• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.3
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• pp.281-292
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• 2014

Objectives: The aim of this case study is to verify the chemical exposure reductions for various chemicals by substituting the ingredients of raw materials in a polyurethane(PU) foaming industry. The PU foaming process was making various passenger car seats from chemicals such as toluene diisocinate(TDI), methylene bisphenyl isocyanate(MDI) and polyols. Methods: Basic process data and workers' health effects could be gathered by interviewing managers and reviewing previous exposure monitoring data. Amine, aldehyde and isocyanate chemicals were analyzed following the NIOSH-NMAM. Area sampling methods rather than personal sampling were introduced for this field investigation. Results: Two amines, triethylene diamine(TEDA) and N,N,N',N'-Tetramethyl-1,6- hexanediamine(TMHDA) were identified in raw polyol, cured PU foam and air. The average concentrations of TEDA and TMHDA showd less than 1 ppm by area sampling; however, that caused halovision among workers in PU-PAD process. Aldehydes and isocyanates were detected in the air while the concentrations were relatively low compare to occupational exposure limits. Successful raw material substitution from nonreactive amine to reactive amine could reduces air-borne amine and aldehyde levels by about 70%. Halovision had been disappeared successfully in the process. Conclusions: Several amines caused halovision among workers in PU-PAD process, especially during summer season in spite of relatively low levels. Combination of reactive amines into urethane foam could reduced vapor generation into air, which resulted in the elimination of eye troubles in the process.

• Journal of the Korean Wood Science and Technology
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• v.26 no.4
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• pp.43-49
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• 1998

The availability of large quantities of waste woods provides an impetus for investigating woody biomass potential uses. Polyurethane (PU) foams are prepared with reacting isocyanates and polyols, and are used. in various industry fields. Thus, lignocellulosic waste raw-materials are proposed as replacement for synthetic polyol to PU foam formulation. In this study PU foams were manufactured from liquefied woods, methanediisocyanate(MDI), catalyst, foaming stabilizer, and viscosity aids. The polyol content, isocyanate.hydroxyl group (NCO/OH) ratio, and water content were varied to evaluate their effects on the foaming and water absorption of the PU foams. Less than 400 Molecular weight. of polyethylene glycol(PEG) and 1 to 3 solvent to woody raw-material ratio were desirable for liquefying woody materials. Liquefying rate was increased with more than 3 % addition of inorganic and organic catalysts and raising reaction temperature more than $150^{\circ}C$. Addition of starch enhanced liquefying of woody materials. Fourty percents of starch resulted in about 90% liquefying rates. Foaming rates were increased with increasing moisture contents of liquefied wood. Moisture contents of 0.6% resulted in 5 time-foaming rates, and seven percents of moisture contents more than 30 time-foaming rates. But, an increase in water content may result in a decrease in cross-links between wood polyol and isocyanate, because the NCO/OH ratio is constant. Increasing moisture contents have significantly decreased density of PU foams. The optimum water content should be about 2.5% or less in this adopted condition.

• Journal of the Korean Solar Energy Society
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• v.28 no.4
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• pp.10-16
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• 2008

The fire resistance of thermal insulation and interior finishing materials is recently much emphasized after the fire accident at the Icheon Cold Store in January 2008. Three kinds of thermal insulation are used in buildings. They are Organic, Non-organic and cellulosic insulation. Organic insulation such as polystyrene foam board and urethane foam has high thermal resistance but it has no fire resistance. While non-organic insulation such as rockwool and glassfiber has high fire resistance, it has lower thermal resistance than organic insulation. Cellulose insulation is primarily manufactured from recycled newsprint or cardboard using shredders and fiberizers. Despite of its environmental friendliness and high thermal resistivity, its domestic use has not much increased because of the prejudice that paper can easily burn. However, the cellulose insulation as a product is about 80 wt.% cellulosic fiber and 20 wt.% chemicals, most of which are fire retardants such as boric acid and ammonium sulfate. It is required to secure its fire safety for more consumption as a building insulation in Korea. Therefore, this study investigates the fire resistance of Korean cellulose insulation according to the rate of fire retardant and finally presents the optimum rate of fire retardant in cellulose as building insulation. The fire safety test was conducted according to the ASTM C 1485-00. The test results indicate that above 18 wt% of fire retardant is necessary to secure the fire safety of cellulose insulation.

• Journal of the Korean Institute of Gas
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• v.26 no.3
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• pp.27-37
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• 2022

With the recent increase in the spread of ESS (Electric Storage System), the damage to human life and property is also rapidly increasing due to continuous fires caused by ESS. In the manufacture of urethane sandwich panels used in ESS, it is necessary to improve the flame retardant performance. In this study, in order to realize the flame retardant properties of flexible polyurethane foam, the effect of the tissue density of the product due to the change of the isocyanate functional group parameter that changes the physical properties of the product on the fire performance was studied. The product was manufactured by changing the density of the urethane structure, and combustion performance tests, gas toxicity tests, and smoke density tests were performed. As a result, it was confirmed that the total amount of heat released had excellent performance when the isocyanate functional group was high, and had no correlation with the maximum heat release rate. When the value of the isocyanate functional group was 2.7 or more, the collapse of the shape could be prevented. In the gas hazard test, the performance was increased when the isocyanate functional group was relatively high, so a flame retardant for the Char system, which had a dense structure and easy to form a carbonized film, was added. confirmed to be. Therefore, as a result of this study, it is thought that it will be possible to lay the foundation for the development of a flame retardant to replace the cheap urethane sandwich panel used in the past.

• Fashion & Textile Research Journal
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• v.14 no.4
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• pp.635-640
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• 2012

In this study, thermoplastic urethane (TPU) coating yarns were prepared at various extruding temperatures. The fine structure and mechanical properties of resultant TPU coating yarns examined by the wide angle X-ray diffractometer (WAXD), differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), and tensile test. TPU coating yarns (prepared at extruding temperatures at $175^{\circ}C$) were confirmed as a stable fine structure that obtained excellent tensile strength and flexibility. The C samples prepared by optimized conditions made by TPU woven floor mat. The structure of the woven mat is $4{\times}4$ basket weave and have laminated with the EVA foam to obtained final TPU woven floor mat products. The resultant TPU woven floor mat was obtained to 1.5MN of tensile strength, 22% of the elongation, and 0.2MN of tear strength. The weight loss abrasion and the resilience by the ball rebound of the TPU-woven floor mat was prior to those of the PVC subsequently, we were able to develop a woven floor mat with TPU coating yarn and produce an eco-friendly high valuable woven floor mat using an interior product.

• Journal of the Korean Society of Propulsion Engineers
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• v.8 no.1
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• pp.70-80
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• 2004

This study proposes a development result for the 1-kW class small wind turbine system, which is applicable to relatively low wind speed regions like Korea and has the variable pitch control mechanism. In the aerodynamic design of the wind turbine blade, parametric studies were carried out to determine an optimum aerodynamic configuration which is not only more efficient at low wind speed but whose diameter is not much larger than similar class other blades. A light composite structure, which can endure effectively various loads, was newly designed. In order to evaluate the structural design of the composite blade, the structural analysis was peformed by the finite element method. Moreover both structural safety and stability were verified through the full- scale structural test.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.434-437
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• 2005

Chemical Mechanical Polishing (CMP) has become an essential step in the overall semiconductor wafer fabrication technology. In general, CMP is a surface planarization method in which a silicon wafer is rotated against a polishing pad in the presence of slurry under pressure. The polishing pad, generally a polyurethane-based material, consists of polymeric foam cell walls, which aid in removal of the reaction products at the wafer interface. It has been found that the material removal rate of any polishing pad decreases due to the so-called 'pad glazing' after several wafer lots have been processed. Therefore, the pad restoration and conditioning has become essential in CMP processes to keep the urethane polishing pad at the proper friction coefficient and to allow effective slurry transport to the wafer surface. Diamond pad conditioner employs a single layer of brazed bonded diamond crystals. Due to the corrosive nature of the polishing slurry required in low pH metal CMP such as copper, it is essential to minimize the possibility of chemical interaction between very low pH slurry (pH <2) and the bond alloy. In this paper, we report an exceptional protective coated conditioner for in-situ pad conditioning in low pH Cu CMP process. The protective Cr-coated conditioner has been tested in slurry with pH levels as low as 1.5 without bond degradation.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 1998.11a
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• pp.408-413
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• 1998

Electromagnetic wave absorbers for anechoic chamber are needed to broaden the useful frequency bandwidth, reduce the thickness, and decrease the weight. There are various absorbers proposed for the above conditions, but they could not decisively solve it the alone requirements. The Electromagnetic wave absorber made by a conventional ferrite tile has, for example, broadened the useful frequency bandwidth by the way of forming air layer(practically use urethane foam, etc.) on the ferrite tile. Therefore, an air layer is formed between a reflection plate and a sintered Ni-Zn ferrite tile of 7 mm in thickness, which has reflectivity less than -20 dB from 30 MHz to 600 MHz in bandwidth. Accordingly, in this paper, a broadened electromagnetic wave absorber will be designed, which has the reflection characteristics less than -20 dB from 30 MHz to 6000 MHz in the bandwidth. Then we will design a super broadband electromagnetic wave absorber by inserting square Ferrite Cylinders Type with the thickness less than 11 m and with the frequency band from 30 MHz to 6000 MHz under the above tolerance limits. The purpose of this research is on the development of a universal anechoic chamber for measuring radiated electromagnetic wave or immunity of electronic equipments, GTEM-cell, wall material for prevention TV ghost, etc.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.3
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• pp.313-318
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• 2012

Application of composite structures on naval ships strongly depends on the mechanical strength and collapse behavior of the T-joints of the whole structure. Because of the weight advantages over single skin composite and bolt fastening joining, three types of T-joints using both honeycomb sandwich composite and adhesive bonding were suggested to determine the effect of T-joint configuration. It was found that joining with a urethane foam block and overlaminates using the secondary co-bonding technique improves T-joint strength.

• Journal of Environmental Health Sciences
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• v.28 no.2
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• pp.41-49
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• 2002

Resource recovery and recycling of materials and products including polyurethanes are viewed as a necessity in today's society. The problems of recycling polyurethane wastes has major technological, economic and ecological significance because polyurethane itself is relatively expensive and its disposal by burning is also costly. In general, the recycling methods for polyurethane could be classified as mechanical, chemical and physical. In the chemical recycling method, there ate hydrolysis, glycolysis, pyrolysis and aminolysis. This study was carried out glycolysis using new method such as sonication and catalyzed reaction. There are kinds of recycled polyols were produced by current method(glycolysis) but, this study were with catalyzed reaction and sonication as decomposers and the chemical properties were analyzed. The reaction results in the formation of polyester urethane diols and then the OH value which is determined by the quantity of diol used for the glycolysis conditions. The glycolysis rates by sonication and catalyzed reaction for the various glycols, increased as: PPG