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Performance enhancement of Organic Thin Film Transistor using $C_{60}$ hole injection layer ($C_{60}$(buckminsterfullurene) 홀주입층을 적용한 유기박막트랜지스터의 성능향상)

  • Yi, Moon-Suk
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.5
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    • pp.19-25
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    • 2008
  • In this study, we fabricated Organic Thin Film Transistors(OTFTs) with $C_{60}$ hole injection layer between organic semiconductor(pentacene) and metal electrode, and we compared the electrical characteristics of OTFTs with/without $C_{60}$. When the $C_{60}$ hole injection layer was introduced, the mobility and the threshold voltage were improved from 0.298 $cm^2/V{\cdot}s$ and -13.3V to 0.452 $cm^2/V{\cdot}s$ and -10.8V, and the contact resistance was also reduced. When the $C_{60}$ is inserted, the hole injection was enhanced because the $C_{60}$ prevent the unwanted chemical reaction between pentacene and Au. Furthermore, we fabricated the OTFTs using Al as their electrodes. When the OTFTs were made by only aluminum electrode, the channel were not mostly made because of the high hole injection barrier between pentacene and aluminum, but when the $C_{60}$ layer with an optimal thickness was applied between aluminum and pentacene, the device performances were obviously enhanced because of the vacuum energy level shift of Al and the consequent decrease of the hole injection barrier which was induced by the interface dipole formation between $C_{60}$ and Al. The mobility and $I_{ON}/I_{OFF}$ current ratio of OTFT with $C_{60}/Al$ electrode were 0.165 $cm^2/V{\cdot}s$ and $1.4{\times}10^4$ which were comparable with the normal Au electrode OTFT.

Recovery of Valuable Metals from the Desulfurizing Spent Catalyst Used in Domestic Petrochemical Industry (국내 석유공장의 탈황 폐촉매로부터 유가금속의 회수에 관한 연구)

  • 김종화;양종규
    • Resources Recycling
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    • v.4 no.3
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    • pp.2-9
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    • 1995
  • The rccoverg and separation pracess of nikcl, vanadium and molybdenum from spent dcsulfilrizing catalyst ofpetrochemical rndustries was studied. Tnis process was canied out wet process which is consist of roasting, ammonialeaching and solve111 exDaction techniqcs. The metal ions of NI, V and Mo as vduable compollents were treated byroasting them a1 low lernperatuc, 400$^{\circ}$C in first dep, and then dlssah'ed nu1 at 80$^{\circ}$C wlth ammonium cabonate mlulion.Aftcr cooling them a1 room tempertaure, vanadium wa rccavered from mathcr iiquur in thc f n m of precipitate, sodiumvanadales The Secand slep, roasting the catalyst which is added sodium carbonate ul IOOO"C, was employed. Leachingwith distilled ~ a l e rga ve a iwo phase resultant, solutio~c~a ntaning Ni, V and Mo and solid residue containing sibca,alurmniu~n and iron. A solvcnt exlclction technique uslng vvriuus extractanls, MSP-8, TOIUC, LIX64Pi was eflecnve farthc extraclion and scparation ol thrcc mcfals from thc ammonical 11qou1 thc ammonical 11qou1.

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A Study on the Stability of Langmuir-Blodgett(LB) Films of Saturated Fatty Acid Monolayer (포화지방산 단분자층 LB막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.352-358
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    • 2014
  • We were investigated the stability through the electrochemical characteristics of saturated fatty acid(C12, C14, C16, C18) monolayer LB films by cyclic voltammetry. Saturated fatty acid monolayer LB films was deposited on the indium tin oxide(ITO) glass by the LB method. The electrochemical properties were measured by cyclic voltammetry with a three-electrode system in 0.1 N $NaClO_4$ solution. The measuring range was continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s were set. As a result, LB monolayer films of saturated fatty acid were appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient(D) of saturated fatty acid(C12, C14, C16, and C18) was calculated 22.231, 2.461, 7.114 and 2.371 ($cm^2s^{-1}{\times}10^{-4}$) in 0.1 N $NaClO_4$ solution, respectively.

Strengthening of 0.25%C Low Carbon Structural Steels by Vanadium Addition (바나듐 첨가에 의한 저탄소 구조용강의 강화)

  • Lee, Sang-Ok;Lee, Hyun-Kwuon;Lee, Sang-Woo
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.2
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    • pp.79-86
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    • 2008
  • As a basic research for developing 600 MPa yield strength reinforcing steel bars, the strengthening of 0.25 wt.% carbon steel by vanadium addition was studied. The changes of microstructure and mechanical properties were investigated for the specimen V0 (0.00 wt.% V), V1 (0.03 wt.% V) and V2 (0.06 wt.% V) processed by various heat treatments. To set the heat treatment conditions, the continuous cooling transformation (CCT) curves were drawn for austenitizing temperatures of $900^{\circ}C$ and $1100^{\circ}C$. For specimens tempered at $600^{\circ}C$ after quenching from $900^{\circ}C$ and $1100^{\circ}C$, yield strength was increased by 19 MPa and 21 MPa for 0.01 wt % V addition, and tensile strength was increased by 25 MPa and 28 MPa for 0.01 wt % V addition, respectively. Also, for 0.06 wt.% V added specimens tempered after quenching and normalized, tensile strength was increased by 50 MPa and 30 MPa for increasing austenitizing temperature of $100^{\circ}C$, respectively.

A NOTE ON CONNECTEDNESS IM KLEINEN IN C(X)

  • BAIK, BONG SHIN;RHEE, CHOON JAI
    • The Pure and Applied Mathematics
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    • v.22 no.2
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    • pp.139-144
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    • 2015
  • Abstract. In this paper, we investigate the relationships between the space X and the hyperspace C(X) concerning admissibility and connectedness im kleinen. The following results are obtained: Let X be a Hausdorff continuum, and let A ∈ C(X). (1) If for each open set U containing A there is a continuum K and a neighborhood V of a point of A such that V ⊂ IntK ⊂ K ⊂ U, then C(X) is connected im kleinen. at A. (2) If IntA ≠ ø, then for each open set U containing A there is a continuum K and a neighborhood V of a point of A such that V ⊂ IntK ⊂ K ⊂ U. (3) If X is connected im kleinen. at A, then A is admissible. (4) If A is admissible, then for any open subset U of C(X) containing A, there is an open subset V of X such that A ⊂ V ⊂ ∪U. (5) If for any open subset U of C(X) containing A, there is a subcontinuum K of X such that A ∈ IntK ⊂ K ⊂ U and there is an open subset V of X such that A ⊂ V ⊂ ∪ IntK, then A is admissible.

A simulation study on the figure of merit optimization of a 1200V 4H-SiC DMOSFET (1200V급 4H-SiC DMOSFET 성능지수 최적화 설계 시뮬레이션)

  • Choi, Chang-Yong;Kang, Min-Suk;Bang, Wook;Kim, Sang-Chul;Kim, Nam-Kyun;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.63-63
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    • 2009
  • In this work, we demonstrate 800V 4H-SiC power DMOSFETs with several structural alterations to observe static DC characteristics, such as a threshold voltage ($V_{TH}$) and a figure of merit ($V_B^2/R_{SP,ON}$). To optimize the static DC characteristics, we consider four design parameters; (a) the doping concentration ($N_{CSL}$) of current spreading layer (CSL) beneath the p-base region, (b) the thickness of p-base ($t_{BASE}$), (c) the doping concentration ($N_J$) and width ($W_J$) of a JFET region, (d) the doping concentration ($N_{EPI}$) and thickness ($t_{EPI}$) of epi-layer. Design parameters are optimized using 2D numerical simulations and the 4H-SiC DMOSFET structure results in high figure of merit ($V_B^2/R_{SP,ON}$>~$340MW/cm^2$) for a power MOSFET in $V_B{\sim}1200V$ range.

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CIGS박막 태양전지소자의 온도변화에 따른 전기적 특성 분석

  • Kim, Sun-Gon;Kim, Sang-Seop;Choe, Byeong-Deok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.224.2-224.2
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    • 2013
  • 본 연구에서는 CIGS박막 태양전지의 온도 및 시간 인가에 따른 전기적 특성 변화를 분석하였다. 실험에서는 온도 스트레스를 $25^{\circ}C$, $50^{\circ}C$, $100^{\circ}C$, $150^{\circ}C$, $200^{\circ}C$에서 각각 10시간씩 인가한 후에 Dark I-V와 C-V측정을 통해 전기적 특성 변화를 분석하였다. $25^{\circ}C$일 때를 초기 온도로 하여 특성을 측정한 것과 온도별로 노출시킨 후에 측정한 것을 비교했을 때 소자의 효율은 $100^{\circ}C$에서 감소하기 시작하였고, 인가한 온도가 높을수록 점점 많이 감소하는 모습이 나타났다. 이와 비슷하게 I-V그래프와 C-V그래프의 모습도 초기 값과 비교해서 변화하는 모습이 나타났고, 온도가 높아질수록 점점 변화하는 양이 증가하였다. I-V그래프에서 Diode ideality factor는 온도변화에 따라 초기 값 대비 증가하는 모습이 나타났다. 온도에 노출되기 전보다 노출된 후에 current와 capacitance가 감소하는 경향을 보이는데, 이는 온도의 영향으로 인해 소자의 결함이 증가하여 전하들의 반응에 영향을 주었기 때문으로 판단된다.

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Changes of Cerebral Metabolism and the Related Factors during Cardiac Surgery

  • Park, Seok-Cheol
    • Biomedical Science Letters
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    • v.8 no.3
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    • pp.143-154
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    • 2002
  • The effect of cardiopulmonary bypass (CPB) on cerebral physiology during heart surgery remains incompletely understood. This study was carried out to investigate changes of cerebral metabolism and the association between the changes and clinical factors during heart surgery. Seventy adult patients (n=70) scheduled for elective cardiac surgery were participated in the present study. Middle cerebral artery blood flow velocity (V$_{MCA}$), cerebral arteriovenous oxygen content difference (C(a-v)O$_2$), cerebral oxygen extraction (COE), and modified cerebral metabolic rate for oxygen (MCMRO$_2$) were measured during six phases of the operation; Pre-CPB, CPB-10 min, Rewarm-1 (nasopharyngeal temperature 34$^{\circ}C$), Rewarm-2 (nasopharyngeal temperature 37$^{\circ}C$), CPB-off, and Post-OP (at skin closure after CPB-off). Each relationship of age, arterial blood gas parameters, or other variables to V$_{MCA}2$, C(a-v)O$_2$, COE, or MCMRO$_2$ was evaluated. V$_{MCA}$ increased (P<0.0001) whereas C(a-v)O$_2$ decreased (P<0.01) throughout the five phases of the operation compared to Pre-CPB value (control). COE diminished at CPB-10, Rewarm-1, and CPB-off (P<0.05) while MCMRO$_2$ reduced at CPB-10 and Rewarm-1 (P<0.05) compared to Pre-CPB value. Positive correlation was found between age and cerebral metabolic parameters (V$_{MCA}$, C(a-v)O$_2$, COE, or MCMRO$_2$) during CPB (range r=0.24 to 0.38, p<0.05). Four cerebral metabolic parameters had partially negative or positive correlation with arterial blood gas parameters and other variables (arterial blood pH, $O_2$ tension, $O_2$ content, $CO_2$ tension, blood pressure, blood flow, temperature, or hematocrit) during the operation. In conclusion, CPB led to marked alterations of cerebral metabolism and age, pH, and $CO_2$ tension profoundly influenced the changes during cardiac surgery.

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Low Temperature Selective Catalytic Reduction of NOx over V2O5/TiO2 Catalyst Doped with Mn (Mn이 첨가된 V2O5/TiO2 촉매상에서 질소산화물의 저온 SCR 특성)

  • Cheon, Tae Jin;Choe, Sang Gi;Choe, Seong U
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.537-542
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    • 2004
  • $V_{2}O_{5}/TiO_{2}$ catalysts promoted with Mn were prepared and tested for selective catalytic reduction of NOx in $NH_3.$ The effects of promoter content, degree of catalyst loading were investigated for NOx activity while changing temperatures, mole ratio, space velocity and $O_2$ concentration. Among the various $V-{2}O_{5}$ catalysts having different metal loadings, $V-{2}O_{5}$(1 wt.%) catalyst showed the highest activity(98%) under wide temperature range of $200-250^{\circ}C.$ When the $V-{2}O_{5}$ catalyst was further modified with 5 wt.% Mn as a promoter, the highest activity(90-47%) was obtained over the low temperature windows of $100-200^{\circ}C.$ From Mn-$V_{2}O_{5}/TiO_{2}$, it was found that by addition of 5 wt.% Mn on $V_{2}O_{5}/TiO_{2}$ catalyst, reduction activity of catalyst was improved, which resulted in the increase of catalytic activity and NOx reduction. According to the results, NOx removal decreased for 10%, but the reaction temperature down to $100^{\circ}C.$

Theoretical Study of the Structures and Binding Energies of Ca+-(CO)n and Ca+-(CO2)n (n=1,2) (Ca+-(CO)n과 Ca+-(CO2)n (n=1,2)의 구조와 결합에너지에 대한 이론 연구)

  • Park, Gil-Soon;Sung, Eun-Mo
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.272-278
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    • 2009
  • The optimized structures and vibrational frequencies for $Ca^+-(CO)_n$ and $Ca^+-(CO_2)_n$ (n=1,2) complexes were calculated with MP2 and B3LYP methods employing 6-311++G(2d,p) basis sets. Also the binding energies were investigated for all complexes to compare the stabilities. For $Ca^+-(CO)_n$ C-bonded complexes are more stable than O-bonded complexes. Two stable conformations, linear and $C_{2v}$ form, are possible for $Ca^+-(CO)_2$ complexes and the $C_{2v}$ form is more stable than the linear form. $Ca^+-(CO_2)_2$ also has two possible conformations and linear form has slightly lower energy than $C_{2v}$ form.