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Electrical Properties of ZnO-Bi2O3-Sb2O3 Ceramics (ZnO-Bi2O3-Sb2O3 세라믹스의 전기적 특성)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hee;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.738-748
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    • 2008
  • In this study, it has been investigated on the changing behavior of electrical properties in $ZnO-Bi_2O_3-Sb_2O_3$ (Sb/Bi=2.0, 1.0 and 0.5) ceramics. The samples were prepared by conventional ceramic process, and then characterized by I-V, C-V curve plots, impedance and modulus spectroscopy (IS & MS) measurement. The electrical properties of ZBS systems were strongly dependent on Sb/Bi. In ZBS systems, the varistor characteristics were deteriorated noticeably with increasing Sb/Bi and the donor density and interface state density were increased with increasing Sb/Bi. On the other hand, we observed that the grain boundary reacted actively with the ambient oxygen according to Sb/Bi ratio. Especially the grain boundaries of Sb/Bi=0.5 systems were divided into two types, i.e. sensitive to oxygen and thus electrically active one and electrically inactive intergranular one with temperature. Besides, the increased pyrochlore and $\beta$-spinel phase with Sb/Bi ratio caused the distributional inhomogeneity in the grain boundary barrier height and the temperature instability. To the contrary, the grain boundary layer was relatively homogeneous and more stable to temperature change and kept the system highly nonlinear at high Bi-rich phase contents.

Relationship of ground level enhancements with solar erupted factors

  • Firoz, K.A.;Cho, Kyung-Suk;Dorotovic, Ivan;Pinter, Teodor;Kaushik, Subhash C.
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.34.2-34.2
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    • 2010
  • Cosmic rays registered by Neutron Monitors on the surface of the Earth are believed to be coming from outer space, and sometimes also from the exotic objects of the Sun. Ground level enhancement (GLE) is the sudden, sharp and short-lived increase in cosmic rays originated from the Sun. Since GLE is the signature in solar cosmic ray intensity, different solar factors erupted from the Sun can be responsible for causing it. In this context, an attempt has been made to determine quantitative relationships of GLEs > 5% with simultaneous solar, interplanetary and geophysical factors from 1997 through 2006 thereby searching the perpetrators which seem to be causing them. The study has revealed that solar flares are stronger ($0.71{\times}10-4$ w/m2) during GLE peaks than the solar flares ($1.10{\times}10-5$ w/m2) during GLE non-peaks and backgrounds. On the average, the solar wind plasma velocity and interplanetary magnetic field are found stronger during the GLE peaks than the GLE non-peaks and backgrounds indicating that the solar flares, in conjunction with interplanetary shocks, sometimes may cause GLE peaks. Direct proportionality of GLE peaks to simultaneous solar energetic particle (SEP) fluxes imply that the GLE peaks may often be caused by SEP fluxes. Although the high intensity of SEP fluxes are also seen extended few minutes even after GLE peaks, the mean (373.62 MeV) of the GLE associated SEP fluxes is much stronger than the mean (10.35 MeV) of the non-GLE associated SEP fluxes. Evidences are also supported by corresponding SEP fluences that the the mean fluence (${\sim}5.32{\times}107/cm2$) across GLE event was more intense than the mean fluence (${\sim}2.53{\times}106/cm2$) of SEP fluxes across non-GLE event.

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Evaluating Commercial Spray Applications of Lactic Acid, Hot Water, and Acidified Sodium Chlorite for the Reduction of Escherichia coli on Beef Carcasses

  • Kang, Dong-Hyun;Lee, Sun-Young
    • Food Quality and Culture
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    • v.2 no.1
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    • pp.55-60
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    • 2008
  • This study examined the effects of lactic acid spray, hot water spray, or their combined treatment, as well as the effects of acidified sodium chlorite (ASC), for the decontamination of Escherichia coli on beef carcass surfaces using a commercial intervention system. With this system, the effects of 2 or 4% lactic acid (v/v), hot water ($89{\pm}1^{\circ}C$), or their combined treatment, were examined in terms of reducing inoculated E. coli. ASC (266 ppm), which was adjusted to pH 2.5 using acetic acid or citric acid, was applied using a hand-held spray system. When the beef carcasses were treated with 2 or 4% lactic acid for 10.4 s, less than 1 log reductions of inoculated E. coli were observed. A hot water spray treatment for 9.8 s resulted in a 2.1 log reduction of inoculated E. coli. However, when the hot water was followed with either 2 or 4% lactic acid, no difference in E. coli reduction was found between the hot water alone or the combined treatment with lactic acid. When ASC was adjusted to pH 2.5 with acetic acid and citric acid, 3.8 and 4.1 log reductions of E. coli were observed, respectively. Overall, the lactic acid spray treatment was least effective, and the ASC treatment was most effective, for the E. coli decontamination of beef carcasses. Therefore, these data suggest that ASC would be a more effective intervention against E. coli than most of the methods currently being used. However, more research is required to evaluate the effects of ASC on other organisms, as well as to identify application methods that will not affect meat quality.

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Plant Community Structure of the Baekcheon Valley in Taebaeksan Area, the Baekdudaegan (백두대간 태백산지역 백천계곡의 식물군집구조)

  • 조현서;최송현
    • Korean Journal of Environment and Ecology
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    • v.15 no.4
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    • pp.369-378
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    • 2002
  • To investigate the forest structure and to suggest the basic data of forest in the Baekcheon Valley, fifty plots were set up and surveyed According to the analysis of classification by TWINSPAN. the community was divided by five groups of Quercus mongolica-Pinus densiflora(I), P. densiflora-Q. mongolica(II), Acer pseudosieboldianum-Q. mongolica(III). Betula schmidtii-A. pseudosieboldianum(IV), and Cornus controversa community(V). The structure of communities was investigated using importance value by layers The survey results were summarized as follows: 1) the results of annual ring analysis revealed that the age of Pinus densiflora forest was about 50~75 years old and Q. mongolica forest was about 40 years. 2) number of the average species was 11 1$\pm$2.2 and number of average individual was 74.6$\pm$28 1 per a plot(100$m^2$). From the above results including DBH distribution analysis it was anticipated that the deciduous broad leaf tree like C. controversa and B. schmidtii will be climax species instead of Q. mongolica. and P. densiflora.

$(Ba, Sr)TiO_3$박막의 전기적 성질과 전도기구 해석

  • 정용국;손병근;이창효
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.69-69
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    • 2000
  • (Ba, Sr)TiO3 (BST)[1-3] 박막은 유전상수가 크고 고주파에서도 유전특성 저하가 적기 때문에 ULSI DRAM(Dynamic Random Access Memory)에 응용 가능한 물질로 최근 각광을 받고 있다. 하지만, 아직 BST 박막을 DRSM에 바로 적용하기 위해선 몇 가지 문제점이 있다. 그 중 누설전류 문제는 디바이스 응용시 매우 중요한 요소이다. 특히, DRAM에서 refresh time와 직접적인 관련이 있어 디바이스 내의 신뢰도 및 전력소모를 결정하는 주된 인자가 된다. 지금까지, BST 박막의 인가전업, 온도, 그리고 전극물질에 따른 누설전류 현상들이 고찰되었고, 이에 관한 많은 전도기구 모델들이 제시되었다. Schottky emission, Poole-Frenkel emission, space charge limited conduction 등이 그 대표적인 예이다. 하지만 아쉽게도 BST 박막의 정확한 누설 전류 전도 기구를 완전히 설명하는데는 아직 한계가 있다. 따라서 본 연구에서는 제작된 BST 커패시터 내의 기본적인 전기적 성질을 조사하고, 정확한 누설전류 기구 규명에 초점을 두고자 한다. 이를 위해 기존의 여러 기구들과 비교 분석할 것이다. 하부전극으로 사용하기 위해 스퍼터링 방법으로 p-Si(100) 기판위에 RuO2 박막을 약 120nm 증착하였다. 증착전의 chamberso의 초기압력은 5$\times$10-6 Torr이하의 압력으로 유지시켰다. Ar/O2의 비는 이전 실험에서 최적화된 9/1로 하였다. BST 박막 증착 시 5분간 pre-sputtering을 실시한 후 하부전극 기판위에 BST 박막을 증착하였다. 증착이 끝난 후 시편을 상온까지 냉각시킨 후 꺼내었다. 전기적 특성을 측정하기 상부전극으로 RuO2와 Al 박막을 각각 상온에서 100nm 증착하였다. 이때 hole mask를 이용하여 반경이 140um인 원형의 상부전극을 증착하였다. BST 박막의 증착온도가 증가하고 Ar/O2 비가 감소할수록 제작된 BST-커패시터의 전기적 성질이 우수하였다. 증착온도 $600^{\circ}C$, ASr/O2=5/5에서 증착된 막의 누설전류는 4.56$\times$10-8 A/cm2, 유전상수는 600 정도의 값을 나타내었다. 인가전압에 따른 BST 커패시터의 transition-current는 Curie-von Schweider 모델을 따랐다. BST 박막의 누설전류 전도기구는 기존의 Schottky 모델이 아니라 modified-Schottky 무델로 잘 설명되었다. Modified-Schottky 모델을 통해 BST 박막의 광학적 유전율 $\varepsilon$$\infty$=4.9, 이동도 $\mu$=0.019 cm2/V-s, 장벽 높이 $\psi$b=0.79 eV를 구하였다.

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Synthesis of mesoporous carbon supported CuO: a new sorbent for $CO_2$ Caapture (이산화탄소 포집용 CuO담지 메조포러스 탄소체 합성)

  • Kim, Dae-Kyung;Peng, Mei Mei;Lee, Joo-Bo;Jeong, Ui-Min;Back, Kyung-Ran;Song, Sung-Hwa;Aziz, Abidov;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2011.12a
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    • pp.196-199
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    • 2011
  • In this study we synthesized mesoporous carbon supported CuO by using mesoporous silica i.e. SBA-15 as the template and cupric nitrate trihydrate ($Cu(NO_3)_23H_2O$)as copper source. The porous CuO was characterized with XRD, TGA, SEM and BET. The result reveals porous CuO has good crystal structure with uniform size of spherical crystal particles. The surface are a ($S_{BET}$) of porous CuO was found to be $153.46m^2g^{-1}$ with a total pore volume ($V_p$)of$0.1516cm^3g^{-1}$ and average pore size of 3.9 nm which was much higher than that of commercial CuO ($S_{BET}$, $7.6m^2g^{-1}$; $V_p$, $0.01cm^3g^{-1}$). The obtained porous CuO was studied for adsorption of $CO_2$and the maximum $CO_2$ adsorption capacity was found to be 67.5 mg/g of the sorbent at $25^{\circ}C$.

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Quality Characteristics and Antioxidant Activity of Immature Citrus unshiu Vinegar (감귤 미숙과 식초의 품질 특성과 항산화 활성)

  • Yi, Mi-Ran;Hwang, Joon-Ho;Oh, You-Sung;Oh, Hyun-Jeong;Lim, Sang-Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.2
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    • pp.250-257
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    • 2014
  • To develop vinegar with immature Citrus unshiu (IC), bacterial strains with high acetic acid-producing capabilities were isolated and identified, after which their quality characteristics, total phenolic and total flavonoid contents, and antioxidant activities were measured. Five bacterial strains were isolated from naturally fermented C. unshiu, and three were identified as Acetobacter fabarum (A. sp. RIC I) and A. pomorum (A. sp. RIC II, V). A. sp. RIC V showed the highest acetic acid-producing capability and was thus chosen as the candidate strain for further acetic fermentation using IC juice. Vinegars made with 30, 35, and 40% IC juices showed acidities of 5.38, 5.38, and 5.32% and fermentation efficiencies of 73, 72, and 70%, respectively. The fermentation periods required to reach greater than 5% acidity were 11, 9, and 9 days for vinegars containing 30, 35, and 40% IC juices, respectively. Fructose and glucose contents of the vinegars increased along with total organic acid contents including acetic acid, with increasing IC juice contents. Total phenolics were 1,546.6 and $230.9{\mu}g$ GAE/mL, whereas total flavonoids were 1,004.7 and $175.1{\mu}g$ QE/mL in vinegars made with IC and mature C. unshiu (MC) juices, respectively. DPPH free radical scavenging activities were 29% and 5%, ABTS radical scavenging activities were 62.0% and 17.9%, SOA scavenging activities were 60.9% and 41.7%, and XO scavenging activities were 32.5% and 5% in vinegars made with IC and MC juices, respectively. Therefore, vinegars made with 35% and 40% IC juices using A. sp. RIC V as the acetic acid fermentation strain showed potent antioxidant activities with greater total phenolic and flavonoid contents, promoting their use as functional vinegars.

Flow Resistance and Modeling Rule of Fishing Nets -1. Analysis of Flow Resistance and Its Examination by Data on Plane Nettings- (그물어구의 유수저항과 근형수칙 -1. 유수저항의 해석 및 평면 그물감의 자료에 의한 검토-)

  • KIM Dae-An
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.2
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    • pp.183-193
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    • 1995
  • Assuming that fishing nets are porous structures to suck water into their mouth and then filtrate water out of them, the flow resistance N of nets with wall area S under the velicity v was taken by $R=kSv^2$, and the coefficient k was derived as $$k=c\;Re^{-m}(\frac{S_n}{S_m})n(\frac{S_n}{S})$$ where $R_e$ is the Reynolds' number, $S_m$ the area of net mouth, $S_n$ the total area of net projected to the plane perpendicular to the water flow. Then, the propriety of the above equation and the values of c, m and n were investigated by the experimental results on plane nettings carried out hitherto. The value of c and m were fixed respectively by $240(kg\cdot sec^2/m^4)$ and 0.1 when the representative size on $R_e$ was taken by the ratio k of the volume of bars to the area of meshes, i. e., $$\lambda={\frac{\pi\;d^2}{21\;sin\;2\varphi}$$ where d is the diameter of bars, 21 the mesh size, and 2n the angle between two adjacent bars. The value of n was larger than 1.0 as 1.2 because the wakes occurring at the knots and bars increased the resistance by obstructing the filtration of water through the meshes. In case in which the influence of $R_e$ was negligible, the value of $cR_e\;^{-m}$ became a constant distinguished by the regions of the attack angle $ \theta$ of nettings to the water flow, i. e., 100$(kg\cdot sec^2/m^4)\;in\;45^{\circ}<\theta \leq90^{\circ}\;and\;100(S_m/S)^{0.6}\;(kg\cdot sec^2/m^4)\;in\;0^{\circ}<\theta \leq45^{\circ}$. Thus, the coefficient $k(kg\cdot sec^2/m^4)$ of plane nettings could be obtained by utilizing the above values with $S_m\;and\;S_n$ given respectively by $$S_m=S\;sin\theta$$ and $$S_n=\frac{d}{I}\;\cdot\;\frac{\sqrt{1-cos^2\varphi cos^2\theta}} {sin\varphi\;cos\varphi} \cdot S$$ But, on the occasion of $\theta=0^{\circ}$ k was decided by the roughness of netting surface and so expressed as $$k=9(\frac{d}{I\;cos\varphi})^{0.8}$$ In these results, however, the values of c and m were regarded to be not sufficiently exact because they were obtained from insufficient data and the actual nets had no use for k at $\theta=0^{\circ}$. Therefore, the exact expression of $k(kg\cdotsec^2/m^4)$, for actual nets could De made in the case of no influence of $R_e$ as follows; $$k=100(\frac{S_n}{S_m})^{1.2}\;(\frac{S_m}{S})\;.\;for\;45^{\circ}<\theta \leq90^{\circ}$$, $$k=100(\frac{S_n}{S_m})^{1.2}\;(\frac{S_m}{S})^{1.6}\;.\;for\;0^{\circ}<\theta \leq45^{\circ}$$

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Validation of Method Determining Coixol in Coix lachryma-jobi var. ma-yuen Roots Extract (율무근 추출물의 Coixol 성분 분석법 검증)

  • Kwon, Jin Gwan;Seo, Changon;Choi, Yun-Hyeok;Choi, Chun Whan;Kim, Jin Kyu;Jeong, Wonsik;Lee, Ji Eun;O, Kyeong Hee;Hong, Seong Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.8
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    • pp.952-956
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    • 2017
  • An high performance liquid chromatography (HPLC) analysis method was developed for standard determination of coixol as a functional cosmetic material in Coix lachryma-jobi var. ma-yuen roots extract. HPLC was performed on a $C_{18}$ Unison US column ($4.6{\times}250mm$, $5{\mu}m$ column) using a gradient elution of 0.1% (v/v) trifluoroacetic acid and acetonitrile at a flow rate of 1.0 mL/min at $30^{\circ}C$. The analyte was detected at 290 nm. The HPLC method was validated in accordance with the International Conference on Harmonization guideline of analytical procedures with respect to specificity, precision, accuracy, and linearity. The limit of detection and quantitation were 0.07 and 0.25 mg/mL, respectively. Calibration curves showed good linearity ($R^2$>0.9995), and the precision of analysis was satisfied (less than 0.29%). Recoveries of quantified compounds ranged from 98.36 to 100.30%. This result indicates that the established HPLC method is very useful for the determination of a marker compound in C. lachryma-jobi var. ma-yuen roots extracts.

Electrochemical Characteristic Change of Cr-doped Li4Ti5O12 due to Different Water Solubility of Dopant Precursors (도판트 프리커서의 용해도 차이에 의한 Cr-doped Li4Ti5O12의 전기화학적 특성 변화)

  • Yun, Su-Won;Song, Hannah;Kim, Yong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.17-23
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    • 2015
  • $Li_4Ti_5O_{12}$ (LTO) have attracted much attention of researchers in the field of energy storage, because of their excellent stability for electric vehicle application. A main drawback of LTO is however their insulating nature due to the wide bandgap, which should be addressed to enhance the battery performance. In this study, we investigated the effect of water solubility of dopant precursor on the electrochemical characteristics of conducting LTO prepared by doping with $Cr^{3+}$ ions with the well-known wet-mixing method. The solubility of dopant precursor directly affected the morphology and the phase of doped LTO, and therefore their battery performance. In the case of employing the most soluble dopant precursor, $Cr(NO_3)_2$, the doped LTO demonstrated a markedly enhanced discharge capacity at high C-rate (130mAh/g @ 10C), which is about 2 times higher value than that of bare LTO.