• Title/Summary/Keyword: Urban ozone

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Modeling the effects of land-sea breeze circulation on ozone distribution in coastal urban area. (연안 도시지역 해륙풍순환이 오존분포에 미치는 영향에 관한 수치모의)

  • 황미경;김유근;오인보
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.303-304
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    • 2003
  • 연안도시의 경우 해양 배경농도의 영향과 내륙과 비교해 강한 풍속조건이 형성됨으로 오존농도의 일변화 폭이 적으며 야간에 농도상승 현상이 빈번히 나타난다. 또한 일반적으로 여름철 주로 발생하는 해풍에 의해 고농도를 경험하게 되는데, 이는 해풍역전으로 인한 연직혼합의 억제와 (Lu and Turco, 1994) 해풍전선의 이동 (McElroy and Smith, 1991), 해풍의 내륙침투 시 생기는 Fumigation 효과(Entwistle, et al., 1997; Zhang et al., 1998) 등으로 설명되어 진다. 아울러 해륙풍순환으로 생기는 오전의 대기정체현상은 오후의 오존의 광화학 생성과 축적에 기여하게 되며 (Liu et al., 1994), 해풍 발달 시에는 오존 및 전구물질이 내륙 수송되어 풍하측 지역에 고농도가 나타나게 된다(Zhang et al., 1998). (중략)

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Influence of Greenhouse Gases on Radiative Forcing at Urban Center and Background Sites on Jeju Island Using the Atmospheric Radiative Transfer Model (대기복사전달모델을 이용한 제주지역 도심 및 배경지점에서의 온실가스에 따른 복사강제력 영향 연구)

  • Lee, Soo-Jeong;Song, Sang-Keun;Han, Seung-Beom
    • Atmosphere
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    • v.27 no.4
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    • pp.423-433
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    • 2017
  • The spatial and temporal variations in radiative forcing (RF) and mean temperature changes of greenhouse gases (GHGs), such as $CO_2$, $CH_4$, and $N_2O$, were analyzed at urban center (Yeon-dong) and background sites (Gosan) on Jeju Island during 2010~2015, based on a modeling approach (i.e., radiative transfer model). Overall, the RFs and mean temperature changes of $CO_2$ at Yeon-dong during most years (except for 2014) were estimated to be higher than those at Gosan. This might be possibly because of its higher concentrations at Yeon-dong due to relatively large energy consumption and small photosynthesis and also the difference in radiation flux due to the different input condition (e.g., local time and geographic coordinates of solar zenith angle) in the model. The annual mean RFs and temperature changes of $CO_2$ were highest in 2015 ($2.41Wm^{-2}$ and 1.76 K) at Yeon-dong and in 2013 ($2.22Wm^{-2}$ and 1.62 K) at Gosan (except for 2010 and 2011). The maximum monthly/seasonal mean RFs and temperature changes of $CO_2$ occurred in spring (Mar. and/or Apr.) or winter (Jan. and/or Feb.) at the two sites during the study period, whereas the minimum RFs and temperature changes in summer (Jun.-Aug.). In the case of $CH_4$ and $N_2O$, their impacts on the RF and mean temperature changes were very small (an order of magnitude lower) compared to $CO_2$. The spatio-temporal differences in these RF values of GHGs might primarily depend on the atmospheric profile (e.g., ozone profile), surface albedo, local time (or solar zenith angle), as well as their mass concentrations.

Air Pollutants Control Technique Trends for Transportation Sources in Korea (우리나라 이동오염원의 제어기술의 동향과 발전방안)

  • Kim, Jeong-Soo;Eom, Myung-Do
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.4
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    • pp.477-485
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    • 2013
  • The major source of harmful air pollutants in Korea have been shifted as economy grows. Particulate matter(PM) and Sulfur dioxide ($SO_2$) emitted from industries and coal-fired domestic sectors were important pollutants in 1970's and later industrializing period of Korea. Then the characteristic of pollution was changed into so-called "developed country type pollution". Vehicles have been responsible for significant amount of Nitric oxide ($NO_x$) pollution and consequent Ozone formation in urban area since 1990's. Variety of control measures have been introduced to deal with the vehicle emissions in Seoul Metropolitan Area (SMA). Emission control technologies have successfully reduced pollutants from vehicles. Three-way catalyst for vehicles fueled by gasoline and liquefied petroleum gas (LPG), for example, has achieved large amount of pollutants. Compressed natural gas (CNG) urban bus have penetrated existing diesel bus market and reduces PM and $NO_x$ emissions in many Korean cities. However, diesel vehicles are still reaming as a critical emission source of urban area. Diesel vehicles gain more popularity than ever because of their better fuel efficiency and driving power. Unfortunately, it is widely known that the pollutant emissions of diesel vehicles are much larger than those of gasoline and LPG vehicles. In this note, we briefly introduce the trends of emission control strategies which are accomplished by automotive industries for about last ten years. Emission regulation, cleaner fuel, diesel particulate filter (DPF) and other measures are discussed from technical as well as legislative perspectives.

Wall Contamination of Teflon Bags Used as a Photochemical Reaction Chamber of Ambient Air (실제 대기의 광화학 반응 챔버로 사용되는 테플론 백의 오염도 평가)

  • Lee, Seung-Bok;Bae, Gwi-Nam;Lee, Young-Mee;Moon, Kil-Choo
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.149-161
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    • 2013
  • Experiments on photochemical reactions of purified air alone in an indoor smog chamber were carried out after flushing Teflon bags with purified air for many hours in order to check the level of contamination on the chamber wall. Ozone concentrations were linearly increased from <4 ppb up to about 8 ppb with irradiation time for four hours. Outgassing of NOx from the chamber wall was found to be less than 1 ppb. New ultrafine particles were formed and grown up to about 70 nm during the photochemical reactions, and then total number and mass concentrations of particles were increased from <10 particles/$cm^3$ up to about 4,000 particles/$cm^3$ and $1.3{\mu}g/m^3$, respectively. The wall conditions of these Teflon bags flushed with purified air might not severly affect the chamber experimental results for photochemical reactions of polluted urban ambient air. The difference of gaseous species between two chambers was 2.4 ppb of ozone at most, indicating that the wall cleaning performance of two chambers was nearly similar.

An Analysis of Air Pollution Effect in Urban Area Related to Asian Dust on All-cause and Cause-specific Mortality in Seoul, Korea, 2000-2006 (도시 대기오염의 위해 평가에 있어서 황사효과 분석 -서울시 총사망 및 원인별 사망률에 미치는 영향-)

  • Son, Ji-Young;Cho, Yong-Sung;Kim, Yoon-Shin;Lee, Jong-Tae;Kim, Yeon-Jung
    • Journal of Environmental Health Sciences
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    • v.35 no.4
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    • pp.249-258
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    • 2009
  • The objectives of this study were to compare the relative risk of all-cause mortality and cause-specific mortality associated with Asian dust events, and especially to investigate the effects on the susceptible population such as the elderly and children, which were based on the data in Seoul from 2000 to 2006. Both of the study periods with/without Asian dust days, respiratory-cause mortality was the highest, followed by cardiovascular-cause mortality and all-cause mortality in sequence among mortality related to air pollution for all-aged group. As to susceptible group, the relative risk of mortality is the highest for +65 yrs group among all-cause mortality. According to comparison of mortality with/without Asian dust days, the relative risk of all-cause mortality is larger in the model with Asian dust days than the one in the model without Asian dust days among all age group (except for under 15 yrs group) and all air pollutants. The relative risk of cause-specific mortality (except for ozone in under 15 yrs group in case of respiratory-cause mortality, and ozone in all age group and over 65 yrs group in case of cardiovascular-cause mortality) per IQR increase of each pollutant is larger in the model without Asian dust days.

Investigation of SO2 Effect on TOMS O3 Retrieval from OMI Measurement in China (OMI 위성센서를 이용한 중국 지역에서 TOMS 오존 산출에 대한 이산화황의 영향 조사 연구)

  • Choi, Wonei;Hong, Hyunkee;Kim, Daewon;Ryu, Jae-Yong;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.32 no.6
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    • pp.629-637
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    • 2016
  • In this present study, we identified the $SO_2$ effect on $O_3$ retrieval from the Ozone Monitoring Instrument (OMI) measurement over Chinese Industrial region from 2005 through 2007. The Planetary boundary layer (PBL) $SO_2$ data measured by OMI sensor is used in this present study. OMI-Total Ozone Mapping Spectrometer (TOMS) total $O_3$ is compared with OMI-Differential Optical Absorption Spectrometer (DOAS) total $O_3$ in various $SO_2$ condition in PBL. The difference between OMI-TOMS and OMI-DOAS total $O_3$ (T-D) shows dependency on $SO_2$ (R (Correlation coefficient) = 0.36). Since aerosol has been reported to cause uncertainty of both OMI-TOMS and OMI-DOAS total $O_3$ retrieval, the aerosol effect on relationship between PBL $SO_2$ and T-D is investigated with changing Aerosol Optical Depth (AOD). There is negligible aerosol effect on the relationship showing similar slope ($1.83{\leq}slope{\leq}2.36$) between PBL $SO_2$ and T-D in various AOD conditions. We also found that the rate of change in T-D per 1.0 DU change in PBL, middle troposphere (TRM), and upper troposphere and stratosphere (STL) are 1.6 DU, 3.9 DU and 4.9 DU, respectively. It shows that the altitude where $SO_2$ exist can affect the value of T-D, which could be due to reduced absolute radiance sensitivity in the boundary layer at 317.5 nm which is used to retrieve OMI-TOMS ozone in boundary layer.

Establishment of Resilient Infrastructures for the Mitigation of an Urban Water Problem: 2. Robustness Assessment of Structural Alternatives for the Problems of Water Pollution (도시 물 문제 저감을 위한 회복탄력적 사회기반시설 구축: 2. 수질오염 문제 구조적 대안의 내구성 평가)

  • Jung, Jihyeun;Lee, Changmin;An, Jinsung;Kim, Jae Young;Choi, Yongju
    • Ecology and Resilient Infrastructure
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    • v.3 no.3
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    • pp.182-188
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    • 2016
  • This study evaluated structural alternatives for managing water quality problems by reinterpreting and then applying the robustness-cost index (RCI) for urban flood problems. Cases of endogenous hormone pollution in treated sewage and proliferation of protozoa in intake-water were chosen as representative examples because they have different types of regulation standards for the treatment. Current facilities and structural alternatives with robustness indices (RIs) greater than unity were determined to be robust. The RI was combined with the cost index (CI) to obtain the RCI values. For the endogenous hormone pollution in treated sewage, a human-oriented estrogen $17{\beta}$-estradiol was selected as a target pollutant. The RI and RCI values for a structural alternative, extension of the current sewage treatment facility for advanced treatment, were greater than the values for the current practice of conventional activated sludge process. For the intake-water pollution by protozoa, UV and ozone disinfection facilities were evaluated for inactivation of Cryptosporidium parvum. The RCI values for ozone disinfection were greater than those for UV disinfection. Based on the results and the logics involved in the calculation of RCI for water quality issues we studied, we proposed procedures for establishing and implementing structural alternatives for the restoration from and prevention of outbreaks of water quality problems.

Variations of Ozone and PM10 Concentrations and Meteorological Conditions according to Airflow Patterns of their High Concentration Episodes on Jeju Island (제주지역 오존 및 미세먼지 고농도일의 기류패턴에 따른 농도변화와 기상조건 분석)

  • Han, Seung-Bum;Song, Sang-Keun;Choi, Yu-Na
    • Journal of Environmental Science International
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    • v.26 no.2
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    • pp.183-200
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    • 2017
  • The classification of airflow patterns during high ozone ($O_3$) and $PM_{10}$ episodes on Jeju Island in recent years (2009-2015), as well as their correlation with meteorological conditions according to classified airflow patterns were investigated in this study. The airflow patterns for $O_3$ and $PM_{10}$ were classified into four types (Types A-D) and three types (Types E-G), respectively, using the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model and synoptic weather charts. Type A was the most dominant airflow pattern for $O_3$ episodes, being characterized by the transport of airflows from urban and industrial areas in China with the highest frequency (about 69%, with a mean of 67 ppb). With regard to the $PM_{10}$ episodes, Type E was the most dominant airflow pattern, and was mostly associated with long distance transport from Asian dust source regions along northwesterly winds, having the highest frequency (about 92%, with a mean of $136{\mu}g/m^3$). The variations in the concentration of $O_3$ and $PM_{10}$ during the study period were clarified in correlation with two pollutant and meteorological variables; for example, the high (low) $O_3$ and $PM_{10}$ concentrations with high (low) air temperature and/or wind speed and vice versa for precipitation. The contribution of long-range transport to the observed $PM_{10}$ levels in urban sites for different airflow patterns (Types E-F), if estimated in comparison to the data from the Gosan background site, was found to account for approximately 87-93% (on average) of its input. The overall results of the present study suggest that the variations in $O_3$ and $PM_{10}$ concentrations on Jeju Island are mainly influenced by the transport effect, as well as the contribution of local emissions.

Water Quality Assessment of Major Drinking Waters in Natural Parks (자연공원내 주요 음용수의 수질환경평가)

  • Yi, Youngkyoung;Yi, Pyongin;Hong, Sungchul
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.439-453
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    • 2018
  • The purpose of this study is to evaluate water quality characteristics of main drinking waters in natural parks, for providing the basic information of water quality and to propose the appropriate management method. to maintain the water quality standards. As a result of the analysis, microorganisms were mostly detected in the nature of natural park. And some sites are currently using UV sterilizer and ozone treatment, and it is considered appropriate to extend the use to other main drinking water. It is also good to boil drinking water at home. Turbidity is expected to improve through environmental cleanup. Overall, the main drinking water in the natural park is suitable for water quality standards, and it is considered that maintenance such as cleaning is necessary.

Characteristics in Atmospheric Chemistry between NO, NO2 and O3 at an Urban Site during MAPS (Megacity Air Pollution Study)-Seoul, Korea (서울 도심대기의 NO, NO2와 O3 사이의 대기화학적 특성 연구)

  • Kim, Deug-Soo;Jeong, Jinsang;Ahn, Joonyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.4
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    • pp.422-434
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    • 2016
  • This study was conducted to understand roles of $NO_x(=NO+NO_2)$ on high $O_3$ episodes at an urban monitoring station in Seoul. Concentrations of NO, $NO_2$, $NO_y$ and $O_3$ were measured intensively at KIST monitoring station which located at urban center in Seoul metropolitan area during May 18~June 13, 2015. Sampling period was planed because high $O_3$ and PM occurred frequently during from late spring to early summer months in Seoul. The experimental site locates in NW from center of Seoul and is surrounded by residential area. Belt highway of the city runs from north to west side nearby experimental site. Vehicle exhaust emissions due to heavy traffic influenced $NO_x$ concentration at the site during northwesterly wind. Specific $NO_2$ concentration was measured by Blue Light photolytic converter, and it was compared to $NO_2$ concentration measured by molybedenum converter. $[NO_2]_{phtolysis}$ was usually lower than $[NO_2]_{molybedenum}$ during the experiment period; however their diurnal variations were very similar. The linear relationship between these $NO_2$ concentrations was found to be $[NO_2]_{phtolysis}$=0.64 $[NO_2]_{molybedenum}$ - 2.6, $r^2$=0.83 during May 16~8, 2015. The difference between $NO_2$ by molybdenum converter and by photolytic converter (${\Delta}NO_2=[NO_2]_{molybedenum}-[NO_2]_{phtolysis}$) accounted for residual $NO_y$ which can represent $NO_z$ (=$NO_y-NO_x$). $O_3$ concentration showed typical daily trend which has maximum at late afternoon and minimum during the night. $O_3$ increased at a rate of 7 ppb/hr since 8 am. and reached the maximum concentration (~80 ppb) at 3 pm.. The diurnal pattern of $O_3$ was inversely related with that of $NO_2$, suggesting that the formation of $O_3$ was the result of photochemical activity of $NO_2$.