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Synthesis and Characterization of a $Di-{\mu}-oxo-bridged$ Molybdeum(V) Complexes (두 개 산소 가교형 몰리브덴(V)착물의 합성과 그 성질에 관한 연구)

  • Kim, Il-Chool;Kim, Yeoung-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.205-210
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    • 1999
  • The Mo(V) $di-{\mu}-oxo$ type $[Mo_2O_4(H_2O)_2L]Cl_2$ complexes(L: 4,4'-Diphenyl-2,2'-dipyridyl, 4,4'-Dimethyl-2,2'-dipyridyl, 4,7-Diphenyl-1,10-phenanthroline) have been prepared by the reaction of $[Mo_2O_4(H_2O)_6]^{2+}$ with a series of chelate ligands. These complexes are completed by two terminal oxygens arranged trans to one another and each ligand forms a chelate types. In $Mo_2O_4(H_2O)_2L$ two $H_2O$ coordinated at trans site of terminal oxgens. The prepared complexes have been characterized by elemental analysis, infrared spectra, electronic spectra, $^1H$ nuclear magnetic resonance spectra, and thermal analysis(TG-DTA). In the potential range -0.00V to -1.00V at scan rate of $50mVs^{-1}$, a cathodic peak at -0.83V ${\sim}$ -0.88V (vs SCE) and an anodic peak at -0.54V ${\sim}$ -0.88V (vs SCE) have been observed in aquous solution. The ratio of the cathodic to anodic current(Ipc/Ipa) is almost 2, we infer that redox is irreversible as dimer forms broken.

Bacteriological and Physiochemical Water Quality of Seawater in Tongyeong Harbor, Korea (통영항 해수의 세균학적 및 이화학적 수질)

  • CHOI Jong-Duck;JEOWG Woo-Geon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.6
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    • pp.611-616
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    • 2001
  • The bacteriological and physiochemical analysis of seawater in Tongyeong harbor was conducted to evaluate sanitary conditions, The samples were collected at 6 stations established once a month from January to December, 2000. During the study period, the ranges of temperature, transparency, chemical oxygen demand, dissolved oxygen, dissolved nitrogen, phosphate and chlorophyll-a were $6.8\sim25.2^{\circ}C,\;1.0\sim2.5\;m,\;1.79\sim2.41\;mg/L,\;5.7\sim10.1\;mg/L,\;6.59\sim10.53{\mu}g-at/L,\;0.56\sim1.01{\mu}g-at/L\;and\;1.21\sim9.54\;mg/m^3$, respectively, The viable cell counts of seawater in Tongyeong harbor ranged from $3.0\times10^4CFU/mL\;to\;6.9\times10^6CFU/mL$. The coliform group and fecal coliform MPN's of the samples were ranged $23\~4,600\;MPN/100\;mL$ (means 540 MPN/100 mL) and $11\~1,600\;MPN/100\;mL$ (means 210 MPN/100 mL), respectively, The coliform group was classified with IMViC reactions and pathogenic vibrios were analyzed. Two hundred eighteen strains that were obtained from seawater samples in Tongyeong harbor represented Escherichia coli group, $66.1\%$; Citrobacter freundii group, $11.0\%$; Enterobacter aerogenes, $9.6\%$; and unknown, $13.3\%$, respectively. During the study period, infectious bacteria such as Vibrio cholerae O1, Salmonella sp. and Shigella sp. were not detected from the samples, but detection ratios of V. parahaemolyticus, V cholerae non-O1 and V. vulnificus were $10.0\sim30.1\%$.

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Isolation of the Phytophthora Root Rot Pathogen of Atractylodes macrocephala, Phytophthora drechsleri, and Bioassay of the isolates with Seedlings (백출의 역병균 분리 및 유묘를 이용한 병원성 정정 방법의 확립)

  • Cho, Joon-Hyeong;Kim, Yong-Wook;Bang, Kyong-Hwan;Park, Chun-Gun;Seong, Nak-Sul
    • Korean Journal of Medicinal Crop Science
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    • v.10 no.3
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    • pp.155-161
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    • 2002
  • Using semi-selective (SS-) and selective (Jee-) medium, we identified the pathogens isolated from the symptomatic plants and soils collected from different locations, such as Suwon, Andong, and Youngju, as P. drechsleri, which is Phytophthora root rot causal agent of A. macrocephala. At $25^{\circ}C$, these isolates were grown faster on 10% V8A (V8 juice agar) medium than on PDA (potato dextrose agar) with hyphal swelling, but no growing was observed at below $5^{\circ}C$ and over $40^{\circ}C$. In order to identify the pathogenicity of each isolate, seedlings of A. macrocephala were inoculated with mycelium -zoospore suspended inoculum, which was prepared by culturing on 10% V8A medium and homogenizing in distilled water. By this method, wide ranges of pathogenicity were observed as follows; $5.0%{\sim}26.4%$ of disease severities concerning the lesion areas of the top plants and $23.5%{\sim}72.2%$ of disease incidences. Therefore, this was considered as a efficient method to identify the pathogenicity of P. drechsleri in large scale screening. P-A200073, isolated from soils in Andong, and P-9755, from the root of symptomatic plant of A. macrocephala in Suwon, showed the highest degree of pathogenicity to the seedlings. By these isolates, lesion areas and disease incidences of the inoculated seedlings were occurred $26.4%{\sim}63.2%$ and $25.1%{\sim}72.2%$, respectively. However, no symptoms were observed in uninoculated control. Same pathogens were reisolated from roots and lower stems of the inoculated plants, but not from leaves.

An Extraction of Barley Protein and a Comparison of the Protein Composition of Some Barleys -I. Extraction of Barley Protein- (보리단백질의 추출 및 품종간 조성비교 -I. 보리단백질의 추출-)

  • Kim, Jung-Sang;Kim, Ze-Uook
    • Applied Biological Chemistry
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    • v.29 no.1
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    • pp.51-56
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    • 1986
  • Using milled barley of four varieties Olbori, Youngsan-bori, Sacheon 6, and Suwon 228, the barley proteins were fractionated by the Osborne method and the modified Osborne method. Two fractionation methods were compared. There was a steady increase in the amount of nitrogen extracted as NaCl concentration increased, reaching a maximum at 0.5M NaCl and the extraction of nitrogen by 0.5M NaCl reached a maximum at $22^{\circ}C$. Alcohol-soluble fraction was least extracted by 70% (v/v) ethanol at $4^{\circ}C$ and most by sequential extraction with 50% (v/v) propan-1-ol alone followed by 50% (v/v) propan-1-ol plus 3% (v/v) 2-mercaptoethanol. Nitrogen was least extracted between pH 4 and 6 and most extracted at higher pH than 10. The modified Osborne fractionation of the protein complex in the four barleys showed that the salt-soluble nitrogen accounted for 21,4% to 24.1%, hordein-I varied from 30.4% to 43.4%, hordein-II varied widely from 9.3% to 19.5% and borate buffer-soluble glutelin content ranged from 17.1% to 23.7%.

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New Line Coding of Visible Light Communication System for WPAN (WPAN용 가시광 통신 시스템의 새로운 라인코딩)

  • Kim, Jin-Young;Choi, Jae-Hyuck;Sang, Cha-Jae
    • Journal of Broadcast Engineering
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    • v.14 no.1
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    • pp.70-80
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    • 2009
  • We propose an ideal line coding for high speed data communication in visible light communication system. B4-HBT line coding is defined as follow. The 1 bit is +V at first though 1 encodes +Voltage and -Voltage doing change of shift each other, then -V newly. V that is been mutually contradictory for 1 bit that exist before that if continuous 0 bits exist 4 here same and reduces mistake because has reverse mark V in 4 continuous last 0 bits and gives half bit variation in 1 bit and made effect of noise low. 2${\sim}$3 dB profit is seen comparing with line coding that exist in simulation result.

Design of potentiostat and I-V converter for micro pO2 sensor (마이크로 산소분압센서용 Potentiostat 및 I-V Converter 회로 설계)

  • Seo, Hwa-Il;Choi, Pyung;Sohn, Byung-Ki
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.22-27
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    • 1994
  • Design of potentiostat and I-V converter for micro pO2 sensor is described. Also, The operation of the designed circuit, in connection with the eqivalent model of micro pO2 sensor, is simulated. The potentiostat showed low output resistance of $l.1k{\Omega}$ and input voltage range of $-3{\sim}2.5V$. And the I-V converter showed low input resistance of $30{\Omega}$ and good linearity between input and output.

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Studies on Benzo(a)pyrene Content in the Surface Soil of Seoul City (서울市 土砂中 Benzo (a) pyrene의 含量에 關한 硏究)

  • 孫東憲;金載翰
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.12-20
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    • 1989
  • Distribution of benzo(a)pyrene (BaP) in Seoul surface soils was investigated with a simple micro-analytical method consisting of ultrasonic extraction, one-dimensional dual band thin-layer chromatographic separation (TLC) and spectrofluorometric determination. The TLC was done in the following condition: thin-layer plate; Kieselguhr G/Acetylated cellulose, Developer; 1st; ether, 2nd; methanol-ether-water (4:4:1, V/V). The results thus obtained were as follows; 1. All the samples collected from various areas were contained detectable amount of benzo(a)pyrene. The range and average of benzo(a)pyrene contents in Seoul areas are 0.20 $\sim$5.90ppm and 1.01 ppm, respectively. 2. Benzo(a)pyrene contents in soils obtained from commercial areas were much higher than those in industrial and residential areas. The contents range in commercial, industrial, and residential areas are 0.31 $\sim$ 5.90 ppm, 0.36 $\sim$ 1.22 ppm and 0.20 $\sim$ 0.67 ppm, respectively. 3. Benzo(a)pyrene contents in soils from major roads were far higher than those from side or park roads. The ranges of benzo(a)pyrene contents in major, park and side road are 0.40 $\sim$ 5.9 ppm, 0.20 $\sim$ 0.70 ppm, 0.31 $\sim$ 1.30 ppm, respectively. These findings suggest strongly that surface soils in Seoul city are polluted by benzo(a)pyrene probably emitted automobiles.

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Efface of Annealing in a Reduction Ambient on Thermoelectric Properties of the $(Bi,Sb)_{2}Te_{3}$ Thin Films Processed by Vacuum Evaporation (환원분위기 열처리가 $(Bi,Sb)_{2}Te_{3}$ 증착박막의 열전특성에 미치는 영향)

  • Kim, Min-Young;Oh, Tae-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.3
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    • pp.1-8
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    • 2008
  • Effects of annealing process in a reduction ambient on thermoelectric properties of the $(Bi,Sb)_{2}Te_3$ thin films prepared by thermal evaporation have been investigated. With annealing at $300^{\circ}C$ for 2 hrs in a reduction ambient(50% $H_2$+50% Ar), the crystallinity of the $(Bi,Sb)_{2}Te_3$ thin films were substantially improved with remarkable increase in the grain size. Seebeck coefficients of the $(Bi,Sb)_{2}Te_3$ thin films increased from$\sim90{\mu}V/K$ to $\sim180{\mu}V/K$ with annealing in the reduction ambient due to decrease in the hole concentration. Power factors of the $(Bi,Sb)_{2}Te_3$ thin films were remarkably improved for $5\sim16$ times with annealing in the reduction atmosphere. After annealing in the reduction ambient, a $(Bi,Sb)_{2}Te_3$ evaporated film exhibited a maximum power factor of $18.6\times10^{-4}W/K^{2}-m$.

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Photoluminescence of Multinary-compound Semiconductor $ZnGaInS_4:Er^{3+}$ Single Crystals (다원화합물 반도체 $ZnGaInS_4:Er^{3+}$ 단결정의 광발광 특성)

  • Kim, Nam-Oh;Kim, Hyung-Gon;Bang, Tae-Hwan;Hyun, Seung-Cheol;Kim, Duck-Tae
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.35-39
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    • 2000
  • $ZnIn_2S_4$ and $ZnGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral (hexagonal) space group $C_{3v}^5(R3m)$, with lattice constants $a=3.852{\AA},\;c=37.215{\AA}$ for $ZnIn_2S_4$, and $a=3.823{\AA}$, and $c=35.975{\AA}$ for $ZnIn_2S_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of there compounds had a direct and indirect band gap, the direct and indirect energy gaps are found to be 2.778 and 2.682 eV for $ZnIn_2S_4$, and 2.725 and 2.651eV for $ZnIn_2S_4:Er^{3+}$ at 293 K. The photoluminescence spectra of $ZnIn_2S_4:Er^{3+}$ measured in the wavelength ranges of $500nm{\sim}900nm$ at 10 K. Eight sharp emission peaks due to $Er^{3+}$ ion are observed in the regions of $549.5{\sim}550.0nm,\;661.3{\sim}676.5nm$, and $811.1{\sim}834.1nm$, and $1528.2{\sim}1556.0nm$ in $CdGaInS_4:Er^{3+}$ single crystal. These PL peaks were attributed to the radiative transitions between the split electron energy levels of the $Er^{3+}$ ions occupied at $C_{2v}$, symmetry of the $ZnIn_2S_4$ single crystals host lattice.

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Production of Organic Acids from Food By-Products - Fermentation Characteristics of Propionibacterium acidipropionici - (식품부산물로부터 유기산의 대량생산공정에 관한 연구 - Propionibacterium acidipropionici의 발효 특성 -)

  • Jin Sun-Ja;Ju Yun-Sang;Hwang Pil-Gi;Choi Chul-Ho;Lee Eui-Sang
    • KSBB Journal
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    • v.19 no.6 s.89
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    • pp.478-483
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    • 2004
  • The optimum fermentation conditions of Propionibacterium acidipropionici were determined for the maximum production of organic acids. Three strains of P. acidipropionici, ATCC 25562, 4875, 4965 were selected to test the productivity of organic acids in the batch fermentation. Nutrients and environmental conditions on cell growth were defined by series of experiments, and the optimum amounts of peptone, yeast extract were determined to be $1.5\%$ (w/v), $0.75\%$ (w/v), respectively. The yields and productivity were highest at pH 6 among the ranges of $5.0{\sim}7.5$, and ATCC 4965 was determined to be the best strain compared to the others by getting total productivity of 0.29 g total acids/L/h. Approximately $1.60{\sim}2.34$ moles of propionic acid and $0.74{\sim}1.05$ moles of acetic acid were produced from 1.5 moles of glucose.