• Title/Summary/Keyword: V-곡선

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Electrical and Physical Properties of Magnetite-Filled NBR (마그네타이트가 충전된 NBR의 전기적 특성 및 물성 연구)

  • 최교창;이은경;최세영;박수진
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.40-45
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    • 2003
  • In this work, the effect of different contents of $Fe_3O_4$ and temperature variation on the electrical conductivity ($\sigma$) in the polar acrylonitrile butadiene rubber (NBR)/$Fe_3O_4$ (magnetite) mixture system was investigated. It was found that the percolation threshold concept holds true for the conductive particle-filled composites where $\sigma$ indicates a nearly sharp increase when the concentration of magnetite in the mixture exceeds 22%. The temperature dependence of $\sigma$ was thermally activated below and at the percolation threshold ($P_c$). Magnetite acted as reinforcing and conductive filler for NBR. At room temperature and higher voltages, the electrical current was proportional to the square of voltage ($I{\propto}V^2$) for the composites which contain 30 phr of magnetite. Moreover, it was shown that the composites with magnetite of 50 phr showed the highest tensile strength and elongation at break, which was due to the formation of optimal physical interlock and crosslinking. The results of 100%, 200%, and 300% Young moduli said that the moduli are largely correlated with reinforcement effect of magnetite and viscosity of the blends from torque curve.

Structural Analysis of Ag Agglomeration in Ag-based Ohmic Contact to p-type GaN (고분해능 X선 회절을 이용한 Ag 기반 p형 반사막 오믹 전극 집괴 분석)

  • Son, J.H.;Song, Y.H.;Lee, J.L.
    • Journal of the Korean Vacuum Society
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    • v.20 no.2
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    • pp.127-134
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    • 2011
  • We investigate the crystallographic orientation and strain states of the Ni/Ag ohmic contacts on p-type GaN. The Ag film in the Ni/Ag contact was severely agglomerated during high temperature annealing in air ambient. As a results, after annealing for 24 h, the Ni/Ag contact shows non-linear I-V curve and low light reflectance of ~21% at 460 nm wavelength. High-resolution X-ray diffraction results show that the interplanar spacing of Ag (111) planes is almost same to that of bilk Ag after annealing for 24 hrs, indicating that the in-plane tensile strain in the Ag film was fully relaxed due to the Ag agglomeration.

A study on the ECMP process improvement with optimization of $NaNO_3$ Electrolyte ($NaNO_3$ 전해액의 최적화로 인한 ECMP 공정 개선에 관한 연구)

  • Lee, Young-Kyun;Park, Sung-Woo;Han, Sang-Jun;Lee, Sung-Il;Jung, Pan-Geom;Choi, Gwon-Woo;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.53-53
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    • 2007
  • 반도체 소자의 고집적화, 미세화 화로 인해 반도체의 동작속도를 증가시키기 위하여 Cu를 이용한 금속배선이 주목받게 되었으나, 높은 압력으로 인한 보은 Cu 영역에서 과잉 디슁 현상과 에로젼을 유도하고 반도체 웨이퍼위의 low-k 물질에 손상을 줌에 따라 메탈라인 브리징과 단락을 초래할 있어, Cu의 단락인 islands를 남김으로서 표면 결항을 제거하지 못한다는 단점을 가지고 있었다. 그래서 이러한 문제점을 해결하기 위하여 기존의 CMP에 전기화학을 결합시킴으로서 낮은 하력에서의 Cu평탄화를 달성할 수 있는 ECMP (electrochemical mechanical polishing)기술이 필요하게 되었다. 따라서 본 논문에서는 전기화학적 기계적 연마(ECMP)작용을 위해, I-V 특성 곡선을 이용하여 패시베이션 막의 active, passive, transient, trans-passive영역의 전기화학적 특성을 비교 분석하였으며, Cu막의 표면 형상을 알아보기 위해 scanning electron microscopy (SEM) 측정과 energy dispersive spectroscopy (EDS)와 X-ray Diffraction (XRD) 분석을 통해 금속 화학적 조성을 조사하였다.

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Experimental Study on the Spalling Properties of Ultra High Strength Concrete containing Amorphous Metallic Fiber (비정질강섬유를 혼입한 초고강도콘크리트의 폭렬특성에 관한 실험적 연구)

  • Choe, Gyeong-Cheol;Kim, Gyu-Yong;Kim, Hong-Seop;Hwang, Eui-Chul;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.111-118
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    • 2019
  • This study examined the effect of amorphous metallic (AM) fibers on the spalling properties of ultra high strength concrete. Six specimens with concrete strengths of 100 MPa and 150 MPa were evaluated with mix proportions of polypropylene (PP) fibers of 0.15% by concrete volume, and proportions of AM fibers of 0.3% and 0.5% by concrete volume. These specimens were then heated in accordance with the ISO-834 heating curve. The movement of water vapor through a pore network formed by molten PP fibers was found to be a dominant factor controlling the spalling of high-strength concrete. Spalling control was not found to be significantly affected by the addition of 0.3% AM fibers; however, when 0.5% AM fibers was added, cracking was limited and so were paths for water vapor migration, increasing the likelihood of a moisture clog and creating the differential internal pressure often blamed for concrete spalling.

Energy Conversion Efficiency of TiO2 Dye-sensitized Solar Cells with WO3 Additive (WO3가 첨가된 TiO2 염료감응형 태양전지의 에너지 전환 효율)

  • Lee, Sung Kyu;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.26-30
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    • 2011
  • In order to improve the energy conversion efficiency of dye-sensitized solar cell (DSSC), the photoelectrode was manufactured by using $TiO_2$ and $WO_3$ on combination effects of two conduction bands. The smash procedure of $TiO_2$ and $WO_3$ was carried out by using a paint shaker to enlarge the contact area of semiconductor with dye and electrolyte. The energy conversion efficiency of prepared DSSC was improved about two times from current-voltage curve based on effects of $WO_3$ and smash. The mechanism was suggested that the conduction band of $WO_3$ worked for prohibiting the trapping effects of electrons in conduction band of $TiO_2$. This result is attributed to the prevention of electron recombination between electron in conduction band of $TiO_2$ with dye and electrolyte. Impedance results indicate the improved electron transport at interface of $TiO_2$/dye/electrolyte.

Characterization of Deep Shear Wave Velocity Profiles in the Gimhae Plains Using the Microtremor Array Method (상시미동 표면파 분석에 의한 김해평야 퇴적층 심부 전단파 속도 결정)

  • Kim, Jae Hwi;Jeong, Seokho
    • Journal of the Korean Geotechnical Society
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    • v.38 no.8
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    • pp.17-27
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    • 2022
  • To characterize the dynamic properties of Gimhae Plains sediments, we calculated natural frequencies using microtremor horizontal-to-vertical spectral ratios and derived shear wave velocity profiles by inversion of Rayleigh-wave dispersion curves obtained by the high frequency-wavenumber and modified spatial autocorrelation methods. Our results suggest that in this region, strong amplification of ground motion is expected in the vibration frequency (f ≥ 1 Hz). Additionally, obtained velocity profiles show that shear wave velocities are ~200 and 400 m/s for the shallow marine and old fluvial sediments, respectively. Bedrock is possibly encountered at depths of 60-100 m at most sites. We developed a simplified shear wave velocity model of shallow sediments based on the obtained profiles. Our results suggest that a large area in the Gimhae Plains could be categorized as an S6 site based on the Korean seismic design code (KDS 17 10 00).

Assessment of the Effect of a Disinfectant to Control Vibrio Strain from White Leg Shrimps Cultured in Korea (국내산 양식 흰다리새우 유래의 비브리오균에 대한 소독제의 방제 효과 검증)

  • Jin Woo Jun
    • Journal of Practical Agriculture & Fisheries Research
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    • v.25 no.3
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    • pp.30-34
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    • 2023
  • White leg shrimps which were cultured in a private aquaculture farm showed abnormal swimming behavior and appetite reduction in July 2023. Then, gradual mortality was observed in the aquaculture farm. During the diagnosis, bacterial strain KNUAFVaSHP08147 was isolated from the hepatopancreas of the dead shrimps. Based on the sequence of 16S rRNA gene, KNUAFVa-SHP08147 was proved to be Vibrio alginolyticus, showing 99.71 % nucleotide identity with that of V. alginolyticus MG54 and GS MYPK1. According to the result of the growth of KNUAFVa-SHP08147, the treatment a commercial disinfectant, VirkonTMS was not proved to be effective to prohibit the growth of Vibrio.

Displacement Analysis of an Excavation Wall using Inclinometer Instrumentation Data, Banyawol Formation, Western Daegu (경사계를 이용한 대구 서부지역 반야월층 굴착 지반의 변위 분석)

  • Ihm, Myeong-Hyeok
    • The Journal of Engineering Geology
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    • v.23 no.1
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    • pp.47-55
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    • 2013
  • To analyze lateral displacement of excavation walls exposed during the construction of Subway Line 1 in the Daegu region, inclinometer measurement data for sites D4, D5, and Y6 are investigated from the perspective of engineering geology. The study area, in the Banyawol Formation, Hayang Group, Gyeongsang Supergroup, is in the lower part of bedrock of andesitic volcanics, calcareous shale, sandstone, hornfels, and felsite dykes that are unconformably overlain by soil. The rock mass around the D4 site is classified as RMR-V grade and the maximum lateral displacement of 101.39 mm, toward N34W, was measured at a bedding-parallel fault, at a depth of 12 m. The rock mass around the D5 site is classified as RMR-IV grade and the maximum lateral displacement of 55.17 mm, toward the south, was measured at a lithologic contact between shale and felsite, at a depth of 14 m. The rock mass around the Y6 site is classified as RMR-III grade and the maximum lateral displacement of 12.65 mm, toward S52W, was measured at an unconformity between the soil and underlying bedrocks, at a depth of 7 m. The directions of lateral displacement in the excavation walls are vector sums of the directions perpendicular to the excavation wall and horizontally parallel to the excavation wall. Lateral displacement graphs according to depth in the soil profile show curvilinear trajectories, whereas those in bedrock show straight and rapid-displacement trajectories.

Simultaneous Determination of Ultra-Trace Pesticides and Synthetic Materials in Surface Water by LC-ESI-MS/MS (하천수에서 LC-ESI-MS/MS에 의한 극미량 농약류 및 합성원료의 동시분석법)

  • Hong, Seon-Haw;Lee, Jun-Bae;Lee, Soo-Hyung;Cho, Young-Hwan;Shin, Ho-Sang
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.225-232
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    • 2015
  • A liquid chromatography-electrospray ionization-tandem mass spectrometry method (LC-ESI-MS/MS) was used for determining seven pesticides (2,4-dichlorophenoxyacetic acid, methomyl, aldicarb, 2-methyl- 4-chlorophenoxy- acetic acid, molinate, carbaryl and carbofuran) and two synthetic materials (quinoline and bisphenol-A) in surface water. The analytes were extracted using solid-phase extraction (SPE). The eluate was concentrated by nitrogen gas. 100 microliters of 30% (v/v) methanol aqueous solution were used to dissolve the residue and an aliquot of the reconstituted solution was directly injected into LC-ESI-MS/MS after the filtration using 0.2 μm polytetrafluoroethylene (PTFE) syringe filter. Under the established condition, the calibration curves of the analytes were linear with correlation coefficients of above 0.997. The quantification limit was 0.002~0.011 μg/L and the relative standard deviations were less than 16.4%. In addition, accuracy was in the range of 84~107% and the recoveries were values between 56.2 and 98.6%. In this study, the developed method was applied to the analysis of real surface water samples.

Effects of Excess Lead Addition on Sol-Gel Derived ($Pb_{0.9}La_{0.1}$)$Ti_{0.975}O_3$(PLT (10)) Thin Film

  • Kim, Seong-Jin;Jeong, Yang-Hui;Yun, Yeong-Seop
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.3
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    • pp.1-8
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    • 2002
  • In order to study electric properties of (Pb$\_$0.9/La$\_$0.1/)Ti$\_$0.975/O$_3$(PLT (10)) films with varying excess lead concentration (7.5, 10, 12.5, 15 ㏖% excess lead), the PLT films were deposited by sol-gel process. DTA analyses reveal that the crystallization temperature of the precursor powers decreased with increasing amount of excess lead. XRD patterns of PLT reveal pure perovskite structure and the preferred orientation increased with increasing Pb content in the films. With increasing amount of excess P$\_$b/, the relative permittivity ($\xi$$\_$r/) increased and leakage current density at 100 ㎸/cm transformed 4.01$\times$10$\^$-5/, 2.42$\times$10$\^$-6/, 1.27$\times$10$\^$-6/, 1.56$\times$10$\^$-6/A/㎠ respectively. In the results of hysteresis loops measured at 166 kV/cm, the remanent polarization (P$\_$r/) and the coercive field (E$\_$c) are 6.36$\mu$C/cm and 58.7 ㎸/cm, respectively (at 12.5 ㏖% excess P$\_$b/) With increasing amount of excess Pb, the remanent polarization for PLT thin film degraded to about 44%, 27%, 15%, 16% of the initial value after 10$\^$9/ cycles./TEX>) With increasing amount of excess Pb, the remanent polarization for PLT thin film degraded to about 44%, 27%, 15%, 16% of the initial value after $10^{9}$ cycles.