamine, 8-hydroxyquinoline, 9,10-phenanthrenequinone, triphenylphosphine, 1,2-bis(diphenylphosphino)ethane, 1,3-bis(diphenylphosphino)propane and 1,1'-bis(diphenylphosphino)ferrocene were chosen as coordinating ligands. Stretching frequency ${\nu}g$(V-Cl) of complexes appears) at 298∼367 cm-1, which show octahedral geometries. Stretching frequency of ${\nu}g$(V-X) (X = N, P, O) indicates that ligands are coordinated to vanadium(III). Stretching frequency ${\nu}g(C{\equiv}N)$ of acetonitrile in these complexes are characteristically shifted to about 70 c$m^{-1}$ higher compared with that of a free ligand (2260 c$m^{-1}$). Bending frequency of $\delta(C{\equiv}N)$ is also shifted to about 60 c$m^{-1}$ higher compared with that of a free ligand (377 c$m^{-1}$). Finally each vanadium(III) complex showed the following formulation; [VC$l_3$(L)$_2$MeCN] or [VC$l_3$(L-L)MeCN].

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Effects of Sugar and Yeast Addition on Red Wine Fermentation Using Campbell Early (가당 및 효모첨가가 Campbell Early 포도주 발효에 미치는 영향)

  • Kim, Jae-Sik;Kim, Sung-Hee;Han, Jung-Sun;Yoon, Byung-Tae;Yook, Cheol
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.516-521
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    • 1999
  • The average sugar content and total acidity (tartaric acid %) in Campbell Early harvested at Youngdong, Chungbuk in 1998 were $11{\sim}16^{\circ}Brix\;and\;0.7{\sim}1.1%$, respectively. Extra sugar should be added to musts to have higher than 12% of alcohol content for red wine fermentation. When extra sugar and active dry yeast were added to Campbell Early must, wine fermentation was ended after 9 days at $25^{\circ}C$. The ethanol content was 14.7% (v/v). However, when sugar was added only without yeast, wine fermentation was ended up at 14. 4% (v/v) of ethanol after 15 days. The total acidity (tartaric acid %) and pH was almost unchanged during both fermentations. Potassium metabisulfite was found to inhibit the propagation of bacteria without affecting red wine fermentation. But when potassium metabisulfite was directly added to young red wine after fermentation, the red color of wine was decolorized to yellow.

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Fabrication and characterization of the SiGe HBTs using an RPCVD (RPCVD를 이용한 실리콘 게르마늄 이종 접합 바이폴라 트랜지스터 제작 및 특성 분석)

  • 한태현;서광열
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.823-829
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    • 2004
  • In this paper, non-self-aligned SiGe HBTs with ${f}_\tau$ and${f}_max $above 50 GHz have been fabricated using an RPCVD(Reduced Pressure Chemical Vapor Deposition) system for wireless applications. In the proposed structure, in-situ boron doped selective epitaxial growth(BDSEG) and TiSi$_2$ were used for the base electrode to reduce base resistance and in-situ phosphorus doped polysilicon was used for the emitter electrode to reduce emitter resistance. SiGe base profiles and collector design methodology to increase ${f}_\tau$ and${f}_max $ are discussed in detail. Two SiGe HBTs with the collector-emitter breakdown voltages ${BV}_CEO$ of 3 V and 6 V were fabricated using SIC(selective ion-implanted collector) implantation. Fabricated SiGe HBTs have a current gain of 265 ∼ 285 and Early voltage of 102 ∼ 120 V, respectively. For the $1\times{8}_\mu{m}^2$ emitter, a SiGe HBT with ${BV}_CEO$= 6 V shows a cut-off frequency, ${f}_\tau$of 24.3 GHz and a maximum oscillation frequency, ${f}_max $of 47.6 GHz at $I_c$of 3.7 mA and$V_CE$ of 4 V. A SiGe HBT with ${BV}_CEO$ = 3 V shows ${f}_\tau$of 50.8 GHz and ${f}_max $ of 52.2 GHz at $I_c$ of 14.7 mA and $V_CE$ of 2 V.

Measurement of Energy Dependent Differential Neutron Capture Cross-section of Natural Sm by Using a Continuous Neutron Flux below (연속에너지 중성자에 대한 천연 Sm의 중성자 포획단면적 측정)

  • Yoon, Jungran
    • Journal of the Korean Society of Radiology
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    • v.10 no.5
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    • pp.337-341
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    • 2016
  • We measured the neutron capture cross-section of natural Sm(n,${\gamma}$) reaction in the energy regions from 0.003 to 10 eV. The 46-MeV electron linear accelerator of Research Reactor Institute, Kyoto University was used for generating a continuous neutron source. The neutron time-of-flight method was adopted for energy measurement. An assembly of BGO($Bi_4Ge_3O_{12}$) scintillators composed of 12 pieces of BGO crystals measured prompt gamma rays from Sm(n,${\gamma}$) reaction. The BGO assembly was located at a distance of $12.7{\pm}0.02m$ from the neutron source. In order to determine the neutron flux impinging on the Sm, the $^{10}B(n,{\alpha}{\gamma})^7Li$ standard cross-section were used. Natural Sm(n,${\gamma}$) reaction measurement result of the neutron capture cross-section was compared with the results of evaluation of the BROND-2.2 and the previous experimental data of J. C. Chou and V. N. Kononov.

Production of Agarooligosaccharides using of Agarase from marine Bacterium Bacillus cereus ASK202 (해양세균 Bacillus cereus ASK202가 생산하는 Agarase를 이용한 Agarooligosaccharides의 생산)

  • 김봉조;하순득;임동중;송창문;공재열
    • KSBB Journal
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    • v.13 no.5
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    • pp.524-529
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    • 1998
  • An agarase was partially purified from the culture broth of marine bacterium Bacillus cereus ASK202. Optimal pH and temperature of this agarase were found to be 7.0 and 40$^{\circ}C$, respectively. The maximum productivity of agarooligosaccharides was obtained from 0.3 %(w/v) agar by using of 1 unit agarase. As the results of TLC and HPLC analysis, these oilgosaccharides consisted of neoagarobiose, neoagarotetraose and neoagarohexaose. Under the optimal reaction conditions, 77.5 %(w/v) neoagarobiose and 6.2 %(w/v) neoagarotetraose were produced from agar and the conversion yield of total agarooligosaccharides was 83.7 %(w/v) after for 2 h reaction at 40$^{\circ}C$.

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Design of a CMOS DC-to-DC Converter for Portable Devices (휴대용 기기를 위한 CMOS DC-DC 변환기 설계)

  • O, N.G.;Lee, J.K.;Cho, I.H.;Jang, S.H.;Cha, C.H.;Yu, C.G.
    • Proceedings of the KIEE Conference
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    • 2008.10b
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    • pp.520-521
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    • 2008
  • This paper describes a low voltage, low-power CMOS buck DC/DC converter, which has a simple common-gate current sensing circuit. It consumes low power because it includes less transistors than other converters which use operational amplifiers for current sensing. The designed DC-DC converter is fabricated in a 0.18um CMOS technology. A maximum efficiency of 88% has been obtained with the proposed circuit. It has $2V{\sim}3.7V$ input voltage range, $1V{\sim}2.5V$ output voltage range and maximum output current of 1000mA.

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Enumeration of Vibrio vulnificus in Natural Samples by Colony Blot Hybridization

  • Lee, Jeong-Hyun;Lee, Kyu-Ho;Choi, Sang-Ho
    • Journal of Microbiology and Biotechnology
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    • v.11 no.2
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    • pp.302-309
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    • 2001
  • Colony blot hybridization using a VVHP DNA probe derived from the sequence of the hemolysin gene, vvhA, was specific in identifying all V. vulnificus strains, thereby, eliminating the need for any additional phenotypic identification. The colony blot hybridization procedure revealed a sensitivity and broad applicability sufficient for the direct enumeration of V. vulnificus in various natural samples, without the use of enrichment or culturing on selective medis. V. vulnificus was detected in all natural samples collected during August and May at concentrations ranging from $2.1{\times}10^1\;to\;4.0{\times}10^3$ organisms per ml. However, during November and February, when the mean temperatures of the seawater were $12^{\circ}C$ and $5^{\circ}C$, respectively, V. vulnificus was not detected in any natural samples.

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Determination of Putrescine, Spermidine and Spermine in urine by HPLC (HPLC법에 의한 뇨 중의 Putrescine, Spermidine 및 Spermine의 정량)

  • Shin, Tae-Yong;Lee, Seok-Bong;Kim, Hyung-Min
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.445-452
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    • 1997
  • A simple and sensitive high performance liquid chromatography for analysis of Putrescine, Spermidine and Spermine in urine is described. The benzoyl chloride derivatives of Putrescine, Spermidine and Spermine are separated on a ${\mu}$ Bondapak $C_{18}$ reverse-phase column with methanol/$H_2O$(50/50v/v) as the mobile phase. The results show that the mean level of polyamines in uterine cancer patients urine is much higher than in normal human urine.

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Early Stages in Morphogenesis of the Shell of Crenella decussata (Bivalvia: Mytilidae)

  • Kolotukhina, N.K.;Kulikova, V.A.;Evseev, G.A.
    • The Korean Journal of Malacology
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    • v.27 no.2
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    • pp.91-97
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    • 2011
  • This study examines the morphological features of larval and postlarval shells of the paedomorphic bivalve Crenella decussata Montagu, 1808 from the Sea of Japan. During the early morphogenesis of the shell of C. decussata the following characteristics appear: prodissoconch I -the anterior and posterior provincular teeth, a broad primary ligament pit located on the chondrophore; nepioconch - the anterior and posterior juvenile teeth,primary lateral teeth, fine commarginal and radial sculpture. Larvae of C. decussata distinctly differ from other mytilid larvae by a D-shaped shell, absence of umbo, astraight hinge margin, and homogeneous fine-grained sculpture without co-marginal lines of growth. These shell characters indicate lecithotrophic development of this species. Some morphostructures are revealed which might be used in crenellin taxonomy.

Effect of Heating Rate and $V_2O_5$ Addition on Densification and Electrical Properties of $Pb(Mn_{1/3}Sb_{2/3})O_3-PZT$ Ceramics for Piezoelectirc Transformer (압전변압기용 $Pb(Mn_{1/3}Sb_{2/3})O_3-PZT$ 세라믹스에서 승온속도 및 $V_2O_5$ 첨가가 치밀화 및 전기적 특성에 미치는 영향)

  • 허수정;손준호;손정호;이준형;김정주;정우환;박명식;조상희
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.295-301
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    • 2000
  • The effect of V2O5 addition on the low temperature sintering of Pb(Mn1/3Sb2/3)O3-PZT ceramics, which is known as a prominent material for piezoelectric transformer application was studied, and the densification behavior and piezoelectric characteristics of the samples as a function of heating rate were also examined. V2O5 led the system to liquid phase sintering by forming liquid phase during sintering, which accelerated densification through the particle rearrangement in the early stage of sintering. The liquid phase mostly existed at grain boundaries retarded the evaporation of PbO, while the densification temperature and the weight loss of V2O5-free samples were higher than those of samples with V2O5. Faster heating improved the densification of the samples regardless of V2O5 addition. The low temperature sintering at 100$0^{\circ}C$ was achieved in PMS-PZT ceramics with high density and reasonable dielectric and piezoelectric characteristics. This result revealed optimistic way to the development of multi-layered piezoelectric transformers.

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