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A Study on the Characteristics of BST Thin Films Using Fractal Process (프렉탈 처리에 의한 BST 박막의 특성에 관한 연구)

  • Gi, Hyeon-Cheol;Jang, Dong-Hwan;Hong, Gyeong-Jin;O, Su-Hong;Kim, Tae-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.34-38
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    • 2000
  • Recently, the ceramics of high permittivity are applied to DRAM and FRAM. In this study, (Ba, Sr)$TiO_3$ (BST) ceramics thin films were prepared by Sol-Gel method. BST solution was made and spin-coated on Pt/$SiO_2$/Si substrate at 4000 [rpm] for 10 seconds. Coated specimens were dried at $150[^{\circ}C]$ for 5 minutes. Coating process was repeated 3 times and then sintered at $750[^{\circ}C]$ for 30 minutes. Each specimen was analyzed structure and electrical characteristics by Fractal Process. Thickness of BST ceramics thin films are about $2000{\AA}$. Dielectric constant and loss of thin films was little decreased at 1[KHz] - 1[MHz]. Dielectric constant and loss to frequency were 250 and 0.02 in BST3. The property of leakage current as the realation between the current and the voltage was that change of the leakage current was stable when the applied voltage was 0~3[V].

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Structural, Electrical, and Optical Properties of AZO Thin Films Subjected to Rapid Thermal Annealing Temperature (급속 열처리 온도 변화에 따른 AZO 박막의 구조, 전기 및 광학적 특성)

  • Jung, Jae-Yong;Cho, Shin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.4
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    • pp.280-286
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    • 2010
  • We have investigated the influence of rapid thermal annealing (RTA) temperature on properties of Al-doped zinc oxide (AZO) thin films deposited on glass substrate by using radio-frequency magnetron sputtering. The RTA is performed in a nitrogen ambient in the temperature range from 300 to $600^{\circ}C$ for 1 minute in a rapid thermal annealer after growing the AZO thin films. The crystallographic structure and the surface morphology of AZO thin film are measured by using X-ray diffraction, and atomic force microscopy and scanning electron microscopy, respectively. The optical transmittance of the deposited thin films is examined in the wavelength range of 300-1100 nm, where the average transmittance is above the 90% in the visible and near-infrared regions. The optical bandgap is calculated from the Tauc's model, and it shows a significant dependence on the RTA temperature. As for the electrical properties of the thin films, the AZO thin film annealed at $400^{\circ}C$ shows the lowest electrical resistivity of $8.6{\times}10^{-3}{\Omega}cm$ and the Hall mobility of $11.3cm^2$/V-sec. These results suggest that the RTA temperature is an important parameter to influence on the structural, electrical, and optical properties of AZO thin films.

Natural dyeing of cow leather with cochineal (코치닐을 활용한 우피의 천연염색)

  • Kim, Sangyool
    • The Research Journal of the Costume Culture
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    • v.24 no.6
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    • pp.817-824
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    • 2016
  • The introduction of natural dyes into modern dye houses is very promising green chemistry concept that should be popularized more to reduce the dependency of leather dyeing on some toxic and non-biodegradable synthetic dyes. In this study, the properties of dyeing of cochineal on cow leather were evaluated. The proper dyeing conditions were identified with dye uptake (K/S values) depending on the colorant concentration, dyeing duration, dyeing temperature, and dye bath pH. For the proper mordanting conditions, color changes for different mordants were observed as $La^{*}b^{*}$ and H V/C values. Color fastness (light, rubbing, and dry cleaning) was also examined. Additionally, antibacterial properties and UV protection were examined. The results were as follows: The optimized dyeing conditions were 300% o.w.f., $40^{\circ}C$, 40 min., and pH 5. The cow leather color was red in the absence of mordanting, while it was red purple after being mordanted with Al and Cu, and purple mordanted with Fe. The K/S value of cow leathers increased in the order of the dyeing using $AlK(SO_4)_2$ > $CuSO_4$ > $FeSO_4$. The colorfastness to light and rubbing were reduced compared to original (untreated) cow leather. However dry cleaning fastness was very satisfactory, with a 4~5 rating. The dyed and pre-mordanting dyed cow leather showed excellent antibacterial properties.

Oven Temperature Control by Integral - Cycle Binary Rate Modulation Technique

  • Tipsuwanporn, V.;Piyarat, W.;Chochai, N.;Jamjan, K.;Paraken, Y.
    • 제어로봇시스템학회:학술대회논문집
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    • 1999.10a
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    • pp.278-280
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    • 1999
  • This paper proposes controlling of temperature in an oven by using 4 bits Integral - Cycle Binary Rate Modulation (IBRM) method and ac line with frequency 50 Hz. Microcontroller MCS-51 controls IBRM according to Proportional Integral controller (PI) function. Discrete signals are used in the system modeled by using Ziegler Nichols principle for analyzing the stability before designing the system. This procedure makes it easy to investigate system response. The system is implemented by 4 bits digital circuit which gives 320 patterns of ac signal fur controlling the generation of energy for 3,000 watts thermal coil every 20 ms of each cycle. We divide scan time (Ts$\sub$n/) in to 20 intervals, 1 ms interval is selected to generate 16 patterns IBRM. Because of this method gives the ripple lower than 2% it generates less noise fur system. Moreover, we can consider whole system from the time model of control procedure and IBRM algorithm at 40-200$^{\circ}C$ with ${\pm}$ 1$^{\circ}C$ error in the 1 cubic meter oven.

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A Study on the Smoldering hazard of Rice bran dust. (쌀겨 분진의 훈소 위험성에 관한 연구)

  • 이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.13 no.2
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    • pp.12-17
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    • 1999
  • We intended to investigate combustion properties of rice bran dust. Combustion properties of h rice bran dust according to size distribution and amount were measured as temperature v variation with time using spontaneous ignition apparatus. Moreover, combustion properties w with blowing or without blowing condition were checked in order to investigate combustion p properties in spontaneous ignition apparatus according to flow condition of air. A As the mass and size of rice bran dust was increased, i띠ti외 smoldering temperature was l lowered. All of combustion forms were smoldering combustion. Initial smold얹ing temperature w was slightly lower with blowing condition than without blowing condition in spontaneous i ignition apparatus, which condition made heating value high.

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Preparation of Ferroelectric PZT Thin Film by Sol-Gel Processing; (III) Effect of Rapid Thermal Annealing on Microstructures and Dielectric Properties (솔-젤법에 의한 강유전성 PZT 박막의 제조;(III) 급속열처리방법이 미세구조 및 유전특성에 미치는 영향)

  • 김병호;박성호;김병호
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.881-892
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    • 1995
  • Sol-Gel derived ferroelectric PZT thin films were fabricated on ITO/Glass substrate. Two kinds of rapid thermal annealing methods, R-I (six times of intermediate and final annealing) and R-II (one final annealing after six times of intermediate annealing) were used for preparation of multi-coated PZT thin films. 2500$\AA$-thick PZT thin films were obtained by the R-I and R-II methods and characterized by microstructure and dielectric properties. In case of using R-II, the microstructure was finer than that of R-I and there was no distinguishable difference in dielectric properties of PZT thin films between the R-I and R-II methods. But dielectric properties were enhanced by increasing perovskite phase fraction with increasing annealing temperature. Measured dielectric constant of PZT thin film annealed at 62$0^{\circ}C$ using the R-I method was 256 at 1kHz. Its remanant polarization (Pr) and coercive field (Ec) were 14.4$\mu$C/$\textrm{cm}^2$ and 64kV/cm, respectively.

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Dielectric properties with heat-input condition of PZT thin films for ULSI's capacitor -1- A study on the improvement of leakage current of PZT thin films using a amorphous PZT layer (초고집적회로의 커패시터용 PZT박막의 입열 조건에 따른 유전특성 -1- 비정질 PZT를 사용한 PZT 박막의 누설전류 개선에 관한 연구)

  • 마재평;백수현;황유상
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.12
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    • pp.101-107
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    • 1995
  • To improve the leakage current, we developed two step sputtering method where PZT thin film in first deposited at room temperature followed by 600.deg. C deposition. The method used an amorphous PZT layer deposited at room temperature to keep a stable interface during sputtering at high temperature. PZT thin films were deposited on Pt/Ti/SiO$_{2}$/Si substrate at room temperature and 600.deg. C sequentially. The effect of the layer deposited at room temperature was investigated with regard to I-V characteristics and P-E hysteresis loop. In the case of the sample with the layer deposited at room temperature, both leakage current and dielectric constant were decreased. The thicker the layer deposited at room temperature was, the lower dielectric constant was. However, leakage current was indepenent of the variation of the thickness ratio. The sample with 200$\AA$ of the layer deposited at room temperature showed the most promising results in both dielectric constant and leakage current.

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Temperature Stability of Electro-mechanical Coupling Factors of PZT Ceramics (PZT 세라믹스의 전기기계결합계수 온도 안정성에 관한 연구)

  • Lee, Gae-Myoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.1
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    • pp.27-32
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    • 2014
  • In this paper, PZT piezoelectric ceramic specimens with 4 compositions (Zr/Ti=50/50, 53/47, 56/44, 58/42) in $Pb(Zr,Ti)O_3$ system were fabricated. We studied effects of poling strength and thermal aging on the temperature characteristics of eletromechanical coupling factor k31 of the specimens, which were poled with the DC electric fields, 1.5, 2.5 and 3.5 kV/mm respectively and thermally aged for an hour at $200^{\circ}C$. The eletromechanical coupling factor k31 of the specimen with the composition Zr/Ti= 53/47, nearest to the morphotropic phase boundary decreased the most greatly, irrelevant to the intensity of poling field, due to 1st thermal aging. And the temperature coefficient of eletromechanical coupling factor k31 was (-) in the tetragonal phase composition and (+) in the rhombohedral phase composition, which is reverse in the temperature coefficient of resonance frequency. It is interesting that eletromechanical coupling factor k31 of PZT ceramics is shown to be able to increase as temperature increase in the interval $-20{\sim}80^{\circ}C$.

Assessing Nitrogen and Phosphorus in Excreta from Grower-finisher Pigs Fed Prevalent Rations in Vietnam

  • Vu, T.K.V.;Sommer, G.S.;Vu, C.C.;Jorgensen, H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.2
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    • pp.279-286
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    • 2010
  • Livestock production in Vietnam is, as in most Asian countries, increasing rapidly and changing into specialized highly intensified operations. The volume of animal excreta generated exceeds the capacity of the operation land base and cannot be utilized efficiently. As a consequence, there is a loss of plant nutrients from livestock farms that causes environmental pollution. This study carried out a feed and excretion experiment measuring fecal characteristic, daily fecal production, daily nitrogen and phosphorous excretion from grower-finisher pigs fed prevalent rations in Vietnam. Furthermore, equations for assessing the excretion were tested, which can be used in farm models for optimal recycling of manure while focusing on reducing pollution. The results indicated that fecal production and nutrient excretion were affected by the different rations tested. This study showed that five selected equations for predicting excretion from grower-finisher pigs in Danish conditions can also be used with precision in Vietnamese pig farming systems. The equations have been proven valid and can, therefore, be used as a much needed tool for assessing fecal production and nitrogen in excreta on pig farms. The study also showed that about 12% of nitrogen excreted was emitted during housing. Waste water contains more than half of the nitrogen excreted, mainly in ammonium form which has a high potential for gaseous emission.

Induction of Apoptosis Signaling by a Glycoprotein of Capsosiphon fulvescens in AGS Cell (매생이 (Capsosiphon fulvescens) 당단백질에 의한 인간 위암세포 사멸기전)

  • Kim, Young-Min;Kim, In-Hye;Nam, Taek-Jeong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.44 no.3
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    • pp.216-224
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    • 2011
  • Capsosiphon fulvescens is well-known green sea algae that, in recent years, has been proposed as a potential anticancer drug. In this study, we found that C. fulvescens glycoprotein (Cf-GP) had pro-apoptotic effects on human gastric carcinoma cells. By SDS-PAGE, we confirmed that C. fulvescens extract contained a glycoprotein. Using H33342 staining, we found that the Cf-GP caused cell death in a does-dependent manner, while an MTS assay showed decreased cellular viability due to induction of apoptosis. To determine the effect of Cf-GP on apoptosis-related cellular events, cells were treated with Cf-GP and the expression of several apoptosis-related protein was determined by Western blotting. Our results indicate that Cf-GP activated both a caspase cascade and PARP, which is a substrate of caspase-3, caspase-8 and the Bcl-2 family proteins. In addition, we assessed caspase-3, and -8 activation and annexin V staining. Our results revealed a cell cycle arrest, itself leading to an increased percentage of sub-G1 cells. Our findings indicate that Cf-GP may be a source of bio-functional material with therapeutic effects on human gastrointestinal cancer.