• Membrane Journal
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• v.15 no.2
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• pp.105-113
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• 2005

Silica membranes were prepared on a porous metal sheet by ultrasonic spray pyrolysis method for gas separation at high temperatures. In order to improve the permselectivity, silica was deposited in the sol-gel derived $silica/\gamma-alumina$ intermediate layer by pyrolysis of tetraethyl orthosilicate (TEOS) at 873 K. The pyrolysis with forced cross flow through the porous wall of the support was very effective in plugging mesopores, Knudsen diffusion regime, that were left unplugged in the membranes. At permeation temperature of 523 K, the silica/alumina composite membrane showed $H_2/N_2$ and water/methanol selectivity as high as 17 and 16, respectively, by molecular sieve effect.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.2
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• pp.83-92
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• 2005

An electromagnetic acoustic transducer (EMAT) is a unique probe that does not require a couplant or gel and also can usually generate or detect an ultrasonic wave into specimens across a small gap. It, therefore can be applied in a noncontact mode with a high degree of reproducibility. Especially stiffness of composites depends on layup sequence of CFRP(carbon fiber reinforced plastics) laminates. It is very important to evaluate the layup errors in prepreg laminates. A nondestructive technique can therefore serve as a useful measurement for detecting layup errors. This shear wave for detecting the presence of the errors is very sensitive. A decomposition model has been used in the interpretation and prediction of test results. Test results have been com pared with model data. It is found that the high probability shows between tests and the model utilized in characterizing cured layups of the laminates. Also a C-scan method was used for detecting layup of the laminates because of extracting fiber orientation information from the ultrasonic reflection caused by structural imperfections in the laminates. Therefore, it was found that interface C-scan images show the fiber orientation information by using two-dimensional fast Fourier transform (2-D FFT).

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1589-1595
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• 2010

In order to effective degradation of organic dye both under visible light or ultrasonic irradiation, the MWCNTs (multiwalled carbon nanotube) deposited with Fe and $TiO_2$ were prepared by a modified sol-gel method. The Fe/$TiO_2$-MWCNT catalyst was characterized by surface area of BET, scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX) and ultraviolet-visible (UV-vis) spectroscopy. The low intensity visible light and low power ultrasound was as an irradiation source and the methylene blue (MB) was choose as the model organic dye. Then degradation experiments were carried out in present of undoped $TiO_2$, Fe/$TiO_2$ and Fe/$TiO_2$-MWCNT catalysts. Through the degradation of MB solution, the results showed the feasible and potential use of Fe/$TiO_2$-MWCNT catalyst under visible light and ultrasonic irradiation due to the enhanced formation of reactive radicals as well as the possible visible light and the increase of ultrasound-induced active surface area of the catalyst. After addition of $H_2O_2$, the MB degradation rates have been accelerated, especially with Fe/$TiO_2$-MWCNT catalyst, in case of that the photo-Fenton reaction occurred. The sonophotocatalysis was always faster than the respective individual processes due to the more formation of reactive radicals as well as the increase of the active surface area of Fe/$TiO_2$-MWCNT catalyst.

• Journal of Periodontal and Implant Science
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• v.51 no.4
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• pp.276-284
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• 2021

Purpose: The aim of this randomized clinical trial was to assess whether chemical cleansing using a sulfonic/sulfuric acid gel solution (HBX) as an adjunct to scaling and root planing (SRP) resulted in a decrease in residual plaque and calculus in deep periodontal pockets compared to SRP alone. Methods: Fifty-six patients with 56 hopeless posterior teeth, scheduled for extraction due to severe periodontitis, were enrolled in this study. Each tooth was randomly assigned to 1 of the 2 experimental procedures. The test teeth were subjected to the irrigation of the subgingival area with HBX for 2 minutes, followed by SRP with hand and ultrasonic instruments for 14 minutes, and then extracted. The control teeth received only mechanical instrumentation before extraction. Residual biofilm was evaluated on photographs and measured as total area and percentage of root surface covered by remaining plaque (RP) or calculus (RC) after treatment. Results: The initial pocket depth (PD) and total subgingival root surface area were similar between the 2 treatment groups. After treatment, the total subgingival root area covered by RP and RC was statistically significantly larger (P<0.001) in the control group than in the test group. The test teeth showed a lower percentage of RP, but a higher percentage of RC than the control teeth (both P<0.001). Complete calculus removal was achieved in 42% of the control teeth surfaces and in 25% of the test teeth surfaces for a PD of 4 mm. Conclusions: The additional chemical cleansing with HBX resulted in a statistically significant improvement in bacterial plaque removal during SRP of deep pockets, but it was not effective in reducing calculus deposits.

• Journal of the Korean Ceramic Society
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• v.47 no.2
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• pp.136-141
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• 2010

ACF/ZnO photocatalyst was synthesized by a sol-gel method using activated carbon fiber (ACF) and Zn $(NO_3)_2$ as precursors. Samples were characterized by Brunauer-Emmett-Teller measurements (BET), scanning electron microscope (SEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX). The XRD results showed that ACF/ZnO composites only included a hexagonal phase by heat-treated temperature at $400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, and $700^{\circ}C$. The SEM analysis revealed that the ACF/ZnO composites did not exhibit any morphological changes of the catalyst surface according to the different heat-treated temperatures. The photocatalytic activity of the samples was tested for degradation of methylene blue (MB) solutions under ultraviolet (UV) light and ultrasonication respectively. The results showed that the photocatalytic activity of ACF/ZnO composites heat-treated at $500^{\circ}C$ was higher than other samples, which is ascribed to the fine distribution of ZnO particles on the surface of the ACF. In addition, an ultrasound of low power (50 W) was used as an irradiation source to successfully induce ACF/ZnO composites to perform sonocatalytic degradation of MB. Results indicated that the sonocatalytic method in the presence of ACF/ZnO composites is an advisable choice for the treatments of organic dyes.

• KIEAE Journal
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• v.17 no.3
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• pp.107-112
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• 2017

Purpose: Both silica gel and activated carbon black particles were adopted for use as PCM absorbed porous media applicable as construction materials. To investigate usable methods for absorbing PCM into the media, they were soaked into PCM and also tested for enhancement of PCM absorption into them. Method: To test PCM absorption into some porous media such as both ${\varphi}1{\sim}2mm$ and $10{\mu}m$ silica gels, and $50{\mu}m$ activated carbon black, $43^{\circ}C$ PCM was used as a laten heat material. The method, soaking into PCM was applied to this study, and the media were moderately rotated by centrifuge to have the extra PCM flow out. DSC analysis was conducted to investigate the melting and solidifying of the PCM absorbed into the porous media. Result: It was found that PCM was absorbed into the porous media by over 85 wt% of all particles. In addition, it was noted that the ultrasonic vibrator was accelerating the PCM absorption into the particles to three times higher speed than simple soaking. Centrifuge was adopted to remove extra PCM sticking on the particle surfaces and extra PCM was moderately removed from the surfaces of the particles. DSC analysis indicated that the latent heat of the absorbed PCM particles was 160 J/g, and the melting temperature was approximately $40^{\circ}C{\sim}50^{\circ}C$.

• Environmental Engineering Research
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• v.24 no.2
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• pp.181-190
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• 2019

Constructed wetlands are improvised man-made systems, designed for adopting the principle of natural wetlands for purifying wastewater - the elixir of life. They are used widely as a cost-effective and energy-efficient solution for treating greywater generated from different tertiary treatment sources. It provides an elaborate platform for research activities in an attempt to recycle earth's natural resources. Among the several organic impurities removal mechanisms existing in constructed wetland systems, the earth's active microbial population plays a vital role. This review deals with the recent advancements in constructed wetland systems from a microbiological perspective to (effect/ devise/ formulate) chemical and physical treatment for water impurities. It focuses on microbial diversity studies in constructed wetlands, influence of wetland media on microbial diversity and wetland performance, role of specific microbes in water reuse, removal of trace elements, some heavy metals and antibiotics in constructed wetlands. The impurities removal processes in constructed wetlands is achieved by combined interactive systems such as selected plant species, nature of substrate used for microbial diversity and several biogeochemical effected reaction cycles in wetland systems. Therefore, the correlation studies that have been conducted by earlier researchers in microbial diversity in wetlands are addressed herewith.

• Korean Journal of Environmental Biology
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• v.24 no.3
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• pp.221-229
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• 2006

The effects of ultrasonication on phytoplankton were investigated in two ponds in which physicochemical and biological water quality was similar, one as a treatment and the other as a control. The samples were collected from August 18 to September 30 in 2003. Traditional morphological analysis showed that Bacillariophyceae dominated phytoplankton community in both ponds. The abundance of Cyanophyceae was lower in the phytoplankton community of the sonicated pond than that of control pond. We used DGGE (denaturing gradient gel electrophoresis) to analyze the diversity and change of phytoplankton community in two ponds. The DGGE banding patterns of 16S rRNA gene and sequence analysis demonstrated that Oscillatoria acuminata and CFB (Cytophaga-Flavobacterium-Bacteroides) group bacterium appeared in the treated pond, and the control pond was dominated by Synechococcus sp. and Aphanizomenon flos-aquae. Especially, Pseudanabaena sp. dominated during the ultrasonic cessation in the treated pond. The DGGE profiles of 18S rRNA gene and sequence analysis showed that the treated pond was dominated by Chlamydomonas reinhardtii and the control pond by C. reinhardtii and Pteromonas protracta. In conclusion, the ultrasonication affected the reduced growth of cyanobacteria, particularly Pseudanabaena.

• KSBB Journal
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• v.22 no.5
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• pp.351-355
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• 2007

Resveratrol, a polyphenolic compound with antioxidative property, was purified from the grape's twig to be used as functional additives of food and/or cosmetics. Extraction of the grape's twig was performed using 80% ethanol in ultrasonic extractor for 60 min. The crude extract was purified up to 99% after elution through silica gel open column chromatography. The stability of the purified resveratrol was as follows: a half life of 90 days at 40$^{\circ}C$ and 60 days at 25$^{\circ}C$. A sensory test of the commercial grape juice including the 1-10 ppm of purified resveratrol showed better preference than the grape juice without purified resveratrol additive. Color and smell test showed no difference between the samples. The grape twig can be used as a valuable resource for the extraction of resveratrol, which would be added to nutraceutical and cosmetic products.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.601-604
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• 2008

When the concrete is placed, the water, needed for hydration of the cement, is under 30% of W/C including bound and gel water. However, as minimum water content cause bad workability, the W/C have to be higher. Therefore, fresh concrete produce 10${\sim}$20% extra water. As those water remain entrapped air in the concrete, life of the structure is reduced because of the degradation caused by entrapped air. For that reason, if extra water is eliminated, it will be great to improve the durability of the structures. Therefore, this study was performed to verity the fundamental properties through the experiment on the dewatering system using the euro form for eliminating extra water. When the dewatering form was applicated, the compressive strength was increased by 16% than those of normal form. However, the increasing rate of compressive strength got lower as the height is higher. In terms of ultrasonic pulse speed and surface roughness, the dewatering form showed better results than the normal one.